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Microstructure and Microwave Dielectric Properties of (1-x) Ba (Co1/3Nb2/3)O3-zBa(Zn1/3Nb2/3)O3 Ceramics

  • Ahn, Byung-Guk (Faculty of New Materials Engineering, Chonbuk National University) ;
  • Ahn, Cheol-Woo (Department of Material Science and Engineering, Korea University) ;
  • Nahm, Sahn (Department of Material Science and Engineering, Korea University) ;
  • Lee, Hwack-Joo (New Materials Evaluation Center, Korea Research Institute of Standards and Science)
  • 발행 : 2003.04.01

초록

Ba (Co$_{1}$ 3/Nb$_{2}$ 3/)O$_3$(BCN) has a 1:2 ordered hexagonal structure. Q-value of BCN increased with increasing sintering temperature however, it significantly decreased when the sintering temperature exceeded 140$0^{\circ}C$ Ba (Co$_{1}$ 3/Nb$_{2}$ 3/)O$_3$(BZN) has the 1:2 ordered hexagonal structure and the degree of the 1 : 2 ordering decreased with the increase of the sintering temperature. The Q value of the BZN increased with increasing the sintering temperature and BZN sintered at 140$0^{\circ}C$ for 6h has a maximum Q-value. For (1-x) Ba (Co$_{1}$ 3/Nb$_{2}$ 3/)O$_3$-zBa(Zn$_{1}$ 3/Nb$_{2}$ 3/)O$_3$[(1-x)BCN-xBZN] ceramics the 1:2 ordered hexagonal structure was observed in the specimens with x$\leq$0.3 and the BaNb$_{6}$ O$^{16}$ second phase was found in the specimens with x$\geq$0.6. Grain Growth, which is rotated to the BaNb$_{6}$ O$^{16}$ second phase occurred in the specimens with x$\geq$ 0.5. In this work, the excellent microwave dielectric properties of $\tau$r=0.0 ppm/$^{\circ}C$$\varepsilon$r=34.5 and Q,$\times$f=97000GHz sere obtained for the 0.7BCV-0.3BZN ceramics sintered at 1400$0^{\circ}C$ for 20h.

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참고문헌

  1. Jpn. J. Appl. Phys. v.21 Ba(Zn Nb )O Sr(Zn Nb ) O Solid Solution Ceramics with Temperature-stable High. Dielectric Constant and Low Microwave Loss M.Onoda;J.Kuwata;K.Kaneta;K.Toyama;S.Nomura https://doi.org/10.1143/JJAP.21.1707
  2. J. Am. Ceram. Soc. v.79 Oder-disorder Phase Formation in the Complex Perovskite Compounds Ba(Ni Nb )O and Ba(Zn Nb )O K.S.Hong;I.T.Kim;C.D.Kim https://doi.org/10.1111/j.1151-2916.1996.tb08098.x
  3. Jpn. J. Appl. Phys. v.41 Effect of Structural Changes on The Microwave Dielectric Properties of Ba(Zn Nb )O Ceramics S.Y.Noh;M.J.You;S.Nahm;C.H.Choi;H.M.Park;H.J.Lee https://doi.org/10.1143/JJAP.41.2978
  4. J. Mat. Sci v.30 Effects on Non-stoichiometry and Chemical Inhomogeneity on The Order-dis-Order Phase Formation in the Complex Perovskite Compounds I.T.Kim;K.S.Hong;S.J.Yoon https://doi.org/10.1007/BF00354420
  5. J. Mat. Sci. v.28 Microwave Dielectric Properties of Ba(Sn Zn Nb )O (0 x 0.32) Ceramics J.S.Sun;J.J.Yu;J.C.You;C.C.Wei https://doi.org/10.1007/BF00367578
  6. Jpn. J. Appl. Phys. v.34 Improved High-Q Dielectric Resonator Sintered at Low Firing Temperature C.C.You;C.L.Huang;C.C.Wei;J.W.Huang https://doi.org/10.1143/JJAP.34.1911
  7. Jpn. J. Apppl. Phys. v.36 Revisit to the Anomaly in Dielectric Properties of(Ba Sr )(Zn Nb )O Solid Solution System J.S.Kim;J.H.Lee;Y.S.Lim;J.W.Jang;I.T.Kim https://doi.org/10.1143/JJAP.36.5558
  8. J. Am. Ceram. Soc. v.70 Dielectric Properties of Ceramics in Ba(Co Nb )O xBa(Zn Nb )O Solid Solutions K.Endo;K.Fujimoto;K.Murakawa
  9. IRE. Trans. Microwave Theory Tech. v.8 Dielectric Resonator Method of Measuring Inductive Capacities in the Millimeter Range B.W.Hakki;P.D.Coleman https://doi.org/10.1109/TMTT.1960.1124749
  10. IEEE Trans. Microwave Theory Tech. v.MTT-18 Analysis and Evaluation of a Method of Measuring the Complex Permittivity of Microwave Insulators W.E.Courthey