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Characterization of Oxide Scales Formed on Ni3Al-7.8%Cr-1.3%Zr-0.8%Mo-0.025%B

Ni3Al-7.8%Cr-1.3%Zr-0.8%Mo-0.025%B 합금의 고온산화막분석

  • Kim, Gi-Yeong (Center for Advanced Plasma Surface Technology, Sungkyunkwan Uiversity) ;
  • Lee, Dong-Bok (Center for Advanced Plasma Surface Technology, Sungkyunkwan Uiversity)
  • 김기영 (성균관대학교 플라즈마 응용 표면기술 연구센터) ;
  • 이동복 (성균관대학교 플라즈마 응용 표면기술 연구센터)
  • Published : 2002.03.01

Abstract

The oxide scales formed on $Ni_3Al$-7.8%Cr-1.3%Zr-0.8%Mo-0.025%B after oxidation at 900, 1000 and 110$0^{\circ}C$ in air were studied using XRD, SEM, EPMA and TEM. The oxide scales consisted primarily of $NiO,\; NiAl_2O_4,\;{\alpha}-Al_2O_3,\; monoclinic-ZrO_2,\; and \;tetragonal-ZrO_2$. The outer layer of the oxide scale was rich in Ni-oxides, whereas the internal oxide stringers were rich in Al-oxides and $ZrO_2$. Within the above oxide scales, Cr and Mo tended to exist as dissolved ions.

Keywords

References

  1. S.C. Deevi and V.K. Sikka, Intermetallics, 4, 357 (1996) https://doi.org/10.1016/0966-9795(95)00056-9
  2. C.T. Liu and K.S. Kumar, JOM, 45(5), 38 (1993) https://doi.org/10.1007/BF03223218
  3. Y.C. Pan, T.H. Chuang and Y.D. Yao, J. Mater. Sci., 26, 6097 (1991) https://doi.org/10.1007/BF01113890
  4. T.T. Chang, Y.C. Pan and T.H. Chuang, J. Alloys Comp., 243, 126 (1996) https://doi.org/10.1016/S0925-8388(96)02370-5
  5. J. Klower, U. Brill and U. Heubner, Inermetallics, 7, 1183 (1999) https://doi.org/10.1016/S0966-9795(99)00042-4
  6. S. Taniguchi and T. Shibata, in Oxidation of high-cemperature intermetallics (eds., T. Grobstein and J. Doychak), p. 17, TMS, Warrendale, PA, (1988)
  7. S. Ochiai, Y. Oya and T. Suzuki : Acta Metall., 32, (1984) 289 https://doi.org/10.1016/0001-6160(84)90057-9
  8. S.C. Choi, H.J. Cho, Y.J. Kim and D.B. Lee, Oxid. Met., 46, 51 (1996) https://doi.org/10.1007/BF01046884
  9. G.H. Meier, N. Birks, F.S. Pettit and R.A. Perkins, in Structural Intermetallics (eds., R. Darolia, J.J. Lewandowski, C.T. Liu, P.L. Martin, D.B. Mirade and M. V. Nathal), p. 861, TMS, Warrendale, PA, (1993)