Properties of Starch Isolated from Wet-milled Rice after Steeping at Elevated Temperatures for Annealing Effect

Annealing 수침처리에 따른 습식제분 쌀가루의 전분 특성

  • Lee, Young-Tack (Department of Food and Bioengineering, Kyungwon University) ;
  • Yoo, Moon-Sik (Department of Food and Bioengineering, Kyungwon University) ;
  • Lee, Bo-Ram (Department of Food and Bioengineering, Kyungwon University) ;
  • Park, Jong-Hyun (Department of Food and Bioengineering, Kyungwon University) ;
  • Chang, Hak-Gil (Department of Food and Bioengineering, Kyungwon University)
  • 이영택 (경원대학교 식품생물공학과) ;
  • 유문식 (경원대학교 식품생물공학과) ;
  • 이보람 (경원대학교 식품생물공학과) ;
  • 박종현 (경원대학교 식품생물공학과) ;
  • 장학길 (경원대학교 식품생물공학과)
  • Published : 2004.06.30

Abstract

Rice was steeped at elevated temperatures of $40,\;50,\;or\;60^{\circ}C$ for 2 hr, and physicochemical properties of starches isolated from wet-milled rice flour were investigated. Steeping at elevated temperatures slightly decreased lightness of rice starch, while increased yellowness and redness. Average granule size of rice starch was decreased by steeping treatment. Swelling power and solubility increased as temperature increased. Starch from rice steeped at $40^{\circ}C$ displayed highest swelling power and solubility. Differential scanning calorimetry data of starch obtained from steeped rice at $60^{\circ}C$ showed increased onset and peak temperatures, with narrower gelatinization temperature range, suggesting partial annealing effect. Pasting properties of starch measured by Rapid Visco-Analyzer indicated increased peak viscosity due to rice steeping at $40^{\circ}C$. Peak and breakdown viscosities decreased at $50\;and\;60^{\circ}C$, whereas setback and final viscosities increased.

$40,\;50,\;60^{\circ}C$의 실온 이상의 상승된 온도에서 쌀을 수침처리한 후 습식제분한 쌀가루로부터 분리한 전분의 특성을 조사하였다. 수침처리하지 않은 대조구 쌀 전분에 비해 수침처리한 쌀 전분의 명도는 약간 감소하였으며 전분의 평균 입자크기는 다소 감소하였다. 전분의 팽윤력과 용해성은 대조구보다 전반적으로 높았으며 특히 $40^{\circ}C$에서 수침처리한 쌀 전분에서 가장 높았지만 그 이상의 처리온도에서는 다소 감소하는 경향이었다. DSC 호화개시온도, 호화정점온도는 $40^{\circ}C$$50^{\circ}C$ 수침처리한 쌀 전분에서 감소하였고 호화엔탈피는 증가하였으나 $60^{\circ}C$ 수침처리에서는 호화개시온도와 호화정점온도가 증가하였고 호화온도범위가 감소하여 전분의 annealing 현상이 나타남을 제시해 주었다. $40^{\circ}C$에서 수침처리한 쌀 전분은 Rapid Visco-Analyzer(RVA) 최고점도가 증가한 반면, $50^{\circ}C$$60^{\circ}C$에서는 최고점도가 감소하였고 breakdown이 감소하였으며 최종점도는 증가하여 setback이 높게 나타났다.

Keywords

References

  1. Nishita KD, Bean MM. Grinding methods: Their impact on rice flour properties. Cereal Chem. 59: 46-49 (1982)
  2. Bean MM. Rice flour-its functional variations. Cereal Foods World 31: 477-481 (1986)
  3. Park YK, Seog HM, Nam YJ, Shin DW. Physicochemical properties of various milled rice flours. Korean J. Food Sci. Technol. 20: 504-510 (1988)
  4. Chiang PY, Yeh AI. Effect of soaking on wet-milling of rice. J. Cereal Sci. 35: 85-94 (2002) https://doi.org/10.1006/jcrs.2001.0419
  5. Kim SK, Bang JE. Physicochemical properties of rice affected by steeping conditions. Korean J. Food Sci. Technol. 28: 1026-1032 (1996)
  6. Choi EJ, Kim HS. Physicochemical and gelatinization properties of glutinous rice flour and starch steeped at different conditions. J. Korean Soc. Food Sci. Nutr. 26: 17-24 (1997)
  7. Stute R. Hydrothermal modification of starches: The difference between annealing and heat-moisture treatment. Starch/Starke 44: 205-214 (1992) https://doi.org/10.1002/star.19920440603
  8. Jacobs H, Eerlingen RC, Clauwaert W, Delcour JA. Influence of annealing on the pasting properties of starches from varing botanical sources. Cereal Chem. 72: 480-487 (1995)
  9. Teste RF, Debon SJJ. Annealing of starch: A review. Int. J. Biol. Macromol. 27: 1-12 (2000) https://doi.org/10.1016/S0141-8130(99)00121-X
  10. Shandera DL, Jackson DS. Effect of corn wet-milling conditions (sulfur dioxide, lactic acid, and steeping temperature) on starch functionality. Cereal Chem. 73: 632-637 (1996)
  11. Yamamoto A, Shirakawa K. Annealing of long-term stored rice grains improves gelatinization properties. Cereal Chem. 76: 646- 649 (1999) https://doi.org/10.1094/CCHEM.1999.76.5.646
  12. Yamamoto K, Sawada, S, Onogaki T. Properties of rice starch prepared by alkali method with various conditions. Denpun Kagaku 20: 99-104 (1973)
  13. AACC. Approved Methods of the AACC. 10th ed. American Association of Cereal Chemists, St. Paul, MN, USA (2000)
  14. AOAC. Official Methods of Analysis, 15th ed. Association of Official Analytical Chemists, Washington, DC, USA (1990)
  15. Schoch TJ. Swelling power and solubility of granular starches: Whole starches and modified starches. Vol. 4, p. 106. In: Methods in Carbohydrate Chemistry. Whistler RL (ed). Academic Press, New York, NY, USA (1964)
  16. Dubois M, Gilles KA, Smith F. Colorimetric method for determination of sugars and related substance. Anal. Chem. 28: 350-356 (1956) https://doi.org/10.1021/ac60111a017
  17. Lund DB. Influence of time, temperature, moisture, ingredients, and processing conditions on starch gelatinization. Crit. Rev. Food Sci. Nutr. 20: 249-252 (1987) https://doi.org/10.1080/10408398409527391
  18. Hayakawa T, Seo SW, Igaue I. Electron microscopic observation of rice grain. I. Morphology of rice starch. J. Jpn. Soc. Starch Sci. 27: 173-179 (1980) https://doi.org/10.5458/jag1972.27.173
  19. Kim SK, Chang BS, Lee SJ. Ultrasturcture of compound starch granules and protein bodies of starchy endosperm cell in rice. J. Korean Soc. Agric. Chem. Biotechnol. 39: 379-383 (1996)
  20. Ko YD, Choi OJ, Park SK, Ha HS, Sung NK. Changes in physicochemical properties of rice starch from rice stored at different conditions. Korean J. Food Sci. Technol. 27: 306-312 (1995)
  21. Leach HW, McCowen LD, Schoch TJ. Structure of the starch granule. I. Swelling and solubility patterns of various starches. Cereal Chem. 36: 534-544 (1959)
  22. Wong RBK, Lelievere J. Comparison of the crystallinities of wheat starches with different swelling capacities. Starch 34: 159-165 (1982) https://doi.org/10.1002/star.19820340504
  23. Lii CY, Tsai ML, Tseng KH. Effect of amylose content on the rheological properties of rice starch. Cereal Chem. 73: 415-420 (1996)
  24. Tsai ML, Li CF, Lii CY. Effects of granular structures on the pasting behaviors of starches. Cereal Chem. 74: 750-757 (1997) https://doi.org/10.1094/CCHEM.1997.74.6.750
  25. ester RF, Morrison WR. Swelling and gelatinization of cereal starches. I. Effect of amylopectin, amylose, and lipids. Cereal Chem. 67: 551-557 (1990)
  26. Kugimiya M, Donovan JW, Wong RY. Phase transitions of amylose- lipid complexes in starches: A calorimetric study. Starch/ Starke 32: 265-270 (1980) https://doi.org/10.1002/star.19800320805
  27. Stevens DJ, Elton GAH. Thermal properties of starch/water system. I. Measurement of heat gelatinization by differential scanning calorimeter. Starch/Starke 23: 8-11 (1971) https://doi.org/10.1002/star.19710230104