Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
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Synthesis of FAU(Faujasite)-type Zeolite with Variation of Synthesis Condition

합성조건의 변화에 따른 FAU(Faujasite)형 제올라이트의 합성

  • 임형미 (요업기술원 신기능재료연구부) ;
  • 김봉영 (요업기술원 신기능재료연구부) ;
  • 남중희 (요업기술원 신기능재료연구부) ;
  • 안병길 (요업기술원 신기능재료연구부) ;
  • 오성근 (한양대학교 화학공학과) ;
  • 정상진 (요업기술원 세라믹ㆍ건재부)
  • Published : 2003.02.01
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Abstract

The effect of synthesis condition, type of starting materials, mole ratio, mixing. aging, and crystallization temperature and time, on the size of FAU-type zeolite has been studied. Different mixing route may lead to the different phase of zeolite even with the same starting materials. In general, the size of particles is smaller after aging, especially at lower aging temperature. Two step mixture gel preparation method resulted to not only the reduction of crystallization time but also that of particle size, but without the aging of two mixture gels before the preparation of the overall gel in the second step, only the crystallization time was reduced, not the particle size. The FAU-type zeolite with average particle size 0.4$\mu$m and BET surface area 838 $m^2$/g was obtained from starting materials of liquid sodium silicate, sodium aluminate, and sodium hydroxide with two step preparation of mixture gel, aging of the mixture gels in two steps, which effectively reduced the crystallization time and particle size.

출발물질의 종류와 몰비 혼합 방법, 숙성, 결정화 온도와 결정화 시간 등 제올라이트 입자를 합성하는 조건이 FAU 형 제올라이트의 입자크기에 미치는 영향을 연구하였다. 동일한 출발물질이라도 혼합 경로에 따라 생성물의 결정상이 달랐다. 일반적으로 숙성과정을 거친 경우, 특히 숙성온도가 낮은 쪽이 입자 크기가 작았다. 2단계의 혼합겔 제조 방법을 거치는 경우 결정화 기간은 크게 단축되고 입자 크기도 작아졌으나. 1단계에서 제조된 2종의 혼합겔을 모두 숙성하지 않는 경우에는 결정화 시간은 단축되지만, 입자크기는 작아지지 않았다. 액상규산나트륨과 알루민산나트륨, 수산화나트륨을 출발물질로 하여. 저농도와 고농도의 혼합겔을 1차 제조하고, 이 혼합겔을 각각 숙성하고 다시 혼합하여 숙성하는 방법으로 결정화 시간을 단축하고 평균입경 0.4$\mu$m. 비표면적 838 $m^2$/g의 우수한 특성을 가지는 FAU혈 제올라이트를 합성하였다.

Keywords

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