Thermal and Flow Analysis in a Proton Exchange Membrane Fuel Cell

  • Jung, Hye-Mi (Graduate School, Hankuk Aviation University) ;
  • Koo, Ja-Ye (School of Aerospace and Mechanical Engineering, Hankuk Aviation University)
  • Published : 2003.09.01

Abstract

The effects of anode, cathode, and cooling channels for a Proton Exchange Membrane Fuel Cell (PEMFC) on flow fields have been investigated numerically. Continuous open-faced fluid flow channels formed in the surface of the bipolar plates traverse the central area of the plate surface in a plurality of passes such as a serpentine manner. The pressure distributions and velocity profiles of the hydrogen, air and water channels on bipolar plates of the PEMFC are analyzed using a two-dimensional simulation. The conservation equations of mass, momentum, and energy in the three-dimensional flow solver are modified to include electro-chemical characteristics of the fuel cell. In our three-dimensional numerical simulations, the operation of electro-chemical in Membrane Electrolyte Assembly (MEA) is assumed to be steady-state, involving multi-species. Supplied gases are consumed by chemical reaction. The distributions of oxygen and hydrogen concentration with constant humidity are calculated. The concentration of hydrogen is the highest at the center region of the active area, while the concentration of oxygen is the highest at the inlet region. The flow and thermal profiles are evaluated to determine the flow patterns of gas supplied and cooling plates for an optimal fuel cell stack design.

Keywords

References

  1. Baschuk, J. J. and Li Xianguo, 2000, 'Modeling of Polymer Electrolyte Membrane Fuel Cells with Variable Degrees of Water Flooding,' J. Power Sources, Vol. 86, Issues 1-2, pp. 181-196 https://doi.org/10.1016/S0378-7753(99)00426-7
  2. Bernardi, D. M. and Verbrugge, M. W., 1992, 'A Mathematical Model of a Solid Polymer Electrolyte Fuel Cell,' J. Electrochem Soc., Vol. 139, No.9, pp.2477-2491 https://doi.org/10.1149/1.2221251
  3. Costamagna, P., 2001, 'Transport Phenomena in Polymeric Membrane Fuel Cells,' Chem. Eng. Sci., Vol. 56, Issue 2, pp. 323-332 https://doi.org/10.1016/S0009-2509(00)00232-3
  4. Dutta, S., Shimp alee, S. and Van Zee, J. W., 2001, 'Numerical Prediction of Mass-Exchange Between Cathode and Anode Channels in a PEM Fuel Cell,' J. Heat and Mass Transfer, Vol. 44, Issue 2, pp. 2029-2042 https://doi.org/10.1016/S0017-9310(00)00257-X
  5. EG & G Services Parsons Inc., 2000, Fuel Cell Handbook, No. DE-AM26-99FT40575
  6. Fand, R. M., Kim, B. Y. K., Lam, A. C. C. and Phan, R. T., 1987, 'Resistance to the Flow of Fluid through Simple and Complex Porous Media Whose Matrices are Composed of Randomly Packed Spheres,' ASME J. Fluids Engineering, Vol. 109, pp.268-274 https://doi.org/10.1115/1.3242658
  7. Fuller, T. F. and Newman, J., 1993, 'Water and Thermal Management in Solid Polymer Electrolyte Fuel Cells,' J. Electrochem Soc., Vol. 140, No.5, pp. 1218-1225 https://doi.org/10.1149/1.2220960
  8. Gunes, M. B., 2001, 'Investigation of a Fuel Cell Based Total Energy System for Residential Application,' M. S. Mechanical Eng., Virginia Poly-technique Institute of University
  9. He, W. and Chen, Q., 1998, 'Three-Dimensional Simulation of a Molten Carbonate Fuel Cell Stack under Transient Conditions,' J. of Power Sources, Vol. 55, Issue 1, pp.25-32 https://doi.org/10.1016/0378-7753(94)02164-X
  10. Jung, S. Y. and Nguyen, T. V., 1998, 'An Along-the-Channel Model for Proton Exchange Membrane Fuel Cells,' J. Electrochem. Soc., Vol. 145, pp.1149-1159 https://doi.org/10.1149/1.1838431
  11. Larminie, J. and Dicks, A., 2000, Fuel Cell Systems Explained, John Wiley & Sons, Inc.
  12. Lee, J. H. and Lalk, T. R., 1998, 'Modeling Fuel Cell Stack Systems,' J. Power Sources, Vol. 73, Issue 2, pp. 229-241 https://doi.org/10.1016/S0378-7753(97)02812-7
  13. Mann, R. F., 2000, 'Development and Application of a Generalized Steady-State Electrochemical Model for a PEM Fuel Cell,' J. Power Sources, Vol. 86, Issues 1-2, pp. 173-180 https://doi.org/10.1016/S0378-7753(99)00484-X
  14. Nguyen, T. V. and White, R. E., 1993, 'A Water and Heat Management Model for ProtonExchange Membrane Fuel Cells,' J. Electrochem. Soc., Vol. 140, No.8, pp. 2178-2186 https://doi.org/10.1149/1.2220792
  15. Raznjevic, K., 1995, Handbook of Thermodynamic Tables, Begell House, Inc.
  16. Singh, D., Lu, D. M. and Djilali, N., 1999, 'A Two-Dimensional Analysis of Mass Transport in Proton Exchange Membrane Fuel Cell,' J. Eng. Soc., Vol. 37, pp.431-452 https://doi.org/10.1016/S0020-7225(98)00079-2
  17. Springer, T. E., Zawodzinski, T. A. and Gottesfeld, S., 1991, 'Polymer Electrolyte Fuel Cell Model,' J. Electrochem Soc., Vol. 138, No.8, pp.2334-2342 https://doi.org/10.1149/1.2085971
  18. Standaert, F., Hemmes, K. and Woudstra, N., 1996, 'Analytical Fuel Cell Modeling,' J. of Power Sources, Vol. 63, Issue 2, pp.221-234 https://doi.org/10.1016/S0378-7753(96)02479-2
  19. Suares, G. E. and Hoo, K. A., 2000, 'Parameter Estimation of a Proton-Exchange Membrane Fuel Cell Using Voltage-Current Data,' Chem. Eng. Soc., Vol. 55, pp. 2237-2247 https://doi.org/10.1016/S0009-2509(99)00508-4
  20. Tuomas Mennola, 2000, 'Design and Experiment Characterization of Polymer Electrolyte Membrane Fuel Cells,' Master's Thesis, Department of Engineering Physics and Mathematics, Helsinki University of Technology
  21. Um, S. K., Wang, C. Y. and Chen, K. S., 2000, 'Computational Fluid Dynamics Modeling of Proton Exchange Membrane Fuel Cells,' J. Electrochem. Soc., Vol. 147, No. 12, pp. 4485-4493 https://doi.org/10.1149/1.1394090
  22. Verbrugge, M. W. and Hill, R. F., 1990, 'Transport Phenomena in Perfluorosulfonic Acid Membrane during the Passage of Current,' J. Electrochem Soc., Vol. 137, pp. 1131-1138 https://doi.org/10.1149/1.2086615
  23. Wang, Z. H., Wang, C. Y. and Chen, K. S., 2001, 'Two-Phase Flow and Transport in the Air Cathode of Proton Exchange Membrane Fuel Cells,' J. Power Sources, Vol. 94, Issue 1, pp. 1-11 https://doi.org/10.1016/S0378-7753(00)00662-5