Journal of Powder Materials (한국분말재료학회지)

The Korean Powder Metallurgy & Materials Institute (한국분말재료학회 (*구 분말야금학회))
권호 표지
DOI QR코드

DOI QR Code

Improvement of Mg-based Hydrogen Storage Alloys by Mechanochemical Ball Milling

기계화학적 볼밀링을 이용한 Mg 합금의 수소저장능 향상 연구

  • 안중호 (안동대학교 신소재공학부) ;
  • 최영묵 (안동대학교 신소재공학부)
  • Published : 2002.04.01
Download PDF
⟨ Previous Next ⟩

Abstract

The mechanochemical milling of Mg and $Mg_2Ni$ alloys were carried out to examine the enhancement of hydrogen storage properties of Mg alloys. The hydroge characteristics of the ball-milled products were evaluated with a Sievert-type apparatus and electrochemical test. Various intermediate compounds were obtained by chemical reactions induced during the ball milling of Mg of $Mg_2Ni$ alloys with C, Ni, $Ni_2Cl$ and $Ca_2Cl$. The system of $Mg_2Ni$ with 10 wt% C improved markedly the kinetics of hydrogen absorption, while the hydrogen capacities were practically unchanged. The hydrogen storage alloys such as Mg-Ca can be successfully.

Keywords

References

  1. Inorg. Chem. v.6 J. J. Reiley;R. H. Wiswall https://doi.org/10.1021/ic50058a020
  2. Fortschr. Ber. v.5 G. Friedlmeier
  3. Electrochem. Acta v.46 C. Iwakura;R. Shinya;K. Miyanohara;S. Nohara;H. Inoue https://doi.org/10.1016/S0013-4686(01)00513-8
  4. Int. Hydrogen Energy v.19 J. C. Bolcich;A. A. Yawuy;H. L. Corso;H. A. Perti;C. O. Anala https://doi.org/10.1016/0360-3199(94)90219-4
  5. Z. Phys. Chem. v.183 Y. Q. Lei;Y. M. Wu;Q. M. Yang;Q. D. Wang https://doi.org/10.1524/zpch.1994.183.Part_1_2.379
  6. J. Alloys Comp. v.231 D. L. Sun;Y. Q. Lei;W. H. Liu;J. J. Jiang;J. Wu;Q. D. Wang https://doi.org/10.1016/0925-8388(95)01739-9
  7. Chem. Commun. C. Iwakura;S. Nohara;H. Inoue;Y. Fukumoto
  8. J. Alloys Comp. v.259 S. Nohara;H. Inoue;Y. Fukumoto;C. Iwakura https://doi.org/10.1016/S0925-8388(97)00051-0
  9. J. Alloys Comp. v.217 L. Zaluski;A. Zaluska;J. I. Strom-Olsen https://doi.org/10.1016/0925-8388(94)01348-9
  10. J. Power Sources v.55 N. Cui;B. Luan;H. K. Liu;H. J. Zao;S. X. Dou https://doi.org/10.1016/0378-7753(95)02195-M
  11. J. Alloys Comp. v.240 N. Cui;B. Luan;J. Zhao;H. K. Liu;H. J. Zao;S. X. Dou https://doi.org/10.1016/0925-8388(96)02298-0
  12. J. Alloys Comp. v.232 S. Orimo;H. Fujii https://doi.org/10.1016/0925-8388(95)02079-9
  13. Acta Mater. v.45 S. Orimo;K. Ikeda;H. Fujii;Y. Fujukawa;Y. Kitano;Y. Yamamoto https://doi.org/10.1016/S1359-6454(96)00357-6
  14. J. Electrochem., Soc, v.143 T. Kohno;S. Tsuruta;K. Kanda https://doi.org/10.1149/1.1837085
  15. J. Electrochem. Sic. v.146 J. H. Woo;K. S. Lee https://doi.org/10.1149/1.1391687
  16. J. Electrochem., Acta v.43 H. Inoue;T. Ueda;S. Nohara;N. Fujita;C. Iwakura https://doi.org/10.1016/S0013-4686(97)10110-4