DOI QR코드

DOI QR Code

A Study on the Characteristics of MgO Thin Films Prepared by Electron Beam

전자빔 증착법에 의해 형성된 MgO 박막의 증착 및 특성

  • Lee, Choon-Ho (Department of Materials Engineering, Keimyung University) ;
  • Kim, Sun-Il (Department of Materials Engineering, Keimyung University) ;
  • Shin, Ho-Shik (Thin Film Devision, Tae Yang Electronics Co., LTD.)
  • Published : 2002.01.01

Abstract

The growth characteristics on the MgO thin films prepared by the e-beam evaporation method have been investigated. We observed the film of preferred orientation and surface morphology with various parameters such as substrate temperature, deposition rate on Si(100) and slide glass respectively. Consequently, it was shown that MgO(111) preferred orientation films can be obtained as the deposition rate was increased on Si(100) substrate. MgO(220) peak was found as the substrate temperature was increased. Whereas, in case of slide glass the orientation is changed from (200) to (111) by substrate temperature. Also we investigated the relationship between the film characteristics and the orientation of MgO thin films.

MgO 박막은 성장용 기판 또는 완충층으로 이용되고 있으며, 근래에는 AC PDP의 유전체 보호막으로써 그 활용도가 넓어지고 있다. 본 연구에서는 전자빔증착법에 의해 MgO 박막을 증착시켜 증착변수에 따른 MgO 박막의 성장특성을 연구하였다. 실험은 증착기판, 증착속도, 기판온도 등의 변화에 따른 MgO 박막의 우선배향성, 표면형상을 통하여 MgO 박막의 물성을 알아보았다. 실험결과, Si 기판에서는 증착속도가 빠를수록 (111)우선배향된 박막을 얻을 수 있었고, 기판온도가 상온일때는 (200)에서 기판온도가 증가할수록 (220)의 peak이 관찰되었다. 비정질인 slide galss 기판일 경우에는 상온에서 MgO 박막의 (200)면의 우선배향을 얻을수 있었고, 온도에 의해 배향성이 (200)면에서 (111)면으로 바뀌는 것을 알 수 있었다. 또한 MgO 박막의 배향성과 특성에 대한 관계를 조사하였다.

Keywords

References

  1. T. Harada, M. Asano and Y. Mizutani, 'Epitaxial Growth of Ag Deposited on Air-cleaved MgO(100) Surface by Molec-ular Beam Deposition,' J. Cryst. Growth, 116 243-50 (1992) https://doi.org/10.1016/0022-0248(92)90630-2
  2. Y. C. Lee, P. Tong and P. A. Montano, 'Deposition of Iron on MgO(100): Reaction of CO and H$_2$,' Surf. Sci., 181 559-72 (1987) https://doi.org/10.1016/0039-6028(87)90205-6
  3. H. Onishi, C. Egawa, T. Aruga and Y. Iwasawa, 'Adsorption of Na Atoms and Oxygen containing Molecules on MgO (100) and (III) Surfaces,' Surf. Sci., 191 479-91 (1987) https://doi.org/10.1016/S0039-6028(87)81192-5
  4. J. Lahthinen, J. Vaari, A. Talo, A. Vehanen and P. Hautojrvi, 'Studies of MgO Overlayers on Co(0001): Growth Mode and CO Chemisorption Properties,' Surf. Sci.. 245 244-54 (1991) https://doi.org/10.1016/0039-6028(91)90027-P
  5. R. Sum, H. P. Lang and H. J. Guntherodt, 'Scanning Force Microscopy Study of Single-crystal Substrates Used for Thinfilm Growth of High-temperature Superconductors,' Phvs. C:Superconductivity, 242 174-82 (1995) https://doi.org/10.1016/0921-4534(94)02414-6
  6. S. S. Kim, Y. B. Park, Y. M. Kang, W. J. Park, S. G. Baik and A. L. Gruvermanc, 'Ferroelectric Domains in Epitaxial PbTiO$_{3} and BaTiO_{3}$ Thin Films on MgO(100);' Thin Solid FiIms, 312 249-53 (1998) https://doi.org/10.1016/S0040-6090(97)00270-8
  7. R. A. McKee, F. J. Walker, E. D. Specht, G. E. Jellison, L. A. Boatner and J. H. Harding, 'Interface Stability and the Growth of Optical Quality Perovskites on MgO,' Phys. Rev. Lett., 72 2741 (1994) https://doi.org/10.1103/PhysRevLett.72.2741
  8. M. Wintersgill and J. Fomtanella, 'The Temperature Variation of the Dielectric Constant of 'Pure' CaF2, SrF2 and MgO,' J. Appl. Phys., 50 8259-61 (1979) https://doi.org/10.1063/1.325932
  9. T. Urade, T. lemori, M. Osaws, N. Nakayama and I. Morita, 'A Protecting Layer for the Dielectric in AC Plasma Panels,' IEEE Trans. Etectron Devices, ED-23, 313-18 (1976) https://doi.org/10.1109/T-ED.1976.18397
  10. C. K. Yoon, J. K. Kim, Y. W. Chung, S. H. Ahn, J. H. Yang and K. W. Whang, 'Dependence of ACPDP Discharge Charactenstics on MgQ,' SID SYM, 611 (1997)
  11. K. Machida, H. Uchiike and H. Sasaki, 'Surface Analysis Comparison of Vacuum Evaporated and Thick film Printed MgO Films in ac Plasma Displays,' SID SYM, 531 (1992)
  12. H. Uchiike and S. Harada, 'Annealing Process of Evap orated MgO Films in ac Plasma Displays,' SID SYM, 444 (1991)
  13. K. K-amata, Y. Shibata and Y. Kishi, 'MgO Films Deposited by Chemical Vapour Deposition,' J. Mat. Sci. Lett, 3 423-26 (1984) https://doi.org/10.1007/BF00724383
  14. L. Eckertova, 'Physics of Thin Films,' pp. 133, Plenum Press, New York, 1986
  15. Y. G. Lee, S. H. Lee, K. H. Kim and D. N. Lee, 'Dendritic Growth Directions of Chromium and Zinc in Solidified Cu 2.3%Cr and Zn 3.8%A1 Alloys,' J. Kor. Inst. Met. and Mater., 33 498-503 (1995)
  16. A. Gittis and D. Dobrev, 'Development of Textures Duhng the Growth of Silver Films Condensed in Vacuum on Glass,' Thin Solid Fitms, 130 335-40 (1985) https://doi.org/10.1016/0040-6090(85)90364-5