Analysis of Radiolytically Proudced Hydrocarbons and 2-Alkylcyclobutanones from Irradiated Pinenut

방사선 조사된 잣으로부터 조사 여부를 확인하기 위한 Hydrocarbon류와 2-Alkylcyclobutanone류의 분석

  • Published : 2001.02.01

Abstract

Pinenut was irradiated with the dose of 0.5∼10 kGy. Radiation-induced hydrocarbons and 2-alkylcyclobutanones were extracted from pinenut, separated by florisil column chromatography and identified with GC/MS method. Concentrations of hydrocarbons and 2-alkylcyclobutanones were increased with the increase of irradiation dose and the composition of patty acids in pinenut affected on products detects. The major hydrocarbons in irradiated pinenut were 8-heptadecene and 1,7-hexadecadiene originated ferom oleic acid and 6,9-heptadecadiene and 1, 7, 10-hexadecatriene originated from linoleic acid. 2-(5'-Tetradecenyl) cyclobutanone originated from oleic acid was highest in the irradiated pinenut. Radiation-induced hydrocarbons hydrocarbons and 2-alkylcyclobutanones in pinenut were detected at 0.5 kGy and over, but not detected in the unirradiated samples.

Keywords

References

  1. Safety of irradiated foods(2nd ed.) Potential and current applications of food irradiation Diehl J. F.
  2. Technical Report Series 659 Wholesomenessof irradiated food. Report of a Joint FAO/IAEA/WHO Expert Commitee WHO
  3. Radiat. Phys. Chem. v.55 Detection of prior irradiation of dried fruits by election spin resonance(ESR) Esteves U. P.;Andrade M. E.;Empis J.
  4. Appl. Radiat. Isotopes v.52 Election paramagnetic resonance identification of cuttlefish(Sepia officinalis L.) Deliu O. G.
  5. J. AOAC Int. v.78 An interlaboratory trial on the identification of irradiate spices, herbs, and spice-hero mixture by thermoluminescence analysis Schreiber G. A.;Helle N.;Bogi K. W.
  6. Spectrochin Acta(A) v.56 Identification of irradiation treatment of aromatic herbs, spices and fruits bu electron paramagnetic resonance and thermoluminescence Raffi J.;Yordanov N. D.;Chabane S.;Douif L.;Gancheva V.;Ivanova S.
  7. Radiat. Phys. Chem. v.52 Detection of irradiated food;DNA framentation in grapefruits Delincee H.
  8. Eur. Food Res. Technol. v.211 Control of imported irradiated frozen meat and poultry using the hydrocarbon method and the DNA comet assay Merino L.;Cerda H.
  9. J. Food Protection v.63 Detrction of radiation induced hydrocarbons and 2-alkylcyclobutanones in irradiated perilla seeds Lee H. J.;Byun M. W.
  10. J Sci. Food Agric v.80 2-alkylcyclobutanones as markers for the detection of irradiated mango, papays, Camemebert cheese and salmon meat Stewart E. M.;Moore S.;Grahm W. D.;McRoberts W. C.;Hamilton J. T. G.
  11. Food Rev. Int. v.2 Volatiles from food irradiation Nawar W. W.
  12. Lipids v.7 2-Alkylcyclobutanones from the radiolysis of triglycerides LeTellier P. R.;Nawar W. W.
  13. J Agric. Food.Chem v.39 Synthesis characterization and potential use of 2-dodecylcyclobutanone, a potential market for irradited chicken Boyd D. R..;Hamilton J. T. G.;Crone A. V. J.;Hand M. V.
  14. J Sci. Food Agric. v.58 Efect of storage and cooking on the dose response of 2-dodecyl-cyclobutanone, a potential marker for irradiated chiken Crone A. V. J.;Hamilton J. T. G.;Stevenson M. H.
  15. Radiat. Phys. Chem. v.42 Identification of irradiated foods by monitoring radiolytically produced hydrocarbons Morehouse K. M.;Ku Y.
  16. J. Sci. Food Agric v.62 Synthesis, characterization and use of 2-tetradecylcyclobutanone together with other cyclobutanones as markers for irradiated liquid whole egg Crone A. V. J.;Hand M. V.;Hamilton J. T. G.;Sharma N. D.;Boyd D. R.;Stevenson M. H.
  17. BCR Information;recent Advances on the Detection of irradiated Food, EUR/14315/EN The use of 2-alkylcyclobutanones for the detection of irradiated lipid containing foods Stevenson M. H.;Crone A. V. J.;Hamilton J. T. G.
  18. Radiat. Phys. Chem. v.43 Methods for routine control of irradiated food;optimization of a method for detection of radiatation induced hydrocarbons and its application to various foods Spiegelberg A.;Schulzki G. M.;Helle N.;Bogl K. W.;Scheiber G. A.
  19. Mitt. Gebiere Lebebsm. Hyg v.87 Detection of irradiation of fat-containing foods by on-line LG-GC-MS of alkylcyclobutaniones Meier W.;Artbo A;Nageli P;
  20. Z. Lebensm. Unters. Forsch. A. v.204 Detection of radiation-induced hydrocarbons in processed food and complex lipid matrices;A New solid phase extraction(SPE)method for detection of irradiated components in food Hartmann M.;Ammon J.;Berg H.
  21. Food Sci. Technol Today v.12 0-Alkylcyclobutanones as markers for exotic fruits Stewart E. M.;Moore S.;McRoberts W. C.;Graham W. D.;Hamilton J. T.G.
  22. Z. Lebensm. Unters. Forsch. A v.207 Influence of τ-irradiation and microwaves on the linear unsaturated hydrocarbon fraction in spices Bendini A.;Toschi T. G.;Lercker G
  23. Radiat. Phys. Chem. v.55 2-Alkylcyclobutanones as markers for irradiated foodstuffs ⅱ. The Cen(European Committee for standardization) method;Field of application and limit of utilization Ndiaye B.;Jamet G.;Miesch M.;Hasselmann C.;Marchioni, E
  24. Korean J. Food Sci. Technol. v.32 Quantitative comparison of radiation-induced hydrocarbons from irradiated beef,pork and chiken Kim K.S.;Kim E. A.;Lee H. J.;Yang J. S.;Byun M. W.
  25. J. Food Sci. Nur v.4 Detection of radiation induced hydrocarbons and 2-alkylcyclobutanones from peanut Lee H .J.;Lee M. Y.;Kim K. S.
  26. Korean J. Food Sci. Technol. v.18 Volatile components of pinenut Kim Y. K.;Chung K. N.;Ishi H.;Muraki S.
  27. J. AOCS Int v.77 Evaluation of a gas chromatographic method to identify irradiated chicken, pork and beef by detection of volatile hydrocarbons Schreiber G. A.;Schulzki G.;Spiegelberg A.;Helle N.;Bogi K. W.
  28. J. Argic. Food Chem v.41 Identification of meat treated with ionizing radiation by capillary gas chromatographic determanation of radiolytically produced hydrocarbons Morehouse K. M.;Kiesel M.;Ku Y.
  29. Detection methods for irradiated foods-current status Progress in the detection of irradiated foods by measurements of lipid-derived volatiles Nawar W. W.;Zhu Z.;Wan H.;Detroote E.;Chen Y.;Aciukewicz T.;McMurrary C. H.(eds.);Stewart E. M.(eds.);Gray R.(eds.);Pearce J.(eds.)
  30. J Argic. Food Chem. v.42 Formation of hydrocarbons in irradiated Brazilian beans;Gas chromatographic analysis to detect radiation processing Villavicencio A. C. H.;Mancini-Filho. J.;Hartmann M.;Ammon J.;Delincee H.