Korean Journal of Fisheries and Aquatic Sciences (한국수산과학회지)

The Korean Society of Fisheries and Aquatic Science (한국수산과학회)
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Effects of Emulsifying Conditions and Alginate Concentration of Encapsulating Ester Compounds on Retention Rate of Core Material in Microcapsules Prepared with Sea Tangle Alginates

다시마 알긴산으로 제조한 에스테르화합물 캡슐에 있어서 내부물질의 잔존량에 미치는 유화조건과 알긴산농도의 영향

  • You Byeong Jin (Kangnung National University, Department of Food Science) ;
  • Lim Yeong Seon (East Coastal Marine Bioresources Research Center, Kangnung National University)
  • 유병진 (강릉대학교 식품과학과) ;
  • 임영선 (강릉대학교 동해안해양생물자원연구센터)
  • Published : 2002.11.01
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Abstract

To investigate the effects of preparation conditions of encapsulating ester compounds on retention rate of core material in microcapsules prepared with sea tangle alginate, the amounts of ester compounds migrated gelling solution (1 M $CaCl_2$) and washing water from microcapsules that were prepared by adding kinds of ester compound, by controlling ratios of emulsifier to ester compounds and by differing ratios of alginates (wall material) to ester compounds (core material) were measured. Also the amount of ester compounds retained in microcapsules was measured. The higher weight molecular of ester compounds were, the lower amounts of ester compounds migrated gelling solution and washing water from microcapsules were, But its amounts retained in microcapsules were increased, The changes of ethyl caprylate amount migrated gelling solution and washing water from microcapsules prepared by increasing ratios of emulsifier to ethyl caprylate were little, but its half-lives in microcapsules during storage at 25$^{\circ}C$ were steeply increased. Increasing ratios of wall material to core material, ethyl caprylate amount migrated gelling solution and washing water from microcapsules showed 1.8$\~$$2.0\%$ and 2.9$\~$$3.5\%$ respectively but half-lives of ethyl caprylate retained in alginate microcapsules were increased.

다시마 알긴산으로 에스테르 화합물을 캡슐화할 때 에스테르화합물의 잔존량에 영향을 미치는 가공조건을 알아보기 위하여, 에스테르 화합물의 종류, 유화제 첨가비율 및 에스테르 화합물 (내부물질)에 대한 alginates (벽막물질)의 비율을 달리하여 캡슐을 제조하고 제조중에 사용하는 gelling solution ($1 M\;CaCl_2$)과 캡슐의 세척수에 이동되는 에스테르 화합물의 량과 캡슐에 잔존하는 에스테르 화합물의 량을 측정하였다. 에스테르 화합물의 분자량이 커질수록 캡슐에 잔존하는 량이 증가하였고 gelling solu-tion과 세척수에 이동되는 량이 감소하였다. Ethyl caprylate량에 대한 유화제의 첨가 비율이 증가하석도 gelling solution와 세척수에 이동되는 ethyl caprylate의 량은 1.7$\~$$1.8\%$와 2.3$\~$$6.5\%$이었고 캡슬에 잔존하는 량은 $90.4\~96.0\%$로 거의 변화가 없었다. 그러나 캡슐을 25$^{\circ}C$에 저장할 때 ethyl caprlate의 반감기는 유화제의 첨가비율이 증가할수록 급격히 증가하였다. Ethyl capr빈ate에 대한 alginates 비율이 증가하여도 gelling solution과 세척수에 이동되는 ethyl caprylate 량은 각각 $1.8\~2.0\%$ 및 $2.9\~3.5\%$이었고 캡슐에 잔존하는 량은 $94.3-95.0\%$로 큰 차이가 없었다. 그러나 캡슐을 25$^{\circ}C$에 저장할 때에 벽막물질의 비율이 증가함에 따라 내부물질의 반감기는 증가하였다.

Keywords

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