This paper deals with the experiment to obtain quantitative information about conditions of the interface between a water drop and surrounding oil. Velocity distributions in very close region of the interface are measured by introducing a new illumination technique and a telecentric lens. It enables precise measurements of velocity distributions in the close region to the interface. Although the measured velocity distributions exhibit strong influence from the solid wall of an experimental tube, the coincidence of inner and outside velocities on the interface is clearly confirmed for the clean interface. The shearing stresses on the interface, which are proportional to the velocity gradient normal to the interface, clearly show conditions of contaminated interface, which can be divided into two parts. From front stagnation point to somewhere near a separation point, the distribution of shearing stresses is well coincide with that of the Hadamard's analytical solution, while the distribution on the latter part of the interface sows quite different feature, which is supposed to be strongly influenced by contamination of the surface.