Changes of Volatile Odor Components in Kimchi by Freeze-drying

동결건조에 의한 김치의 휘발성냄새성분의 변화

  • Ko, Young-Tae (Department of Foods and Nutrition, Duksung Women's University) ;
  • Kang, Jung-Hwa (Department of Foods and Nutrition, Duksung Women's University)
  • 고영태 (덕성여자대학교 식품영양학과) ;
  • 강정화 (덕성여자대학교 식품영양학과)
  • Published : 2002.08.01

Abstract

Volatile odor components of ripened and ripened/freeze-dried kimchi were analyzed by gas chromatograph. As ripening temperature of kimchi increased, pH of kimchi decreased, viable cell count of lactic acid bacteria of kimchi increased up to ripening temperature of $15^{\circ}C$, and sensory properties of kimchi gradually decreased. Allyl mercaptan, methyl allyl sulfide, dimethyl disulfide, diallyl sulfide, diallyl disulfide, and ethanol were detected in ripened kimchi and ripened/freeze-dried kimchi. The amounts of allyl mercaptan, methyl allyl sulfide, diallyl sulfide, and ethanol increased as the ripening temperature increased, while those of dimethyl disulfide and diallyl disulfide decreased. Freeze-drying for 24 hr removed most of the above-mentioned volatile odor components, which were further removed by freeze-drying for 48 hr.

김치를 각각 다른 온도에서 일주일간 숙성시킨 후, 먼저 젖산균수와 관능성을 관찰하고 동결건조시킨 후, 동결건조에 의한 김치의 주요한 휘발성냄새성분의 변화를 관찰하였다. 김치의 숙성온도를 증가시킴에 따라 시료의 pH는 저하하였고 $25^{\circ}C$의 경우를 제외하고는 젖산균수는 증가하였으며, 관능적 특성은 $0^{\circ}C$의 경우는 표준시료와 차이가 없었으나, $5^{\circ}C$, $15^{\circ}C$, $25^{\circ}C$의 관능적 특성은 숙성온도가 증가함에 따라 점차 저하하였다. 본 실험에서 검출된 김치의 휘발성냄새성분은 allyl mercaptan, methyl allyl sulfide, dimethyl disulfide, diallyl sulfide, diallyl disulfide와 같은 황함유성분 5종과 ethanol이며, 이 중에서 allyl mercaptan, methyl allyl sulfide, diallyl sulfide, ethanol은 시료에 따라 차이는 있었으나 김치의 숙성온도가 증가함에 따라 생성량이 증가하였고, dimethyl disulfide와 diallyl disulfide는 숙성온도가 증가함에 따라 감소하였다. 한편 24시간 동결건조의 경우는 이상의 모든 휘발성 냄새성분이 현저하게 감소하였으며 48시간 동결건조에 의하여 시료에 따라서는 24시간과 거의 같거나 24시간보다 더 감소하였다.

Keywords

References

  1. Jo, J.S. Studies on Kimchi, pp. 261-339. Yurim-munhwasa, Seoul(2000)
  2. Kim, M.H. and Chang, M.J. Influence of organic acid or ester addition on kimchi fermentation. Foods and Biotechnol. 4: 146-149 (1995)
  3. Cho, S.Y, Lee, I.S., Yoo, J.Y, Chung, K.S. and Koo, Y.J. Inhibi-tory effect of nisin upon kimchi fennentation. Korean J. Appl. Microbiol. Biotechnol. 18: 620-623 (1990)
  4. Moon, K.D., Byun, J.A., Kim, S.J. and Han, D.S. Screening of natural preservatives to inhibit kimchi fermentation. Korean J.Food Sci. Technol. 27: 257-263 (1995)
  5. Ryu, H.J., Chung, C.H. and Kyung, K.H. Evaluation of nisin as a preservative to prevent over-acidification of kimchi. Food Sci Biotechnol. 7: 205-208 (1998)
  6. Kim, S.J. and Park, K.H. Retardation of kimchi fermentation by the extracts of Allium tuberosum and growth inhibition of related microorganisms. Korean J. Food Sci. Technol. 27: 813-818 (1995)
  7. Yun S.I. Method to increase preservation of kimchi by addition of cinnamon oil. Korean Patent 1002 (1990)
  8. Chung, D.K. and Yu, R. Antimicrobial activity of bamboo leaves extract on microorganisms related to kimchi fermentation. Korean J. Food Sci. Technol. 27: 1035-1038 (1995)
  9. Lee, S.H., Choi, W.J. and Im, Y.S. Effect of Scizandra chinensis (Omija) extract on the fermentation of kimchi. Korean J. Appl. Microbiol Biotechnol. 25: 229-234 (1997)
  10. Ahn S.C. and Lee. G.J. Effects of salt-fermented fish and chito-san addition on the pectic substance and the texture changes of kimchi during fermentation. Korean J. Soc. Food Sci. 11: 309-315(1995)
  11. Son, Y.M., Kim, K.O., Jeon, D.W. and Kyung, K.H. The effect of low molecular chitosan with or without other preservatives on the characteristics of kimchi during fermentation. Korean J. Food Sci.Technol. 28: 888-896(1996)
  12. Kim, K.O., Moon, H.A. and Jeon, D.W. The effect of low molec-ular weight chitosans on the characteristics of kimchi during fer-mentation. Korean J. Food Sci. Technol. 27: 420-427(1995)
  13. Park, K.H., Seo, B.C., Han, J.S. and Na, S.I. Method to prolong ripening of kimchi by addition of glucono-delta-lactone. Korean Patent 3501(1993)
  14. An D.J., Lew, K.C. and Lee, K.P. Effects of adipic acid and stor-age temperature on extending the shelf-life of kimchi. Food Sci. Biotechnol. 8: 78-82 (1999)
  15. Lee, C.Y, Kim, H.S. and Chun, J.K. Studies on the manufacture of canned kimchi. J, Korean Agri. Chem. Soc. 10: 33-38 (1968)
  16. Kim, C.S., Kim, J.H. and Jung, M.H. Method of preparation of kimchi can. Korean Patent 850 (1966)
  17. Lee N.J. and Chun, J.K. Studies on the kimchi pasteurization. Part II. Effects of kimchi pasteurization conditions on the shelf-life of kimchi. J. Korean Agri. Chem. Soc. 25: 197-200 (1982)
  18. Park K..H., An, S.Y. and Yook, C. Method to prevent deteriora-tion of kimchi by pre-heat treatment. Korean Patent 22 (1987)
  19. Cha, B.S., Kim, W.J., Byun, M.W., Kwon, J.H. and Cho, H.O. Evaluation of gamma irradation for extending the shelf life of kimchi. Korean J. Food Sci. Technol. 21: 109-119 (1989)
  20. Byun, M.W., Cha, B.S. Kwon, J.H., Cho, H.O. and Kim, W.J. The combined effect of heat treatment and irradiation on the inactivation of major lactic acid bacteria associated with kimchi fermentation. Korean J. Food Sci. Technol. 21: 185-191 (1989)
  21. Byun, M.W. and Kwon, J.H. Method of long term storage of Chinese cabbage kimchi. Korean Patent 5282 (1991)
  22. Ko, Y.T, Kang, J.H. and Kim, T.E. Quality of freeze dried kim-chi. Korean J. Food Sci. Technol. 33: 100-106 (2001)
  23. Hawer, W.D. Study of changes in Havor components in Korean cabbage kimchi during fermentation, pp. 175-190. In: Science of Kimchi. Symposium of Korean Soc. of Food Sci. Technol., Seoul(1994)
  24. Hawer, W.D., Ha, J.H., Seog, H.M., Nam, Y.J., and Shin, D.W. Changes in the taste and flavor compounds of kimchi during fer-mentation. Korean J. Food Sci. Technol. 20: 511-517 (1988)
  25. Larmond, E. Laboratory Methods for Sensory Evaluation of Food Canada Department of Agriculture, Ottawa, Canada (1997)
  26. Ko, Y.T, Kim, T.E. and Kang, J.H. Volatile aroma compounds inice cream prepared from lactic fermented egg white food addedwith cream. Korean J. Food Sci. Technol. 33: 373-377 (2001)
  27. Jandel Co. SigmaStat for Windows. V 1.02, Jandel Co., USA(1994)