Bulletin of the Korean Chemical Society

  • 제21권6호
  • /
  • Pages.618-622
  • /
  • 2000
  • /
  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지
DOI QR코드

DOI QR Code

Synthesis and MNR Studies of Core-Modified, N-Confused porphyrins Possessing Alkyl Groups at the Rim Nitrogen

  • 발행 : 20000600
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

The '3+1'type condensation of 16-thiatripyrromethane with $N-alkyl-24-bis[(\alpha+hydroxy-\alpha-phenyl)methyl]pvrole$, in the presence of acid catalyst afforded core-modified, N-confused porphyrins bearing alkyl groups at the rim nitrogen. The proton NMR spectra indicate that the bulkiness of the N-alkyl substituents is somewhat relatedwith the tiltedness of the inverted pyrrole ring. The changes in chemical shift of inner methine protons depending on the N-alkyl group and protonation site is discussed.

키워드

참고문헌

  1. J. Am. Chem. Soc. v.116 no.767 Furuta, H.;Asano, T.;Orawa, T.
  2. Angew. Chem. Int. Ed. Engl. v.33 no.779 Chmielewski, P. J.;Latos-Grazynski, L.;Rachlewicz, K.;Glowiak, T.
  3. Chem. Lett. v.453 Ishikawa, Y.;Yoshida, I.;Akaiwa, K.;Koguchi, E.;Sasaki, T.;Furuta, H.
  4. J. Chem. Soc. Perkin Trans 2. v.667 Ariga, K.;Kunitake, T.;Furuta, H.
  5. J. Org. Chem. v.64 no.1596 Geier, G. R.;Lindsey J. S.
  6. J. Am. Chem. Soc. v.121 no.2945 Furuta, H.;Ishizuka, T.;Osukam A,;Ogawa, T.
  7. Inorg. Chem. v.38 no.2676 Furuta, H.;Ogawa, T.;Uwatoko, Y.;Araki, K.
  8. Angew. Chem. Int. End. Engl. v.34 no.1028 Ghosh, A.
  9. Tetrahedron Lett. v.38 no.3935 Lee, C. H.;Kim, H. J.
  10. Tetrahedron v.51 no.11645 Lee, C. H.;Li, F.;Iwamoto, K.;Dadok, J.;Both-nerby, A.;Lindsey, J. S.
  11. The Porphyrins;Dolphin, D.(Ed.) v.Ⅲ Gouterman, M.
  12. Tetrahedron v.50 no.11427 Lee, C. H.;Lindsey, J. S.
  13. J. Org. Chem. v.64 no.7890 Cho, W. S.;Kim, H. J.;Littler, B. J.;Miller, A. M.;Lee, C. H.;Lindsey, J. S.
  14. J. Org. Chem. v.64 no.2864 Littler, B. J.;Ciringh, Y. Z.;Lindsey, J. S.
  15. Bull. Korean Chem. Soc. v.20 no.276 Lee, C. H.;Kim, H. J.;Yoon, D. W.

피인용 문헌

  1. Carbaporphyrinoid Systems vol.117, pp.4, 2000, https://doi.org/10.1021/acs.chemrev.6b00326
  2. Heteroatom-Containing Porphyrin Analogues vol.117, pp.4, 2000, https://doi.org/10.1021/acs.chemrev.6b00496
  3. Rational Synthesis of 5,5,5‐Tricyclic Fused Thia‐heptaphyrin (1.1.1.1.1.1.0) From a Helical Oligopyrrin Hybrid vol.15, pp.8, 2000, https://doi.org/10.1002/asia.202000100
  4. Friedel-Crafts acylation of antiaromatic norcorroles: electronic and steric modulation of the paratropic current vol.8, pp.14, 2000, https://doi.org/10.1039/d1qo00621e