Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
권호 표지
DOI QR코드

DOI QR Code

Preparation Method of Spherical 0.9PMN-0.1PT Powder

구형의 PMN-PT 분말 제조 방법

  • 임경란 (한국과학기술연구원 재료연구부) ;
  • 정순용 (한국과학기술연구원 재료연구부) ;
  • 김창삼 (한국과학기술연구원 재료연구부)
  • Published : 2002.07.01
Download PDF
⟨ Previous Next ⟩

Abstract

Preparation of spherical single-perovskite phase PMN-PT powder was tried by surface modification of the precursor powder with magnesia sol. The ball-milled mixed powder was heat treated at 550$\^{C}$/l h to remove any volatiles. The calcined powder was treated with the magnesia sol of 0.3-1.0 wt% and followed by calcination at 800$\^{C}$/l h to give rise to single phase perovskite PMN-PT powders. The powder with a binary size of <0.3 ㎛ and -2 ㎛ was obtained for MgO(0.3), but the spherical, agglomerate-free powder of 0.5-0.8 ㎛ was obtained for MgO(0.6) as well as for MgO(1.0).

단일상 페로브스카이트 PMN-PT 분말 합성 과정에서 전구체 분말의 표면을 소량의 magnesia 졸로 코팅하여 구형의 분말을 제조하고자 시도하였다. 질량 감소가 더 이상 발생하지 않도록 정량의 혼합 분말을 55$0^{\circ}C$/lh 열처리하여 얻은 전구체 분말을 0.3-1.0wt% MgO에 해당하는 magnesia졸과 혼합한 후 80$0^{\circ}C$/lh 하소하여 페로브스카이트 단일상 PMN-PT 분말을 얻었다. MgO(0.3)일 경우는 <0.3$\mu\textrm{m}$와~2$\mu\textrm{m}$의 두 종류 크기의 분말로 나타나나, MgO(0.6)과 MgO(1.0)의 경우는 0.5-0.8$\mu\textrm{m}$의 구형 분말을 응집없이 얻을 수 있었다.

Keywords

References

  1. Ferroelectrics v.76 Relaxor Ferroelectrics L. E. Cross https://doi.org/10.1080/00150198708016945
  2. Ferroelectrics v.41 Electrostrictive Effect in$ Pb(Mg_⅓Nb_⅔)O_3$-type Materials S. Nomura;K. Uchino https://doi.org/10.1080/00150198208210614
  3. Am. Ceram. Soc. Bull. v.65 no.4 Electrostrictive Actuator: Materials and Applications K. Uchino
  4. Mater. Res. Bull. v.17 Fabrication of Perovskite Lead Magnesium Niobate S. L. Swartz;T. R. Shrout https://doi.org/10.1016/0025-5408(82)90159-3
  5. J. Am. Ceram. Soc. v.72 no.4 Electrostrictive and Dielectric Response in Lead Magnesium Niobate-lead Titanate (0.9PMN·0.1PT) and Lead Lanthanum Zirconate Titanate (PLZT 9.5/65/35) under Variation of Temperature and Electric Field Q. Zhang;W. Pan;A. Bhalla;L. E. Cross https://doi.org/10.1111/j.1151-2916.1989.tb06181.x
  6. Ferroelectrics v.90 Electrostriction in Various Ferroelectric Ceramics with Diffuse Phase Transition V. A. Isupov;E. P. Smirnova https://doi.org/10.1080/00150198908211282
  7. J. Am. Ceram. Soc. v.73 no.4 The Role of Excess Magnesium Oxide or Lead Oxide in Determining the Microstructure and Properties of Lead Magnesium Niobate H. Wang;W. A. Schulze https://doi.org/10.1111/j.1151-2916.1990.tb05121.x
  8. J. Mater. Sci.: Materials in Electronics v.8 Multilayer Capacitor Ceramics in the PMN-PT-BT System : Effect of MgO and 4PbO·B₂O₃Addition U. Syamaprasad;A. R. Sheeja Nair;M. S. Sarma;P. Guruswamy;P. S. Mukherjee;L. Krishnamurthy;M. Achuthan;A. D. Damodaran https://doi.org/10.1023/A:1018554431950
  9. J. Am. Ceram. Soc. v.74 no.12 Synthesis and Dielectric Properties of Sol-gel-derived $0.9Pb(Mg_{1/3}Nb_{2/3})O_3$-0.1PbTiO₃Ceramics P. Ravindranathan;S. Komareni;A. S. Bhalla;R. Roy https://doi.org/10.1111/j.1151-2916.1991.tb04292.x
  10. J. Am. Ceram. Soc. v.72 no.8 Low Temperature Route to Lead Magnesium Niobate F. Chaput;J. P. Boilot;M. Lejeune;R. Papiernik;L. G. Hubert Pfalzgraf https://doi.org/10.1111/j.1151-2916.1989.tb07651.x
  11. J. Am. Ceram. Soc. v.80 no.4 Kinetic Analysis of Combustion Synthesis of Lead Magnesium Niobate from Metal Carboxylate Gels Y. Narendar;G. L. Messing https://doi.org/10.1111/j.1151-2916.1997.tb02922.x
  12. J. Am. Ceram. Soc. v.81 no.11 New Preparation Method of Low-temperature-sinterable Perovskite$ 0.9Pb(Mg_{1/3}Nb_{2/3})O_3$-0.1PbTiO₃Powder and its Dielectric Properties K. R. Han;S. Kim;H. J. Koo https://doi.org/10.1111/j.1151-2916.1998.tb02725.x
  13. J. Kor. Ceram. Soc. v.39 no.2 Preparation of PMN-PT-BT Powder by Modified Mixed Oxide Method and Effect of Ag on Dielectric Properties K. R. Han;S. Jeong;C. S. Kim https://doi.org/10.4191/KCERS.2002.39.2.159
  14. J. Am. Ceram. Soc. v.83 no.9 Novel Route to Lead-Based Ferroelectric Compounds Via Tetragonal Lead(Ⅱ) Oxide Intermediates K. R. Han;H. J. Koo;C. S. Lim https://doi.org/10.1111/j.1151-2916.2000.tb01537.x
  15. J. Kor. Ceram. Soc. v.33 no.1 Synthesis of $Pb(Mg_{1/3}Nb_{2/3})O_3$Powder by Solvent Evaporation and its Dielectric Properties J. P. Lee;J. Lee;S. Kang;H. Kim
  16. Ceram. Int. v.8 no.3 Formation Mechanism and Ceramic Process of the Ferroelectric Perovskite:$Pb(Mg_{1/3}Nb_{2/3})O_3$and $PbFe_{1/2}Nb_{1/2}O_3$ M. Lejeune;J. P. Boilot https://doi.org/10.1016/0272-8842(82)90025-6
  17. J. Mater. Chem. v.8 no.10 Synthesis and Dielectric Characterization of Lead Magnesium Niobate from Precipitation and Freeze-drying Methods W. B. Ng;J. Wang;S. C. Ng;L. M. Gan https://doi.org/10.1039/a804428g
  18. J. Am. Ceram. Soc. v.80 no.4 Synthesis of Pyrochlore-free $ 0.9Pb(Mg_{1/3}Nb_{2/3})O_3$-0.1PbTiO₃ Ceramics Via a Soft Mechno-chemical Route J. G. Baek;T. Isobe;M. Senna https://doi.org/10.1111/j.1151-2916.1997.tb02929.x
  19. J. Euro. Ceram. Soc. Direct Synthesis of PMN Samples by Spray-drying A. L. Costa;C. Galassi;E. Roncari