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Preparation of Poly(oxypropylene-oxyethylene glycol) Block Copolymers Oil Dispersant and Characteristics of W/O Emulsion to Weathering Crude Oils

Poly(oxypropylene-oxyethylene glycol) Block Copolymer계 유분산제의 제조와 Weathering Crude Oil에 대한 W/O 에멀젼 특성

  • Kang, Doo-Whan (Hyperstructured Organic Materials Research Center, Department of Polymer Science and Engineering, Dankook University)
  • 강두환 (고차구조형 유기산업재료 연구센터, 단국대학교 고분자공학과)
  • Published : 2003.09.30

Abstract

Poly(oxypropylene-oxyethylene glycol) block copolymer(PBC) oil dispersant, which has low toxicity, high biodegradability, and an excellent dispersion efficiency to crude oils and weathered W/O emulsion was prepared by blending PBC, poly(oxyethylene) oleate, and sorbitan monooleate. The dispersing efficiency was measured by swirling flask method. The PBC oil dispersant had an excellent dispersing efficiency to weathered oil products formed as stable W/O emulsion, and the low toxicity, such as 4000 ppm to Oryzias Latipes(24 hr, TLM), Brine Shrimp Artemia(24 hr, TLM).

Keywords

References

  1. E. C. Birchard, "Oil and Dispersants inCanadian Seas-Research Appraisal and Recommendations", EPS, Ottawa (1982)
  2. J. R. Payne and C. R. Phillips,"Petroleum Spills in the MahneEnvironment : The Chemistry andFormation of Water-in-Oil Emulsionsand Tar Balls", Lewis Pub. Inc.,Michigan (1985)
  3. D. Mackay, "Formation and Stability ofWater-in Oil Emulsion", IKU, Trondheim,Norway (1987)
  4. S. L. Ross, "An Expehmental Study ofthe Oil Spill Treating Agents that Inhibit Emulsification and Promote Dispersion", Report EE-87, Environment Canada,Ottawa (1986)
  5. A. L. Bridie, Matine Pott. Bull., 11, 343(1980)
  6. K. S. Yeom, D. W. Kang, and W. K.Kim, J. Kore. OiI Chem. Soc., 14, 29(1997)
  7. K. S. Yeom, D. W. Kang, W. K. Kim, N.J. Jhung, and J. W. Whang, J. Korea. Oit Chem. Soc., 15, 59 (1998)
  8. H. F. Eicke, "Aqueous Nanophase inLiquid Hydrocarbons Stabilized by Ionic Surfactants", Chapter 2, p. 41, Eicke andParfitt, Marcel Dekker, New York (1987)
  9. S. E. Friberg, "Stabilization of InverseMicelles by Nonionic Surfactants",Chapter 3, P. 93, Friberg and Pierre Bothorel, CRC Press, Flohda (1987)
  10. C. D. Getter and B. J. Baca, "A Lab.Approach for Determining the Effect ofOils and Dispersants on Mangroves", p.5, ASTM, Philadelphia (1984)
  11. P. S. Daling, Description of Lab. Methodsin PART 1 of the DIWO-Project a Technical Report, IKU, Trondheim, Norway (1988)