Bulletin of the Korean Chemical Society

  • 제24권4호
  • /
  • Pages.479-483
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  • 2003
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Synthesis and Characterization of Oligomers Composed of Alternating 2,5-Bis(ethynylenedimethylsilylene)thienylene and Arylene Units

  • Kwak, Young-Woo (Department of Chemistry, Kyungpook National University) ;
  • Lee, Kyung-Koo (Department of Chemistry, Kyungpook National University) ;
  • Cha, Seung-Hun (Department of Chemistry, Kyungpook National University) ;
  • Lee, Sang-Koo (Department of Chemistry, Kyungpook National University) ;
  • Lee, In-Sook (Department of Chemistry, Kyungpook National University) ;
  • Park, Yong-Tae (Department of Chemistry, Kyungpook National University) ;
  • Lee, Jae-Keun (Department of Chemistry, Kyungpook National University) ;
  • Yoh, Soo-Dong (Department of Chemistry Education, Kyungpook National University) ;
  • Kim, Woo-Sik (Department of Polymer Science, Kyungpook National University)
  • 발행 : 2003.04.20
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초록

The reactions of 2,5-bis(ethynyldimethylsilyl)thiophene (1) with aromatic dihalides(1,4-dibromobenzene, 4,4'- dibromobiphenyl, 9,10-dibromoanthracene, 2,5-dibromopyridine, 2,5-dibromothiophene, and 2,6-diiodo-4- nitroaniline) were carried out in the presence of a $[(PPh_3)_2PdCl_2]$-CuI catalyst in refluxing triethylamine to give poly{[2,5-bis(ethynylenedimethylsilylene)thienylene](arylene)} (2-7) with molecular weights of 2200-7400. The oligomers reveal characteristic absorption in the UV/visible region. The thermal behavior of 2-7 was examined by thermogravimetric analysis in an argon atmosphere.

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