일본 노지채소 집약 재배지역 토양 침출수 중의 NO3-N 농도와 질소 안정동위원소 자연존재비(δ15N)

Concentrations and Natural 15N Abundances of NO3-N in Groundwater and Percolation Water from Intensive Vegetable Cultivation Area in Japan

  • Park, Kwang-Lai (National Institute of Agricultural Science and Technology, RDA) ;
  • Choi, Jae-Seong (National Honam Crop Experiment Station, RDA) ;
  • Baek, Hyung-Jin (National Institute of Agricultural Biotechnology, RDA) ;
  • Kim, Won-Il (National Institute of Agricultural Science and Technology, RDA) ;
  • Jung, Goo-Bok (National Institute of Agricultural Science and Technology, RDA) ;
  • Yun, Sun-Gang (National Institute of Agricultural Science and Technology, RDA) ;
  • Cho, Jin-Kyu (Kimpo College)
  • 투고 : 2003.05.17
  • 심사 : 2003.05.30
  • 발행 : 2003.06.30

초록

질소 안정동위체 자연존재비(${\delta}^{15}N$)측정을 통해 노지 채소 재배토양에서 침출되어 지하로 이동하는 $NO_3-N$의 동태를 조사한 결과는 다음과 같다. 1) 3 m 관정수와 6 m 관정수의 $NO_3-N$ 농도 평균값은 각각 25.7 및 $2.8mg\;L^{-1}$이었으며, ${\delta}^{15}N$는 +3.6 및 +4.7‰이었다. 2) 암거배수의 $NO_3-N$ 농도와 ${\delta}^{15}N$의 평균은 각각 $35.5mg\;L^{-1}$와 +6.6‰로 토양 침투수는 즐인 선상지 전체로부터 모아지며 비교적 민감하게 화학비료, 가축분 퇴비 유래 질소농도의 변화를 반영하였다. 3) 단지 말단부의 용출수의 $NO_3-N$ 농도와 ${\delta}^{15}N$의 평균은 각각 $19.4mg\;L^{-1}$ 및 +7.9‰로서 채소 재배지대의 복류수 중에는 축산폐기물 유래가 침투되어 있는 것을 나타냈다. 4) 본 지구의 채소재배 토양의 ${\delta}^{15}N$은 2 N KCl 추출 가용태 질소로서 +6.1‰, 질산태 질소로서 +5.1‰이며, 주로 사용되는 화학비료의 전질소의 ${\delta}^{15}N$은 질산 억제비료가 -6.1‰, 그리고 완효성비료가 2.2‰이었다.

Nitrate-N concentrations and the corresponding ${\delta}^{15}N$ values were determined with water samples collected periodically from artesian wells (3 and 6 m deep), underdrainage and gushout waters in a Welsh onion cultivated area in the Kushibiki Fan, Saitama Prefecture, Japan. Average $NO_3-N$ concentrations in waters from 3 and 6 m wells were 25.7 and $2.8mg\;L^{-1}$, whereas ${\delta}^{15}N$ values were 3.6 and 4.7‰, respectively. The $NO_3-N$ concentration and ${\delta}^{15}N$ value of the underdrainge water were $35.5mg\;L^{-1}$ and 6.6‰, reflecting rapid input of chemical fertilizers and farmyard manure. The mean values of $NO_3-N$ concentration and ${\delta}^{15}N$ in the gushout water flown out of the edge of Kushibiki Fan were $19.4mg\;L^{-1}$ and 7.9‰, respectively. As a results the ${\delta}^{15}N$ values of the gushout water were higher than those of the artesian wells and underdrinage water. The ${\delta}^{15}N$ values of total-N and $NO_3-N$ of the soils were 6.1 and 5.10‰, respectively, while those for nitrification-inhibitor containing fertilizer and slow-release fertilizers were -6.1 and -2.2‰, respectively.

키워드

참고문헌

  1. Choi, W.J., S.M. Lee, and H.M. Ro. 2002. Evalulation ofnitrate contamination sources of unconfined groundwaterin the north Han river basin of Korea using nitrogenisotope ratios. Geosci.J.6:47-55 https://doi.org/10.1007/BF02911335
  2. Choi W.J., S.M. Lee, and H.M. Ro. 2003. Evaluation ofcontamination sources of groundwater $NO_{3-}$ usingnitrogen isotope data : a review. Geosci. J. 7: 81-87 https://doi.org/10.1007/BF02910268
  3. Hidaka S. 1991. Measurement of nitrogen circulation ingroundwater using land and paddy field chain. SoilWater Research Report 8:70-89
  4. Hidaka S. 1992. Effect of fertilizer establish examination inSaitama prefecture. Ferilizer Report 1:37-39
  5. Kawanishi T., N.H. Kiho, Y.O. Ozaki, and T.K.Yoneyama. 1991. Measurement of $^{15}N/^{14}N$ fraction coefficient by denitrification process. Jpn. J. Soil SciPlant Nutr. 62:424-426
  6. Koh, Y.K, D.S. Bae, C.S. Kim, K.S. Kim, H.J. Chung, andS.Y. Kim. 2001. Consideration of the groundwater rechargebased on environmental istopic characteristics of the small basin in the yeosu area J. KoSSGE. 6:93-106
  7. Kicitler, C.W., and D.C. Jones. 1975. Natural soil nitratethe course of the nitrate contamination of groundwater inRunnels county, Texas. Groundwater 13:53-61
  8. Kuchida, K., K. Kato, M. Suzuki, and S. Miyoshi. 2000.Utilization of the information from M. semispinaliscapitis and M. semis pinatis dorsi by computer imageanalysis on BMS number prediction. Jpn. J. Soil Sci.Plant Nutr. 71:305-310
  9. Kumazawa, K. 1999. Situation of nitrate pollution ingroundwater. Jpn. J. Soil Sci. PlantNutr. 70:207-213.Nisio, M. 2001. Analysis of the actual state of nitrogenapplication in arable farming in Japan. Jpn. J. Soil Sci.Plant Nutr. 72:513-521
  10. Oh, Y.K. and I. H. Hyun, 1997. Estimation of nitrate-nitrogen contamination sources in Cheju island groundwater using $\delta^{15}N$ values. J. Kor. Sci. Groundwater4:1-4
  11. Park, K.L. 1996. Variation of ammonium in solution due tothe evaporation of ammonia. Jpn. J. Soil Sci. Plant Nutr67:314-316
  12. Spalding, R.F, M.E. Exner, C.W. Lindau, and D.W. Eaton.1982. Investigation of sources of groundwater nitrate contamination in the Burbank-Wallula area of Washineton, USA. J. Hydrol. 58:307-324 https://doi.org/10.1016/0022-1694(82)90041-5
  13. Song, Y.C, Y.K. Koh, and J. G. U, 1999. Estimation of nitrate sources in Cheju island groundwater using $\delta^{15}N$. J.Kor. Sci. Groundwater 6:107-110
  14. Tamura. Y., Y. Yamamoto, K.L. Park, and K. Kumazawa.2000. Nitrate nitrogen and $\delta^{15}N$ values of the spring waters in the Tamagawa basin. Jpn. J. Soil Sci. Plant Nutr. 71:488-493
  15. Yamamoto Y, K.L. Park, Y.H. Nakanishi, S. Kato, and K.Kumazawa. 1995. Nitrate concentrations and $\delta^{15}N$ values of groundwater in the Miyakojima island. Jpn. J. SoU Sci Plant Nutr. 66:18-26
  16. Yun, J.A., and K.K. Kim. 2000. Geochemistry and stableisotopes of carbonated waters in South Korea. J. Kor. Sci.Groundwater-7:116-124