DOI QR코드

DOI QR Code

폴리이미드/TiO2 나노복합재의 합성과 물성 연구

A study on the Synthesis and Characterization of Polyimide/TiO2 Nanocomposite

  • 이봉신 (전북대학교 신소재공학부) ;
  • 이중희 (전북대학교 신소재공학부) ;
  • 김인택 (전북대학교 신소재공학부) ;
  • 이명훈 (전북대학교 신소재공학부) ;
  • 나창운 (전북대학교 신소재공학부)
  • 발행 : 2002.12.01

초록

Organic/inorganic hybrid materials have rapidly become a fascinating research field. In this study, $polyimide/TiO_2$ composites were synthesized from nano-sized anatase $TiO_2$ and two types of polyimide, that is, BPDA-PPD and PMDA-ODA. Nano-sized $TiO_2$ particles were prepared from $TiOEt_4$ solution by the sol-gel method. The synthesized PI/$TiO_2$ composites were characterized by using XRD, TGA, FT-IR, TEM, and Atomic Force Microscope(AFM). $TiO_2$ particles were dispersed well in polyimides and the mechanical and thermal stability of polyimide was improved with $TiO_2$ nano particles.

키워드

참고문헌

  1. Lee, Y. T., 1993, 'Preparation of Specialty Organic-lnorganic Materials by Sol-Gel Process,' Polymer Science and Technology, Vol. 4, No. 6, pp. 444-451
  2. Polymer Science and Technology v.10 no.4 Clay-Dispersed Polymer Nanocomposites Ko, M. B.;Kim, J. K.
  3. Ko, M. B. and Kim, J. K., 1999, 'Clay-Dispersed Polymer Nanocomposites,' Polymer Science and Technology, Vol. 10, No. 4, pp. 451-464
  4. Lee, C. U., Bae, K. S., Choi, H. K., Lee, J. H. and Sur, G. S., 2000, 'A Study on the Prepatation of Polyimide/Clay Nanocomposites,' Polymer (Korea), Vol. 24, No. 2, pp. 228-236
  5. Lee, Y. T., 1993, 'Preparation of Specialty Organic-Inorganic Materials by Sol-Gel Process,' Polymer Science and Technology, Vol. 4, No. 6, pp. 444-451
  6. Krug, H. and Schmidt, S., 1994, 'Organic-Inorganic Nanocomposites for Micro Optical Applications,' New Journal of Chemistry, Vol. 18, No. 10, pp. 1125-1134
  7. Hedrick, J. L., DiPietro, R., Plummer, C. J. G., Hilborn, J. and Jerome, R., 1996, 'Polyimide Foams Derived from a High$T_g$Polyimide with Grafted Poly(${\alpha}-methylstyrene$),' Polymer, Vol. 37, No. 23, pp. 5229-5236 https://doi.org/10.1016/0032-3861(96)00331-X
  8. Girardeaux, C., Druet, E., Demoncy, P. and Delamar, M., 1995, 'The Polymide(PMDA-ODA) Titanium Interface. Part 2. XPS Study of Polyimide Treatments and Ageing,' Journal of Electron Spectroscopy and Related Phenomena, Vol. 74, No. 1, pp. 57-66 https://doi.org/10.1016/0368-2048(95)02351-8
  9. Caulfield M. J. and Solomon, D. H., 1999, 'Studies on Polyimides: Part 3. Interactions between Hexamethy lenetetramine and Models for Polyimides and Novolacs,' Polymer, Vol. 40, No. 11, pp. 3041-0350 https://doi.org/10.1016/S0032-3861(98)00382-6
  10. Delozier, D.M., Orwoll, F. F., Cahoon, J.F., Johnston, J.R., Smith Jr, J.G., Connell, J.W., 2002, 'Preparation and Characterization of Polyimde/Organoclay Nanocomposites,' Polymer, Vol. 43, No. 3, pp. 813-822 https://doi.org/10.1016/S0032-3861(01)00640-1
  11. Liu, X., Yang, J., Wang, L., Yahng, X., Lu, L., and Wang, X., 2000, 'An Improvement on Sol-gel Method for Preparing Ultrafine and Crystallized Titania Powder,' Material Science & Engineering, A. Vol. 289, No. 1-2, pp. 241-245 https://doi.org/10.1016/S0921-5093(00)00901-1
  12. Zhang, Q., Gao, L., and Guo, J., 2000, 'Effect of Hydrolysis Consitions on Morphology and Crystallization of Nanosized TiO2 Powder,' Journal of the European Ceramic Society, Vol. 20, No. 12, pp. 2153-2158 https://doi.org/10.1016/S0955-2219(00)00085-6
  13. Seo, D. S., Lee, J. K., You, H. K., and Kim, H., 2001, 'Preparation of $TiO_2$ Nanocrystalline Powder at Low Temperature,' Journal of the Korean Ceramic Society, Vol. 38, No. 4, pp. 331-336