A clean technology development and the molybdenum dissolution reaction with hydrogen peroxide

과산화수소를 이용한 몰리브덴(Mo) 용해 반응과 이에대한 청정기술 개발에 관한 연구

  • 김재우 (경원전문대학 환경과학과) ;
  • 강수정 (성균관대학교 화학공학과) ;
  • 김남기 (성균관대학교 화학공학과)
  • Published : 2003.06.01

Abstract

The advantages of hydrogen peroxide dissolution method were no discharge of noxious matter when dissolution of molybdenum wire which used as the center supporter, reactions occur in room temperature. The results were as follows : 1. In the FL/10-A type: Dissolution-reaction Time was 50Min., C.R.(Coil resistance) was $9.27{\Omega}(St.{\;}:{\;}9.2{\pm}0.22{\Omega})$, P.W.(Piece weight) was $10.59mg(St.{\;}:{\;}10.5{\pm}0.26mg)$. In the FL/15-D type: Dissolution-reaction Time was 55Min., C.R. was $6.39{\Omega}(St.{\;}:{\;}6.38{\pm}0.02{\Omega})$, P.W. was $16.7mg(St.{\;}:{\;}16.5{\pm}0.3mg)$. In the FL/20-H type: Dissolution-reaction Time was 45Min., C.R. was $4.7{\Omega}(St.{\;}:{\;}4.6{\pm}0.3{\Omega})$, P.W. was $20.8mg(St.{\;}:{\;}20{\pm}1.5mg)$. In the FL/20-C type: Dissolution-reaction Time was 60Min., C.R. was $4.5{\Omega}(St.{\;}:{\;}4.6{\pm}0.3{\Omega})$, P.W. was $19.8mg(St.{\;}:{\;}19{\pm}1.0mg)$. 2. In the GLS-230/40-B type: Dissolutiona-reaction Time was 45Min., C.R. was $105.1{\Omega}(St.{\;}:{\;}104{\pm}2.6{\Omega})$, P.W was $6.37mg(St.{\;}:{\;}6.3{\pm}0.16mg)$. In the GLS-230/60-F type: Dissolution- reaction Time was 45Min., C.R. was $65.92{\Omega}(St.{\;}:{\;}65{\pm}1.62{\Omega})$, P.W. was $11.91mg(St.{\;}:{\;}11.8{\pm}0.29mg)$.

Keywords

References

  1. Inorg. Chem v.20 Kinetc studies on the Oxidation of Trimeric Aquomolybdenum Mark A.Harmer;Allan B.Soares;Andrew T.Thornton;A.Geoffrey Syles https://doi.org/10.1021/ic50226a025
  2. Inorg. Chem v.17 no.4 Reaction of MoO(S₂CNR₁R₂)₂with Azide E.A.Maatta;R.A.Wentworth https://doi.org/10.1021/ic50182a025
  3. J. Am. Chem. Soc. v.108 Thermodynamic Fitness of Molybdenum(Ⅳ,Ⅵ) Complexes for Oxygen Atom Transfer, Including Those with Enzymatic Substrates Edgar W. Harlan;Jeremy M. Berg;R.H.Holm https://doi.org/10.1021/ja00282a025
  4. Inorg. Chem. v.5 no.5 Coordination Chemistry of Molybdenum Oxochlorieds Melvin L. Larson;Fred W. Moore https://doi.org/10.1021/ic50039a023
  5. Inorg. Chem. v.6 no.5 Dialkyldithiocarbamate Complexes of Molybdenum(Ⅴ) and Molydenum(Ⅵ) Fred W. Moore;Melvin L. Larson https://doi.org/10.1021/ic50051a031
  6. Report of cooperative agreement CR-808825, U.S. Environmental protection agency, Municipal evironmental researc laboratory, cincinnati, OH. Pilot scale evaluation of photolytic ozonation for trihlomethane precursor removal Glaze,W.H.
  7. Am. Cherm. Soc Mechanism of photolytic ozonation Peyton,G.R.;Glaze,W.H.
  8. Trans. Faraday Soc. v.53 Photochemical reactions of ozone in solution Taube,H. https://doi.org/10.1039/tf9575300656
  9. J. Institution of Water Engineers Some characteristics of ozene in relation to treatment J.M.Taylor
  10. J. of KSEE v.15 no.2 오존, 과산화수소, UV를 이용한 고급산화처리 공정의 kinetic에 관한 연구 강원준
  11. 日本國特許廳(JP), 特許公報(B2) モリプデンの 選擇溶 解方法 ムタ;ミユマザキ;フ