Journal of the Korea Institute of Military Science and Technology (한국군사과학기술학회지)

The Korea Institute of Military Science and Technology (한국군사과학기술학회)
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Systhesis and Characterization of energetic plasticizers, Formal

포르말계 에너지화 가소제의 합성 및 특성분석

  • Published : 2002.12.01
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Abstract

For the purpose of the increase in the performance and thermal stability of PBX's, the mixed formal consisting of BDNPF, DNPBF and BDNBF were synthesized. In order to find out the optimal condition for the synthesis of energetic plasticizer, BDNPF, DNPBF and BDNBF, the synthetic procedures have been investigated. We synthesized DNP-OH and DNB-OH through oxidative nitration and controlled various composition of mixed formal by $H_{2}SO_{4}$ and s-trioxane to investigate optimal composition, and then characterized its thermo-physical properties.

Keywords

References

  1. H.G. Adolph, NSWC, DEA channel, unpublished, 1991
  2. 전용구, 함덕순, 김진석, 권영환, 국방과학연구소, GWSD-419-940402, 1994
  3. S.M. Chen and A.L. Leu, Thermochimica Acta., Vol.180, 251, 1991
  4. S.M. Chen, A.L. Leu and H.C. Yeh, Thermochimica Acta., 176, 75, 1991
  5. R.S. Hamilton, R.B. Wardle, US Patent, 5449835, 1995
  6. H.G. Adolph, US Patent, 4997499, 1991
  7. 조진래, 국방과학연구소, GWSD-519-9708 39, 1997
  8. R. B. Kaplan, H.Shechter, J. Am. Chem. Soc., 83, 3535, 1961
  9. Z.Matadz, H. Piotrowska, T. Urbanski, Rocz. Chem, 53, 187, 1979
  10. Kornblum, H.K. Singh, W.J. Kelly, J. Org.Chem., 48, 332, 1983
  11. E. E.. Hamel, J. S. Dehn, J. A. Love, J. J.Scigliano, A. H. Swift, I&EC Product Research and Devlopment, 1, 108, 1962
  12. L. C. Garver,V. grakauskas, K. Baum, J. Org. Chem., 50, 1699, 1985
  13. Lippincott, S. B., J. Am. Chem, Soc., 622604(1940); US Patent 2,260,256, 1941
  14. Grakauskas, V., Graver, L.C., Baum, K., US Patent 4594430, 1986
  15. R. S. Hamilton, R. B. Wardle, US Patent 5449835, 1994
  16. B. S. Lee, K. H. Chung, H. W. Lee, I. K. Lee, H. S. Lee, 국방과학연구소, ATRC-412-93768, 1994