Korean Journal of Optics and Photonics (한국광학회지)

Optical Society of Korea (한국광학회)
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Study on the photo-induced refractive index change of diarylethene derivative using fiber-to-planar waveguide coupler

광섬유-평면도파로 결합기를 이용한 광변색성 디아릴에텐 유도체의 광유도 굴절률 변화에 관한 연구

  • 조강민 (경북대학교 센서공학과) ;
  • 윤정현 (경북대학교 센서공학과) ;
  • 임선정 (서울대학교 재료공학부) ;
  • 박수영 (서울대학교 재료공학부) ;
  • 강신원 (경북대학교 전자전기공학부)
  • Published : 2004.04.01
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Abstract

We have manufactured and characterized the fiber-to-Planar Waveguide Coupler for analysis of the photo-induced refractive index change of DM-BTE .(l,2-bis[2,5-dimethylthio-phen-3-yl]-hexafluorocyclopentene) When irradiated with ultraviolet light, the colorless diarylethene(DM-BTE)-crystal turned red while keeping the crystal shape. The red color was bleached by irradiation with visible light(λ＞450 nm). The resonant wavelength was shifted and recovered owing to the refractive index variation of the planar waveguide because of its photo-functional properties on exposure to UV and visible light. The wavelength responses of this switch by UV exposure were measured as 0.057 nm/sec with saturation time of 60 seconds. and when illuminated by visible light, resonance wavelength variations were measured as 0.028 nm/sec, with recovery time of 140 seconds.

광섬유와 평면도파로 결합기의 소산장 결합을 이용하여 디아릴에텐 유도체 DM-BTE(1,2-bis[2,5-dimethylthio-phen-3-yl]-hexafluorocyclopentene)의 광유도 굴절률 변화(photo-induced refractive index change)에 관하여 그 특성을 평가하였다. DM-BTE가 분산된 평면도 파로는 자외선과 가시광선(λ＞450 nm)의 조사에 의해 광변색 반응이 가역적으로 진행되었으며 굴절률변화에 의한 공명 파장 또한 가역적으로 이동하였다. 광변색 반응이 진행되는 동안 평면도 파로의 결정상태(crystal shape)는 일정한 형태를 유지하였으며, 자외선 조사시간에 대한 소자의 파장응답은 0.057 nm/sec 이었고 포화시간은 60 sec로 나타났으며, 가시광선이 다시 조사될 때의 공명파장의 변화는 0.028 nm/sec 이었고, 복귀시간은 140 sec로 측정되었다.

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