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Synthesis and Characterization of SiO2/Fe2O3 Nanocomposite Particles for Hyperthermia

온열치료용 SiO2/Fe2O3 나노복합입자의 제조와 특성

  • Yu, Ji-Hun (Department of Materials Technology, Korea Institute of Machinery and Materials) ;
  • Lee, Chang-Woo (Division of Materials and Chemical Engineering, Hanyang University) ;
  • Lee, Jai-Sung (Division of Materials and Chemical Engineering, Hanyang University) ;
  • Choa, Yong-Ho (Department of Advanced Materials Engineering, Hanyang University) ;
  • Hofmann, Heinrich (Swiss Federal Institute of Technology at Lausanne(EPFL))
  • 유지훈 (한국기계연구원 재료기술연구소 나노분말재료그룹) ;
  • 이창우 (한양대학교 재료화학공학부) ;
  • 이재성 (한양대학교 재료화학공학부) ;
  • 좌용호 (한양대학교 신소재공학과) ;
  • Published : 2003.09.01

Abstract

The magnetic heating effect of $SiO_2$coated $ \Upsilon-Fe_2$$O_3$nanocomposite particle due to magnetic relaxational loss of superparamagnetic regime was investigated by measuring the generated heat from nanocomposite particles in alternative applied magnetic fields. The commercial $ \Upsilon-Fe_2$$O_3$nanoparticles were coated by SiO$_2$in water solution with TEOS and the synthesized nanocomposite powders and its magnetic properties were characterized and compared with the raw$ \Upsilon-Fe_2$$O_3$nanoparticles. The 10∼30 nm sized $ \Upsilon-Fe_2$$O_3$. nanoparticles were coated by 5 nm thickness of amorphous $SiO_2$film. The nanocomposite particle has very low Mr and Hc value showing superparamagnetic behavior The magnetic heating effect of nanocomposite particle on surface coating phase of $SiO_2$was discussed in terms of superparamagnetic behaviors of each particles, and their potential for hyperthermia application was evaluated.

Keywords

References

  1. R. K. Gilchrist, R. Medal and W. D. Shorey, R. C. Hanselman, J. C. Parrot and C. B. Taylor, Ann. Surgery, 146, 596 (1057) https://doi.org/10.1097/00000658-195710000-00007
  2. E. Keller, Theory of the magnerization curve of small crystals, in Encyclopedia of Physics, XVIII/2, Ferromagnetism, H.P.J.Wijn Ed. New York: Springer-Verlag, 438 (1996)
  3. S. Chikazumi, Physics of Magnetism, Philadelphia, PA: Lippincott, 1964
  4. L. Neel, C. R. Acad, Sci., 228, 664 (1949)
  5. M. I. Shliomis, Sov. Phus.-Usp., 17, 153 (1963)
  6. D. C. F. Chan, D. B. Kirpotin and P. A. Bunn Jr., 122, 374 (1993) https://doi.org/10.1016/0304-8853(93)91113-L
  7. A. Jordan, P. Wust, H. Fahling, W. John, A. Hinz and R. Felix, Intern. J. Hyperthermia, 9, 51 (1993) https://doi.org/10.3109/02656739309061478
  8. L. D. Landau and E. M. Lifshitz, Electrodynamics of Continuous Media, London, U.K., Pergamon, (1960)
  9. R. Hergt, W. Andra, C. G. d'Ambly, I. Hilger, W. A. Kaiser, U. Richter, and H.-G. Schmidt, IEEE Trans. on Magnetics, 35(5), 3745 (1998) https://doi.org/10.1109/20.718537
  10. B. D. Cullity, Introduction to Magnetic Materials, Addison-Wesley Publishing Company, Massachusetts, U.S.A., (1972)