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Characteristics of the SrBi2Nb2O9 Thin Films Deposited by RF Magnetron Sputtering with Controlling of Bi Contents

RF마그네트론 스퍼터링 법에 의해 증착된 SrBi2Nb2O9 박막의 Bi 량의 조절에 따른 특성분석

  • Lee, Jong-Han (Department of Material Science & Engineering, Korea University) ;
  • Choi, Hoon-Sang (Department of Material Science & Engineering, Korea University) ;
  • Sung, Hyun-Ju (Department of Material Science & Engineering, Korea University) ;
  • Lim, Geun-Sik (Department of Material Science & Engineering, Korea University) ;
  • Kwon, Young-Suk (Department of Material Science & Engineering, Korea University) ;
  • Choi, In-Hoon (Department of Material Science & Engineering, Korea University) ;
  • Son, Chang-Sik (Department of Photoelectronics Engineering, Silla University)
  • 이종한 (고려대학교 재료공학과) ;
  • 최훈상 (고려대학교 재료공학과) ;
  • 성현주 (고려대학교 재료공학과) ;
  • 임근식 (고려대학교 재료공학과) ;
  • 권영석 (고려대학교 재료공학과) ;
  • 최인훈 (고려대학교 재료공학과) ;
  • 손창식 (신라대학교 광전자공학과)
  • Published : 2002.12.01

Abstract

The $SrBi_2$$Nb_2$$O_{9}$ (SBN) thin films were deposited with $SrNb_2$$O_{6}$ / (SNO) and $Bi_2$$O_3$ targets by co-sputtering method. For the growth of SBN thin films, we adopted the various power ratios of two targets; the power ratios of the SNO target to $Bi_2$$O_3$ target were 100 W : 20 W, 100 W : 25 W, and 100 W : 30 W during sputtering the SBN films. We found that the electrical properties of SBN films were greatly dependent on Bi content in films. The $Bi_2$Pt and $Bi_2$$O_3$ phase as second phases occurred at the films with excess Bi content greater than 2.4, resulting in poor ferroelectric properties. The best growth condition of the SBN films was obtained at the power ratio of 100 W : 25 W for the two targets. At this condition, the crystallinity and electrical properties of the films were improved at even low annealing temperature as $700^{\circ}C$ for 1h in oxygen ambient and the Sr, Bi and Nb component in the SBN films were about 0.9, 2.4, and 1.8 respectively. From the P-E and I-V curves for the specimen, the remnant polarization value ($2P_{r}$) of the SBN films was obtained about 6 $\mu$C/c $m^2$ at 250 kV/cm and the leakage current density of this thin film was $2.45$\times$10^{-7}$ $A/cm^2$ at an applied voltage of 3 V.V.

Keywords

References

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