DOI QR코드

DOI QR Code

Hydrothermal Stability of Zirconia Ceramics

지르코니아 세라믹의 열수 상 안정성

  • Lee, Deuk-Yong (Department of Materials Engineering, Daelim College of Technology) ;
  • Gogotsi, George A. (Institute for Problems of Strength, National Academy of Sciences of Ukraine) ;
  • Kim, Dae-Joon (Multifunctional Ceramics Research Center, KIST) ;
  • Park, No-Jin (Department of Materials Engineering, Kumho National University of Technology)
  • 이득용 (대림대학 재료정보공학과) ;
  • ;
  • 김대준 (한국과학기술연구원 복합기능세라믹센터) ;
  • 박노진 (금오공과대학교 재료공학과)
  • Published : 2002.01.01

Abstract

3mol% $Y_2O_3$ Partially-Stabilized Zirconia single Crystals (PSZCs) containing a small quantity (<0.5%) of rare-earth oxides ($CeO_2,\;Tb_2O_3$) were prepared by using a direct high-frequency skull melting technique to evaluate hydrothermal stability in an autoclave. Pole exhibited no $t{\rightarrow}m$ phase transformation during aging for 5h at temperatures from 150 to 250$^{\circ}C$ and 4MPa water vapor pressure in an autoclave, resulting in excellent hydrothermal stability.

3Y-TZP에 희토류 산화물($CeO_2,\;Tb_2O_3$)을 0.5% 이하로 첨가시킨 지르코니아 단결정을 skull melting법으로 제조하여 오토클레이브 하에서 열수 상 안정성을 조사하였다. 극점도 측정결과, skull melting 법으로 제조한 $CeO_2$$Tb_2O_3$가 첨가된 시편들은 단결정이었으며 150∼250$^{\circ}C$에서 5시간 수증기 분위기 하에서 열처리한 후에도 정방정 상이 유지되는 우수한 열수 상 안정성이 관찰되었다.

Keywords

References

  1. M. J. Readey and C. L. McCallen, 'Microstructure, Flaw Tolerance and Reliability of Ce-TZP and Y-TZP Ceramics,' J. Am. Ceram. Soc., 78, 2769-2776 (1995) https://doi.org/10.1111/j.1151-2916.1995.tb08053.x
  2. J. Li, A. Kawasaki and R. Watanabe, 'R-curve Determination of 3Y-PSZ by the Indentation Strength-in-bending Method,' J. Ceram. Soc. Jpn., 105, 88-90 (1997) https://doi.org/10.2109/jcersj.105.88
  3. R. M. Anderson and L. M. Braun, 'Technique for the Rcurve Determination of Y-TZP Using Indentation-produced Flaws,' J. Am. Ceram. Soc., 73, 3059-3062 (1990) https://doi.org/10.1111/j.1151-2916.1990.tb06716.x
  4. S. Lawson, 'Environmental Degradation of Zirconia Ceramics,' J. Eur. Ceram. Soc., 15, 485-502 (1995) https://doi.org/10.1016/0955-2219(95)00035-S
  5. M. Hirano and H. Inada, 'Fabrication and Properties of (Y,Ce)-TZP/Al$_{2}$O$_{3}$ and Y-TZP/Al$_{2}$O$_{3}$ Composites from Fine Powder Prepared by a Hydrolysis Technique,' J. Ceram. Soc. Jpn., 99, 124-130 (1991) https://doi.org/10.2109/jcersj.99.124
  6. D-J. Kim, 'Influence of Aging Environment on Low-temperature Degradation of Tetragonal Zirconia Alloys,' J. Eur. Ceram. Soc., 17, 897-903 (1997) https://doi.org/10.1016/S0955-2219(96)00205-1
  7. D. Y. Lee, D-J. Kim and D-H. Cho, 'Low-temperature Phase Stability and Mechanical Properties of Y$_{2}$O$_{3}$ and Nb$_{2}$O$_{5}$ Co-doped Tetragonal Zirconia Polycrystal Ceramics,' J. Mater. Sci. Lett., 17, 185-187 (1998). https://doi.org/10.1023/A:1006567808134
  8. D. Y. Lee, J-w. Jang and D-J. Kim, 'Raman Spectral Characterization of Existing Phases in the $ZrO_2-Y_2O_3-Nb_2O_5$ System,' Ceram. Inti., 27, 291-298 (2001) https://doi.org/10.1016/S0272-8842(00)00079-1
  9. P. Li, I-W. Chen and J. E. Penner-Hahn, 'Effect of Dopants on Zirconia Stabilization-an X-ray Absorption Study: III, Charge-compensating Dopants,' J. Am. Ceram. Soc., 74, 1289-1295 (1994)
  10. D. Y. Lee, D-J. Kim, D-H. Cho and M-H. Lee, 'Effect of Nb$_{2}$O$_{3}$ and Y$_{2}$O$_{3}$ Alloying on the Mechanical Properties of TZP Ceramics,' Ceram. Inti., 24, 461-465 (1998) https://doi.org/10.1016/S0272-8842(97)00036-9
  11. D. Y. Lee and D-J. Kim, 'Strength and Fracture Toughness of Isostatically Hot-pressed (Y,Nb)-TZP/Al$_{2}$O$_{3}$ Composites,' J. Mater. Sci. Lett., 19, 1233-1235 (2000) https://doi.org/10.1023/A:1006709110273
  12. G. A. Gogotsi, V. I. Galenko, B. A. Ozerskii, E. E. Lomonova, V. A. Myzina, M. A. Vishnyakova and V. F. Kalabukhova, 'Strength and Crack Resistance of Zirconium Dioxide Crystals Containing Yttrium and Terbium Oxides,' Refractories, 34, 247-358 (1993)
  13. G. A. Gogotsi, E. E. Lamonova, Y. A. Furmanov and I. M. Savitskaya, 'Zirconia Crystals Suitable for Medicine: 1. Implants,' Ceram. Intl., 20, 343-348 (1994) https://doi.org/10.1016/0272-8842(94)90052-3
  14. G. A. Gogotsi and D. Yu. Ostrovoy, 'Mechanical Behaviour of Partially Stabilized Zirconia Crystals with Terbia and Ceria Additives,' J. Eur. Ceram. Soc., 15, 1177-1184 (1995) https://doi.org/10.1016/0955-2219(95)00100-X
  15. R. C. Garvie and P. S. Nicholson, 'Phase Analysis in Zirconia Systems,' J. Am. Ceram. Soc., 67, 303-305 (1972)
  16. M. J. Mendelson, 'Average Grain Size in Polycrystalline Ceramics,' J. Am. Ceram. Soc., 52(8), 443-446 (1969) https://doi.org/10.1111/j.1151-2916.1969.tb11975.x
  17. D-J. Kim, M-H. Lee, D. Y. Lee and J-S. Han, 'Mechanical Properties, Phase Stability and Biocompatibility of (Y,Nb)TZP/Al$_{2}$O$_{3}$ Composite Abutments for Dental Implant,' J. Biomed. Mater. Res., 53, 438-443 (2000) https://doi.org/10.1002/1097-4636(2000)53:4<438::AID-JBM19>3.0.CO;2-3
  18. D. Y. Lee, D-J. Kim, J-w. Jang, D-W. Choi and S-J. Lee, 'Phase Stability of (Y,Nb)-TZP/Composites under Low Temperature Hydrothennal Conditions,' Mater. Lett., 39, 221-226 (1999) https://doi.org/10.1016/S0167-577X(99)00010-5
  19. J-w. Jang, D-J. Kim and D. Y. Lee, 'Size Effect of Trivalent Oxides on Low Temperature Phase Stability of 2Y-TZP,' J. Mater. Sci., 36(22), 5391-5395 (2001) https://doi.org/10.1023/A:1012409009280