Analytical Science and Technology (분석과학)

The Korean Society of Analytical Sciences (한국분석과학회)
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Determination of bisphenol-A using GC/MS in Can Materials

기체크로마토그래피/질량분석법을 이용한 캔 물질에서의 bisphenol-A 분석

  • Kim, Ki-Cheol (Kyonggi-do Institute of Health & Environment Research) ;
  • Kim, Yang-Hee (Kyonggi-do Institute of Health & Environment Research) ;
  • Choi, Ok-Kyung (Kyonggi-do Institute of Health & Environment Research) ;
  • Ko, Hoan-Uck (Kyonggi-do Institute of Health & Environment Research) ;
  • Yim, Jun-Rae (Kyonggi-do Institute of Health & Environment Research) ;
  • Choi, Kyo-Hong (Kyonggi-do Institute of Health & Environment Research) ;
  • Cho, Hyun-Woo (Department of Chemistry, KyongGi University) ;
  • Kim, Hye-Young (Doping Control Center, Korea Institute of Science and Technology) ;
  • Kim, Myungsoo (Doping Control Center, Korea Institute of Science and Technology) ;
  • Myung, Seung-Woon (Doping Control Center, Korea Institute of Science and Technology)
  • 김기철 (경기도 보건환경연구원) ;
  • 김양희 (경기도 보건환경연구원) ;
  • 최옥경 (경기도 보건환경연구원) ;
  • 고환욱 (경기도 보건환경연구원) ;
  • 임준래 (경기도 보건환경연구원) ;
  • 조규홍 (경기도 보건환경연구원) ;
  • 조현우 (경기대학교 화학과) ;
  • 김혜영 (한국과학기술연구원 도핑콘트롤센터) ;
  • 김명수 (한국과학기술연구원 도핑콘트롤센터) ;
  • 명승운 (한국과학기술연구원 도핑콘트롤센터)
  • Received : 2001.05.14
  • Published : 2001.12.25
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Abstract

A new simple, rapid and sensitive gas chromatographic technique for the determination of bisphenol-A in can materials, which is the major material of epoxy resin and polycarbonate polymer, is proposed. This method is characterised by derivatization of the bisphenol-A with a acylating reagent forming the acetate derivative to optimize the chromatographic property. The detection of bisphenol-A is performed based on GC/MS (gas chromatography/mass spectrometry). Several beverages were analyzed by the proposed method for the determination of bisphenol-A Bisphenol-A was assayed the range of $0.11{\sim}11.40{\mu}g/can$ from the can materials.

비스페놀-A는 epoxy resin, polycarbonate, polyester-styrene resin 등의 플라스틱 제조에 사용되는 물질로써, 기체 크로마토그래피를 이용하여 간단하며 빠르고 감도 좋은 분석방법을 연구하였다. 비스페놀-A를 acylating 시약을 사용하여 크로마토그래피의 성질에 적합하도록 유도체화 한 후 SIM(selected ion monitoring) mode를 이용하여 GC/MS(gas chromatography/mass spectrometry)로 분석하였으며, 본 연구 결과 캔 물질에서 비스페놀 A는 $0.11{\sim}11.40{\mu}g/can$이 검출되었다.

Keywords

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