Macromolecular Research

The Polymer Society of Korea (한국고분자학회)
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Sulfonated Polystyrene Ionomers Containing 4-Aminobenzoic Acid Studied by a Small-Angle X-Ray Scattering Technique

  • Song, Ju-Myung (Department of Polymer Science & Chosun University) ;
  • Hong, Min-Chul (Department of Polymer Science & Chosun University) ;
  • Kim, Joon-Seop (Department of Polymer Science & Chosun University) ;
  • Jikang Yoo (Department of Polymer Science & Chosun University) ;
  • Yu, Jeong-A (Department of Science Education, Chosun University) ;
  • Kim, Whangi (Department of Applied Chemistry, Konkuk University)
  • Published : 2002.12.01
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Abstract

In a recent study by the same authors using a DMTA (Dynamic Mechanical Thermal Analyzer), it was found that the 4-aminobenzoic arid (ABA) molecules acted as either a neutralizing agent, or a plasticizer, or a filler, depending on the order of mixing of poly(styrene-co-styrenesulfonic acid) (PSSA), ABA, and NaOH. Subsequent to that study, we here pursued the same topic, i.e., the effect of the addition of CsOH (instead of NaOH) and ABA on the morphology of PSSA, but this time, by using a small-angle X-ray scattering (SAXS) technique. In line with the previous results, the present study with the SAXS technique verified that the order of mixing has a significant effect on the morphology of ionomers. In addition, with the SAXS data and the density values of the ionomers, we attempted to calculate both the number of sulfonate ionic groups per multiplet and the size of the multiplet of the ionomer.

Keywords

References

  1. Ionomers: Characterization, Theory, and Applications S. Schlick
  2. Ionomers: Synthesis, Structure, Properties and Application M. R. Tant;K. A. Mauritz;G. L. Wilkes
  3. Introduction to Ionomers A. Eisenberg;J. -S. Kim
  4. Macromolecules v.23 A. Eisenberg;B. Hird;R. B. Moore https://doi.org/10.1021/ma00220a012
  5. Macromolecules v.3 A. Eisenberg https://doi.org/10.1021/ma60014a006
  6. Macromolecules v.16 D. J. Yarusso;S. L. Cooper https://doi.org/10.1021/ma00246a013
  7. Macromolecules v.24 R. B. Moore;m. Bittencourt;M. Gauthier;C. E. Williams;A. Eisenberg https://doi.org/10.1021/ma00006a024
  8. J. Polym. Sci v.45 W. J. MacKnight;W. P. Taggert;R. S. Stein
  9. J. Polym. Sci., Polym. Phys. Ed. v.20 D. G. Peiffer;R. A. Weiss;R. D. Lundberg https://doi.org/10.1002/pol.1982.180200815
  10. Polymer v.26 D. J. Yarusso;S. L. Cooper https://doi.org/10.1016/0032-3861(85)90196-X
  11. J. Polym. Sci., Polym. Lett. v.24 J. J. Fizgerald;D. Kim;R. A. Weiss
  12. Polymer v.27 R. A. Weiss;J. A. Lefelar https://doi.org/10.1016/0032-3861(86)90349-6
  13. Macromolecules v.20 A. F. Galambos;W. B. Stockton;J. T. Koberstein;A. Sen;R. A. Weiss;T. P. Russell https://doi.org/10.1021/ma00178a028
  14. Macromolecules v.21 Y. S. Ding;S. R. Hubbard;K. O. Hodgson;R. A. Register;S. L. Cooper https://doi.org/10.1021/ma00184a028
  15. Macromolecules v.22 R. A. Register;A. Sen;R. A. Weiss;S. L. Cooper https://doi.org/10.1021/ma00195a040
  16. Macromolecules v.23 R. A. Register;S. L. Cooper https://doi.org/10.1021/ma00203a053
  17. Macromolecules v.25 R. B. Moore;M. Gauthier;C. E. Williams;A. Eisenberg https://doi.org/10.1021/ma00047a031
  18. Macromolecules v.26 B. Chu;D. Q. Wu;R. D. Lundberg;W. J. MacKnight https://doi.org/10.1021/ma00057a018
  19. Macromolecules v.26 D. Q. Wu;B. Chu;R. D. Lundberg;W. J. MacKnight https://doi.org/10.1021/ma00057a019
  20. Macromolecules v.26 J. Wang;Y. Li;D. G. PeifferB. Chu; https://doi.org/10.1021/ma00062a039
  21. Macromolecules v.26 Y. Li;D. G. PeifferB. Chu https://doi.org/10.1021/ma00067a042
  22. Macromolecules v.26 M. Jiang;A. A. Gronowski;H. L. Yeager;G. Wu;J. -S. Kim;A. Eisenberg
  23. J. Appl. Polym. Sci v.29 R. A. Weiss;P. K. Agarwal;R. D. Lundberg
  24. J. Polym. Sci., Polym. Phys v.26 P. Smith;A. Eisenberg https://doi.org/10.1002/polb.1988.090260309
  25. Macromolecules v.28 X. D. Fan;C. G. Bazuin https://doi.org/10.1021/ma00128a035
  26. Polym. Bull. v.41 H.-S. Kim;Y.-H. Nah;J.-S. Kim;J.-A Yu;Y. Lee https://doi.org/10.1007/s002890050403
  27. US Patent 870 841 H. S. Makowski;R. D. Lundberg;G. L. Singhal
  28. Macromol. Res v.10 J. Bolze;J. Kim;J.-Y Huang;S. Rah;H. S. Yoon;B. Lee;T. J. Shin;M. Ree https://doi.org/10.1007/BF03218282
  29. A Johnson Matthey Companys Alfa Aesar Catalog for Research Chemicals, Metals, and Materials
  30. Physical Properties of Polymers, American Chemical Society J. E. Mark;A. Eisenberg;W. W. Graessley;L. Mandelkern;E. T. Samulski;J. L. Koenig;G. D. Wignall
  31. Polymer Handbook J. Brandrup;E. H. Immergut;E. A. Grulkr
  32. Macromolecules v.25 B. Hird;A. Eisenberg https://doi.org/10.1021/ma00050a013
  33. Handbook of Chemistry and Physics 78th Ed. D. R. Ride (Ed.)
  34. J. Polys. Sci., Polym. Phys v.33 J. -S. Kim;A. Eisenberg https://doi.org/10.1002/polb.1995.090330205