Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Ab initio Study on Structures, Energies and Vibrations of Methylammonium-(water)$_n$ (n=1-3) Complexes

  • Published : 20010600
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Abstract

The reaction of [(2-N,N-dimethylaminomethyl) pheny] methylvinychlorosiane with t-BuLi in hexane solvent gave dimers, five isomeric 1,3-disilacyslobutanes which were weparated and charaterized. In trapping experiments with various trapping agents, no corresponding silene-trapping aduct was observed. We suggest that more important species for the formation of five isomeric dimers might be the zwitterionic species generated by virtue of intramolecular donor atom rather than the silene.

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