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Study on Properties of Al2O3-TiO2 Composites by Wet Method I. Mechanical Properties of Al2O3-TiO2 Composites(2)

습식법에 의한 Al2O3-TiO2 복합체의 합성 및 특성연구 I. Al2O3-TiO2 복합체의 기계적 특성(2)

  • Ryu, Su-Chak (Department of Materials Engineering, Miryang National University)
  • 류수착 (밀양대학교 재료공학과)
  • Published : 2002.01.01

Abstract

$Al_2O_3$ composites powders with 1∼11 wt% $TiO_2$ were prepared by wet method and sintered at 1350$^{\circ}C$, 1450$^{\circ}C$ for 2h. Mechanical properties and microstructural evolution were investigated in this study. $Al_2O_3$-3 wt% $TiO_2$ composite were high bulk density of 2.37 g/$cm^3$ and low apparent porosity of 6.3%. The composites containing of 3 wt% $TiO_2$ showed moderately high bending strength of 68.9 MPa and the young's modulus of 35.5 MPa. The composites with increasing $TiO_2$ contents exhibit reduced thermal expansion coefficient due to the formation of $Al_2TiO_5$ phase.

습식법에 의하여 제조된 $Al_2O_3$-1∼11 wt% $TiO_2$계 복합체를 1350$^{\circ}C$, 1450$^{\circ}C$ 에서 2시간 열처리 한 후 이에 대한 기계적 물성변화 및 미세구조를 조사하였다. 그 결과, $TiO_2$ 첨가량이 3 wt%였을 때의 복합체가 bulk density도 높고 기공율도 낮은 치밀한 미세구조를 이루었으며 이 때 young's modulus는 35.5 GPa, 곡강도값은 68.7 MPa로서 다른 $TiO_2$ 첨가량에 비하여 우수한 물성을 나타내었다. $TiO_2$ 첨가량이 증가할 수록 많은 양의 aluminium titanate의 합성으로 인해 열팽창 계수는 낮은 값을 나타내었다.

Keywords

References

  1. R. W. Cahn, P. Haasen and E. J. Kramer, 'Structure and Properties of Ceramics,' Materials Science and Technology, II, 528-530 (1994)
  2. L. J. Kim, H. B. Lee and Y. S. Ko, 'Aluminium TitanatePart 2,' J. Kor. Ceram. Soc., 10(1), 68-75 (1995)
  3. B. Freudenberg and A. Mocellin, 'Aluminium Titanate Formation by Solid-state Reaction of Fine Al$_{2}$O$_{3}$ and TiO$_{2}$ Powders,' J. Am. Ceram. Soc., 70(1), 33-38 (1987) https://doi.org/10.1111/j.1151-2916.1987.tb04849.x
  4. B. Freudenberg and A. Mocellin, 'Aluminium Titanate Formation by Solid-state Reaction of Coarse Al$_{2}$O$_{3}$ 3 and TiO$_{2}$ Powders,' J. Am. Ceram. Soc., 71(1), 22-28 (1988) https://doi.org/10.1111/j.1151-2916.1988.tb05755.x
  5. H. L. Lee and H. S. Lee, 'A Study on the Preparation of Al$_{2}$O$_{3}$-TiO$_{2}$ Nanocomposite Powders,' J. Kor. Ceram. Soc., 30(2), 115-122 (1993)
  6. W. F. Kladnig and H. Mayer, 'Aluminium Titanate Formation by the Gas-phase Hydropyrolysis Method,' J. Mater. Sci., 25, 1973-1977 (1990) https://doi.org/10.1007/BF01045751
  7. S. C. Ryu and J. Y. Um, 'Synthesis and Properties of Al$_{2}$O$_{3}$-TiO$_{2}$ Composites by Wet Method, 1. Synthesis of Al$_{2}$O$_{3}$-TiO$_{2}$ Composite Powders (1),' J. Kor. Ceram. Soc., 38(5), 412-417 (2001)
  8. H. A. J. Thomas and R. Stevens, 'Aluminium Titanate-A Literature Review, Part 2: Engineering Properties and Thermal Stability,' Br. Ceram. Soc., 184-190 (1989)
  9. Y. Ohya, K. Hamano and Z. Nakagawa, 'Effects of some Additives on Microstructure and Bending Strength of Aluminium Titanate Ceramics,' J. Am. Ceram. Soc., 70(8), 184-186 (1987)