Quality Evaluation of Dried Laver (Porphyra yezoensis Ueda) Using Electronic Nose Based on Metal Oxide Sensor or GC with SAW Sensor During Storage

Metal oxide 센서를 바탕으로한 전자코와 SAW 센서를 바탕으로한 GC를 이용한 저장 중 김의 품질 평가

  • Cho, Yen-Soo (Department of Foods and Microbial Technology, Seoul Women's University) ;
  • Noh, Bong-Soo (Department of Foods and Microbial Technology, Seoul Women's University)
  • 조연수 (서울여자대학교 식품.미생물 공학과) ;
  • 노봉수 (서울여자대학교 식품.미생물 공학과)
  • Published : 2002.12.01

Abstract

Two types of electronic nose were used for investigating the quality of dried lavers stored at 5, 15, and $30^{\circ}C$ RH of 32, 43, and 75%. The electronic nose is composed of metal oxide sensors, and GC is based on SAW sensor. Quality change in dried lavers was described in terms of the sensitivities $(R_{gas}/R_{air})$ of the sensors. Principal component analysis (PCA) was carried out using data obtained from six metal oxide sensors. The first principal component scores were correlated with quality changes of dried lavers. As storage time increased, the stored laver cluster separated from that of fresh lavers. A chromatogram was obtained from GC based on SAW sensor. Olfactory image, A $VaporPrint^{TM}$ image for pattern recognition, showed a significant difference between the stored and the fresh samples. Dried lavers during storage at $30^{\circ}C$ and 75% had bacterial counts of $5.7{\times}10^6\;CFU/g$ after 8 day. Increase of microbial count correlated with the response of electronic nose $(r^2=0.87)$. Whereas, color values showed no correlation.

시중에서 판매되는 김을 구입하여 습도가 32%, 43%, 75%, 온도는 $5^{\circ}C,\;15^{\circ}C,\;30^{\circ}C$에서 각각 김을 보관 한 후 저장 기간에 따른 김의 품질변화를 metal oxide 센서로 구성된 전자코와 SAW 센서를 바탕으로한 GC(z-Nose)를 이용하여 측정하였다. PCA 분석결과, $5^{\circ}C$, 32%에서 보관한 김의 경우는 저장기간이 지나도 김의 품질변화가 거의 없었다. 이것은 온도와 습도가 모두 낮아 김의 품질변화에는 영향을 미치지 않았으며, RH 43%, RH 75%에서 보관한 김의 경우는 저장기간이 지날수록 제 1 주성분 값이 양의 값$(+0.2{\sim}0.4})$에서 음의 값$(-0.4{\sim}\;-0.2)$으로 변화하는 경향으로 나타났다. RH 43% 보다 75%의 경우가 더 뚜렷한 감소를 보였으며 높은 상대습도 조건에서는 $15^{\circ}C$$30^{\circ}C$에서 유사한 경향을 나타내었다. z-Nose로 얻은 데이터를 패턴 분석한 결과 저장 기간이 지나면서 저장 온도와 습도에 따라 변질된 향시성분의 차이를 보여주었다. 이것은 미생물 수를 측정할 때와 마찬가지의 결과$(r^2=0.87)$를 보였으며 색도와는 크게 영향이 없음을 알 수 있었다. 이것으로 보면 전자코를 이용하여 조건을 달리하여 보관한 김의 품질관리를 효과적임을 알 수 있었다.

Keywords

References

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