Korean Journal of Food Science and Technology (한국식품과학회지)

Korean Society of Food Science and Technology (한국식품과학회)
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The Identification of Blended Sesame Oils by Electronic Nose

전자코를 이용한 혼합 참기름의 판별 연구

  • Shin, Jung-Ah (Department of Food Science and Technology, Chungnam National University) ;
  • Lee, Ki-Teak (Department of Food Science and Technology, Chungnam National University)
  • Published : 2003.08.01
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Abstract

Precise and rapid method out for distinguishing blended sesame oils through the electronic nose analysis was developed. Sesame oil was blended with corn oil at the ratio of 95 : 5, 90: 10, and 80 : 20 (w/w), respectively. Samples were then analyzed by gas chromatography, SPME-GC/MS, and the electronic nose composed of 12 different metal oxide sensors. Sensitivities $(delta\;R_{gas}/R_{air})$ of sensors from electronic nose were analyzed by principal component analysis (PCA). Proportion of the first principal component was 98.76%.

본 실험은 순수참기름과 혼합참기름의 구별 및 순도판별을 용이하게 하기 위한 분석방법을 제시하고자 실행되었다. 순수참기름과 옥수수기름을 95 : 5, 90 : 10, 80 : 20(w/w)의 비율로 각각 비율을 달리해서 혼합참기름을 제조한 후 GC, SPME-GC/MS, 전자코를 이용한 분석을 실시하였다. 지방산조성(mole%)을 비교한 결과 옥수수기름이 10%이상 함유된 혼합참기름과 순수참기름 간에는 stearic acid와 linoleic acid의 함량의 변화로 구별이 가능하였으나 5%내로 옥수수유가 함유된 혼합참기름과 순수참기름과의 구별은 용이하지 않았다. 향기성분동정을 위해 SPME-GC/MS 분석을 실시한 결과순수참기름과 혼합참기름은 같은 향기성분 패턴을 보여 구별하기 어려웠다. 반면, MOS 유형의 전자코를 이용하여 향기성분패턴 분석결과 제1주성분 값의 기여율이 98.76%로 구별이 가능하였으며 이로써 신속하고 편리하게 비파괴적 분석 방법인 전자코를 활용하여 순수참기름과 혼합참기름을 구별할 수 있었다.

Keywords

References

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