오존산화에 의한 염색체수의 색도 제거에 관한 연구

A Study on Removal of Color in Dyeing Wastewater by Ozone Oxidation

  • 정순형 (대구보건대학 보건환경과) ;
  • 최준호 (계명대학교 화학공학과)
  • 발행 : 2003.12.01

초록

This study was conducted to remove the color in dyeing wastewater by ozone oxidation process, and the results were summarized as follows ; The 18.3% of BOD and 56.3% TOC were removed as decreasing with pH 1 in dyeing wastewater, containing the polyester reducing process. It showed that terephthalic acid was precipitated at low pH. The color of dyeing wastewater was removed by the first order reaction, and the reaction rate constants at pH 3, 7, 12 were investigated $0.234{\;}min^{-1},{\;}0.215{\;}min^{-1}{\;}and{\;}0.201{\;}min^{-1}$ respectively. It showed that color was more effectively removed with direct reaction of ozone than radical reaction(non-direct reaction). As increasing of the water temperature, the reaction rate constants were increased slightly. It indicated that activity of ozone was improved at high water temperature.

키워드

참고문헌

  1. 嶺南大學校 環境工學科 碩士學位論文 浮上메디아 生物膜-凝集工程에 의한 染色廢水處理 尹泰漢
  2. Chemical Industry and Technology v.11 no.3 Chemical Oxidation에 의한 有機性廢水의 處理 李東水
  3. Proceeding of the First International Symposium v.1 Ozonation of Volatile and Semi-Volatile Compuounds for Groundwater Treatment, Chemical Oxidation Jack Musterman
  4. Preceeding of the 9th Ozone World Congress v.1 Decomposition of Ozone in Aqueous Solution H.Sugimitsu;S.Okazaki;T.Moriwaki
  5. Handbook of Ozone Technology and Application v.1 Mechanisms, Rates and Selectivities of Oxidation of Organic Compounds Initiated by Ozonation in Water R.G.Rice
  6. Ozone in water Treatment, Cooperative Research Report Reaction with Aquatic Humic Substances B.L.David;A.Reckhow;R.B.Deborah
  7. Preceeding of the 9th Ozone World Congress v.1 Molecular Weight Characterization of Color Constituents and Subsequent Removal by Ozone and Actived Carbon Adsorption R.A.Sierka;G.L.Amy;J.Renna
  8. Ozone in water Treatment, Cooperative Research Report Treatment for Color Removal B.L.David;A.Reckhow;R.B.Deborah
  9. Ozone in water Treatment, Cooperative Research Report Oxidation of Synthetic Chemicals B.L.David;A.Reckhow;R.B.Deborah
  10. Preceeding of the 9th Ozone World Congress v.2 The Effect of Low-Level Pre-ozonation on Organohalide Formation Potential in Three Municipal Effluents E.R.Lehan;D.A.Reckhow
  11. Preceeding of the 9th Ozone World Congress v.1 Advantages of Preozonation in the Upgrading of the Mont Valerien Plant in France Y.Richard;P.Jacq
  12. 公定試驗方法(水質編) 東和技術
  13. Standard Methods For Examination of Water and Wastewater(17th)
  14. Preceeding of the 9th Ozone World Congress v.1 Effect of Ozonation on Organics Removal by Coagulation-Flocculation H.Paillard;E.LeFebvre;B.Legube