A study on the fabrication of poly crystalline Si wafer by vacuum casting method and the measurement of the efficiency of solar cell

  • Published : 2002.06.01

Abstract

Si-wafers for solar cells were cast in a size of $50{\times}46{\times}0.5{\textrm}{mm}^3$ by vacuum casting method. The graphite mold coated by BN powder, which was to prevent the reaction of carbon with the molten silicon, was used. Without coating, the wetting and reaction of Si melt to graphite mold was very severe. In the case of BN coating, SiC was formed in the shape of tiny islands at the surface of Si wafer by the reaction between Si-melt and carbon of the graphite mold on the high temperature. The grain size was about 1 mm. The efficiency of Si solar cell was lower than that of Si solar cell fabricated on commercial single and poly crystalline Si wafer. The reason of low efficiency was discussed.

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References

  1. W.C. Omara, RB. Herring and L.P. Hunt, 'Handbook of Semiconductor Silicon Technology' (Noyes publica-tion, Park Rkdge, 1990) p. 10
  2. W.R. Runyan, 'Silicon Semiconductor Technology' (McGraw Hill, New York, 1965) p. 21
  3. J.C. Brice, 'Crystal Growth Processes' (John Wiley and Sons, New York, 1986) p. 130
  4. T.E Ciszek, 'Crystal Growth of Electronic Materials, Chap. 15 Silicon for Solar Cells', E. Kaldis, ed. (Elsevier, Amsterdam, 1985) p. 185
  5. G.H. Lee and Z.H. Lee, 'A Study on the Vacuum Cast-ing of Poly-Si Wafer', 1. the Korean Foundrymens Soci-ety 20(3) (2000) 188
  6. Y. Poong, Private communication
  7. P.S. Ravishankar, 'Liquid Encapsulated Bridgman (LEB) Method for Directional Solidification of Silicon using Calcium Chloride', J.Crystal Growth 94 (1989) 62
  8. P.R Celmer, R.V. Jensen and N.J. Trenton, 'Preparation of Reactive Materials in a Molten Non-Reactive Lined Crucible', US patent 2,872,299 (1959)
  9. T.F. Ciszek, 'The Capillary Action Shaping Technique and its Application' (Springer-Verlag, Berlin Heidelberg, 1981) p. 109
  10. AK- Ghosh, C. Fishman and T. Feng, 'Theory of the Electrical and Photovoltaic Properties of Polycrystalline Silicon', J. Appl. Phys. 51 (1980) 446
  11. K.V. Ravi, 'The Growth of EFG Silicon Ribbons', J. Crystal Growth 39 (1977) 1
  12. G.H. Lee and Z.H. Lee, 'Fabrication of Polycrystalline Si Wafer by Vacuum Casting and the Effect of Mold Coating Materials', J. Crystal Growth 233 (2001) 45
  13. C. Gerhards, C. Marckmann, R. Tolle, M. Spiegel, P. Fath, G. Willeke and E. Bucher, 'Mechanically V-tex-tured Low Cost Multicrystalline Silicon Solar Cells with a Novel Printing Metallization', Proc. 26th IEEE PVSEC (1977) 43
  14. R. Einhaus, E. Vazsonyi, J. Szlufcik, J. Nijs and R Mertens, 'Isotropic Texturing of Multicrystalline Silicon Wafers with Acidic Texturing Solutions', Proc. 26th IEEE PVSEC (1997) 167