DOI QR코드

DOI QR Code

Separation of Positional Isomers in a Calix[4]arene-methylsiloxane Polymer as Stationary Phase in Capillary GC


초록

Poly(p-tert-butyltrimethoxymonopropyloxycalix[4]arene-methylsiloxane) (TBCX-MS) has been prepared and used as a stationary phase in isothermal capillary gas chromatographic separation of some positional isomers. Retention factors (k) and separatio n factors $(\alpha)$ for the isomers were measured and compared with those on poly(p-tert-butyl-dimethoxydipropyloxycalix[4]arene-tetramethyldisiloxane) (TBCX-TMDS), poly(dimethoxydipropyloxycalix[4]arenetetramethyl-disiloxane) (CX-TMDS). Most of the isomers investigated are well resolved on TBCX-MS. Retention of all the compounds decreases on the three phases in the order, TBCX-TMDS ${\geq}$ TBCX-MS > CX-TMDS. Similar retention values on TBCX-TMDS and TBCX-MS seem to indicate that retention property of the two phases is not significantly affected by the spatial position of the calixarene moiety.

키워드

참고문헌

  1. Kluwer A Versatile Class of Macrocyclic Compounds Viens, J.;Bohmer, V.
  2. Angrew. Chem. Int. Ed. Engl. v.19 Saemger, W.;
  3. Sep. Purif. Methods v.10 Hinze, W. L.
  4. J. Chronmatogr. v.258 Nobuhara, Y.;Hirano, S.;Nakanishi, Y.
  5. J. Inclustion Phenom v.2 Amstrong, D. W.;Alak, A.;Bui, K.;DeMond, W.;Ward, T.;Riehl, T. E.;Hinze, W. L.
  6. J. Chromatogr. Sci. v.22 Amstrong, D. W.;DeMond, W.
  7. Anal. Chem. v.57 Hinze, W. L.;Riehl, T. E.;Armstrong, D. W.;DeMond, W.;Alak, A.;Ward, R.
  8. J. Chromatogr. v.499 Mohseni, R. M.;Hurtubise, R. J.
  9. J. Chromatogr. v.595 Park, J. H.;Jang, M. D.;Shin, M. J.
  10. Liq. Chromatogr. v.10 Street, Jr. K. W.
  11. J. Am. Chem. Soc. v.103 Gutsche, C. D.;Chawan, B.;No, K. H.;Muthukrishana, R.
  12. Makromol. Chem. v.188 Dhawan, B.;Chen, S. I.;Gutsche, C. D.
  13. Anal. Lett. v.16 Mangia, A.;Pochini, A.;Ungaro, R.;Andreetti, G. D.
  14. J. Chromatogr. A. v.696 Mnuk, P.;Feltl, L.
  15. J. Chromatogr. A. v.732 Mnuk, P.;Feltl, L.;Schurig, V.
  16. Anal. Lett. v.126 Glennon, J. D.;Herne, E.;Srijaranai, S.;Manley, K.;Harris, S. J.;McKervey, M. A.
  17. Anal. Proc. v.31 Glennon, J. D.;Horne, E.;O'Connor, K.;Kearney, G. A.;Harris, S. J.;McKervey, M. A.
  18. J. Chromatogr. A. v.731 Brindle, R.;Albert, K.;Harris, S. J.;Troltasch, C.;Horne, E.;Glennon, J.
  19. J. Chromatogr. A. v.731 Gennon, J. D.;Horne, E.;Hall, K.l;Cocker, D.;Kuhn, A.;Harris, S. J.;Mckervey, M. A.
  20. J. Chromatogr. Sci. v.33 Freibe, S.;Gebauer, S.;Krauss, G. J.;Goermar, G.;Krueger, J.
  21. Anal. Lett. v.31 Healy, L. O.;McEnergy, M. M.;Mccarthy, D. G.;Harris, S. J.;Glennon, J. D.
  22. J. Protein Chem. v.17 Kruss, G. J.;Freibe, S.;Gebauer, S.
  23. J. Chromatogr. Sci. v.36 Gebauer, S.;Friebe, S.;Gubitz, G.;Krauss, G. J.
  24. J. Chromatogr. Sci. v.36 Gebauer, S.;Friebe, S.;Scherer, G.;Gubitz, G.;Krauss, G. J.
  25. J. Am. Chem. Soc. v.108 Shinkai, S.;mori, S.;Koreishi, H.;Tsubki, Y.;Manabe, O.
  26. Chrimatographia v.37 Park, J. H.;Lee, Y. K.Cheong, N. Y.;Jang, M. D.
  27. Chromatographia v.46 Lee, Y. K.;Ryu, Y. K.;Ryu, J. W.;Kim, B. E.;Park, J. H.
  28. Anal. Chem. v.66 Shohat, D.;Grushka, E.
  29. Chromatographia v.48 Lim, H. J.;Lee, H. S.;park, J. H.;Kim, I. W.;Chang, S. H.;Moon, S. C.;Kim, B. E.;
  30. J. Microcol. Sep. v.11 Gross, B.;Jauch, J.;Schrig, V.
  31. J. Chromatogr. A. v.840 Pfiffer, J.;Schrig, V.
  32. J. Chem. Soc. Chem. Commun v.16 Zhong, Z. L;Tang, C. P.;Wu, C. Y.;Chen, Y. Y.
  33. Chromatographia v.47 Lin, L.;Wu, C. Y.;Yan, Z. Q.;Yan, X. Q.;Su, X. L.;Han, H. M.
  34. J. Chromatogr. A v.840 Zhang, L. F.;Chen, L.;Lu, X. R.;Wu, C. Y.;CHen, Y. Y.
  35. J. Org. Chem. v.51 Gutshe, C. D.;Iqbal, M.;Stewart, D. J.;
  36. Tetrahedron v.42 Gutsche, C. D.;Lin, L. G.
  37. J. Org. Chem. v.55 Loon, j. D.;Arduini, A.;Coppi, L.;Verboom, W.;Pochini, A.;Ungaro, R.;Harkema, S.;Reinhout, D. M.
  38. Tetrahedron Lett. v.30 Loon J. D. V.;Arduini, A.;Verboom, W.;Ungaro, R.;Hummel, G. J.;Harkema, S.;Reinhoudt, D. N.
  39. J. Gas Chromatogr. v.6 Bouche, J.;;Verzele, M.
  40. J. High Res. Chromatogr. v.20 Kim, B. E.;Lee, S. H.;Lee, K. P.;Park, K. S.;Park, J. H.;
  41. J. High Res. Chromatogr. v.20 Kim, B. E.;Lee, K. P.;Park, K. S.;Lee, S. H.;Park, J. H.;
  42. Chromatographia v.246 Kim, B. E.;Lee, K. P.;Park, K. S.;Lee, S. H.;Park, J. H.;
  43. J. Chromatogr. v.118 Guardino, X.;Albaiges, J.;Firpo, G.;Rodriguez, R. V.;Gassiot, M.

피인용 문헌

  1. Calixarenes as Stationary Phases in High Performance Liquid Chromatography vol.37, pp.3, 2001, https://doi.org/10.1080/10408340701244672
  2. Ionic Imprinted Calix[4]resorcinarene Host for Pb(II) Adsorbent Using Diallylaminomethyl-Calix[4]resorcinarene Copolymer vol.42, pp.10, 2001, https://doi.org/10.1246/cl.130427