Membrane Journal (멤브레인)

The Membrane Society of Korea (한국막학회)
권호 표지

Development and Application of Pervaporation Membranes

투과증발막의 발전과 응용

  • 유제강 (웅진코웨이주식회사 환경기술연구소) ;
  • 임지원 (한남대학교 화학공학과) ;
  • 이영무 (한양대학교 응용화학연구부 국가지정분리막연구실) ;
  • 남상용 (경상대학교 고분자공학과)
  • Published : 2002.12.01
Download PDF
⟨ Previous Next ⟩

Abstract

Pervaporation separation is one of promising membrane technology for the energy saving processes and it has been developed to separate complex mixture systems including azeotropic mixture, close-boiling mixture, aqueous organic mixtures etc. Many researchers focused on dehydration pervaporation separation and they commercialized ethanol dehydration and isopropanol recycling processes. Nowadays, petroleum separation and volatile organic compound removal using pervaporation membranes is one of the emerging application of pervaporation separation. We reviewed the development and application of pervaporation membranes.

투과증발법은 공비혼합물 등의 분리하기 어려운 액체혼합물을 효과적으로 분리하기 위한 분리법으로 각광을 받아오고 있는 막분리공정 중의 하나이다. 수용액의 탈수에 초점을 맞추어서 발전을 거듭해온 투과 증발막의 개발은 에탄을 탈수막과 이소프로판을 탈수막의 상용화에 성공하였으며, 현재 여러 분야에서 응용이 되고 있는 공정이다. 특히 최근에 와서 석유화학공정과 휘발성유기화합물의 분리에 유용한 효과적인 막재료와 공정의 개발이 이루어지고 있다. 투과증발분리막과 공정의 발전과 그 응용분야에 관하여 서술하여 보고자 한다.

Keywords

References

  2. J. Am. Chem. Soc. v.39 Pervaporation, perstillation and percrystallization P. A. Kober https://doi.org/10.1021/ja02250a011
  3. J. Phys. Chem. v.10 On the nature of the process of osmosis and osmotic pressure with observation concerning dialysis L. Kahlenberg https://doi.org/10.1021/j150075a001
  4. Pet. Eng. v.30 Permeation. A new commercial separation tool R. C. Binning;F. E. James
  5. Ind. Eng. Chem. v.53 Separation of liquid mixtures by permeation R. C. Binning;R. J. Lee;J. F. Jennings;E. C. Martin
  6. U.S. Patent 3,035,060 Removal of water from or ganic chemicals R. C. Binning;J. F. Jennings;E. C. Martin
  7. Lavoisier Technique & Documentation Pervaporation J. Neel
  8. Research Needs Assessment Group v.Ⅱ Membrane Spearation Systems - A research & development needs assessment, department of energy membrane separation systems R. Baker
  9. Ind. Eng. Chem. Res. v.36 Liquid separation by membrane pervaporation: A review X. Feng;R. Y. M. Huang https://doi.org/10.1021/ie960189g
  10. J. Polym. Eng. v.18 no.1-2 Pervaporation of water-alcohol mxitures through chitosan composite membranes S. Y. Nam;D. J. Woo;Y. M. Lee
  11. J. Mem. Sci. v.113 Pervaporation of ionically surface crosslinked chitosan composite membranes for water-alcohol separation Y. M. Lee;S. Y. Nam;D. J. Woo
  12. J. Appl. Polym. Sci. v.72 no.2 Pervaporation separation of water/isopropanol mixtures through carboxymethylated poly(vinyl alcohol) composite membranes S. Y. Nam;H. J. Chun;Y. M. Lee https://doi.org/10.1002/(SICI)1097-4628(19990411)72:2<241::AID-APP9>3.0.CO;2-B
  13. J. Mem. Sci. v.61 Influence of composite membrane structure on pervaporation W. Gudernatsch;Th. Menzel;H. Strathmann https://doi.org/10.1016/0376-7388(91)80003-O
  14. J. Separation of gaseous mixtures using polymer membranes W. J. Koros;R. T. Chen;R.W. Rousseau(ed.)
  15. J. Mem. Sci. v.22 Preferential sorption versus preferential permeability in pervaporation M. H. V. Mulder;C. A. Smolders https://doi.org/10.1016/S0376-7388(00)81277-6
  16. J. Mem. Sci. v.23 On the mechanism of separation of ethanol/water mixtures by pervaporation Ⅱ. Experimental concentration profiles M. H. V. Mulder;C. A. Smolders https://doi.org/10.1016/S0376-7388(00)83133-6
  17. Sep. Puri. Method v.15 Pervaporation solubility aspects of the solution-diffusion model M. H. V. Mulder;C. A. Smolders
  18. Sep. Sci. & Tech. v.26 Mass transport phenomena in pervaporation processes M. H. V. Mulder;C. A. Smolders https://doi.org/10.1080/01496399108050458
  19. Ind. Eng. Chem. Res. v.31 Solubility and pervaporation properties of the filling-polymerized membrane prepared by plasma-graft polymerization for pervaporation of organic-liquid mixtures T. Yamaguchi;S. Nakao;S. Kimura https://doi.org/10.1021/ie00008a012
  20. J. Mem. Sci. v.44 Sorption, diffusion and pervaporation of organics in polymer membranes Y. M. Lee;D. Bourgeois;G. Belfort https://doi.org/10.1016/S0376-7388(00)83350-5
  21. National Research Council Canada Reverse Osmosis/Ultrafiltration Processes Principles S. Sourirajian;T. Matsuura
  22. J. Mem. Sci. v.78 Study of interaction between butyl alcohols and cellulose-acetate polymers with reverse osmosis, high pressure liquid chromatography and pervaporation method T. Balint;E. Nagy;M. Kraxner https://doi.org/10.1016/0376-7388(93)85252-R
  23. AlChE Symp. Ser. v.85 no.272 Pervaporation as an attractive process for the separation of methanol from C4 hydrocarbons in the production of MTBE and TAME B. A. Farnand;S. H. Noh
  24. Pervaporation Membrane Separation Processes Synthesis of novel copolymer membranes for pervaporation T. Shimidzu;M. Yoshokawa;R.Y.M. Huang(Ed.)
  25. 2nd Ed. Synthetic polymeric membranes- a structural perspective R. E. Kesting
  26. J. Mem. Sci. v.159 Pervaporation of water-isopropanol mixtures through polyaniline membranes doped with poly(acrylic acid) Y. M. Lee;S. Y. Nam;S. Y. Ha https://doi.org/10.1016/S0376-7388(99)00051-4
  27. J. Mem. Sci. v.153 Pervaporation of ethylene glycol-water mixtures Ⅰ. Pervaporation performance of surface crosslinked chitosan membranes S. Y. Nam;Y. M. Lee https://doi.org/10.1016/S0376-7388(98)00263-4
  28. J. Mem. Sci. v.102 Separation of glycol and water from coolant liquid by evaporation, reverse osmosis and pervaporation W. Jehle;Th. Staneff;B. Wagner;J. Steinwandel https://doi.org/10.1016/0376-7388(94)00202-A
  29. PhD Dissertation Preparation and permeation mechanism of zeolite membrane I. Kumakiri
  30. J. Mem. Sci. v.135 Pervaporation and properties of chitosan-poly (acrylic acid) complex membranes S. Y. Nam;Y. M. Lee https://doi.org/10.1016/S0376-7388(97)00144-0
  31. J. Mem. Sci. v.95 Preparation of pervaporation membranes for removal of dissolved organics from water by plasma-graft filling polymerization T. Yamaguchi;S. Yamahara;S. Nakao;S. Kimura https://doi.org/10.1016/0376-7388(94)85027-5
  32. J. Mem. Sci. v.164 Design of a vapor permeation membrane for VOC removal by the filling membrane concept B. G. Wang;Y. Miyazaki;T. Yamaguchi;S. Nakao https://doi.org/10.1016/S0376-7388(99)00193-3
  33. Environmental Science & Technology News MTBE; To what extent will past releases contaminate community water supply wells? R. Johnson
  34. Sep. Introduction to membrane processes in environmental technology M. H. V. Mulder
  35. J. Mem. Sci. v.157 Pervaporation separation of methanol/methyl t-butyl ether through chitosan composite membranes modified with surfactants S. Y. Nam;Y. M. Lee https://doi.org/10.1016/S0376-7388(98)00368-8
  36. PhD Thesis Separation of alcohols from organic liquid mixtures by pervaporation H. C. Park
  37. Proceedings of the 5th International Conference on Pervaporation Processes in the Chemical Industry Pervaporation aided esterification: Alternative in plant extension for an existing chemical process A. Dams;J. Krug