Journal of the Korean Crystal Growth and Crystal Technology (한국결정성장학회지)

The Korea Association of Crystal Growth (한국결정성장학회)
권호 표지

Structural change of cobalt dodecanesulfate

Cobalt dodecanesulfate의 구조변화

  • Published : 2004.04.01
Download PDF
⟨ Previous Next ⟩

Abstract

The layered structure of cobalt dodecanesulfate was synthesized. A phase transition takes place at various temperature ranges and results in a drastic change of the layer distance. A monolayer structure of cobalt dodecanesulfate at room temperature transformed to a bilayer structure as a dehydrated form at high temperature.

층상 구조의 cobalt dedecanesulfate 화합물을 합성하였다. 여러 온도 영역에서 상 전이가 일어나면서 층간 거리의 큰 변화가 생겼다. 상온에서 단일 층 구조의 cobalt dodecanesulfate 화합물이 고온에서 탈수된 화합물의 이중층의 구조로 변화되었다.

Keywords

References

  1. J. Mater. Chem. v.12 Intercalation chemistry of layered double hydroxides: recent developments and applications A.L.Khan;D.O'Hare https://doi.org/10.1039/b204076j
  2. Angew. Chem. Int. Ed v.39 Inoranic layered double hydroxides as nonvirol vectors J.H.Choy;S.Y.Kwak;Y.J.Jeong;J.S.Park
  3. Bull. Kor. Chem. Soc. v.22 Intercalation of functional organic molecules with pharmaceutical, cosmeceutical and nutraceutical functions into layered double hydroxides and zinc basic salts S.H.Hwang;Y.S.Han;J.H.Choy
  4. J. Colloid Interface Sci. v.123 Anionic surfactants between double metal hydroxide layers H.Kopka;K.Beneke;G.Lagaly https://doi.org/10.1016/0021-9797(88)90263-9
  5. J. Mater. Chem. v.9 Hybrid organic-inorganic layered compounds prepared by anion exchange reaction: correlation between structure and magnetic properties V.Laget;C.Hornick;P.Rabu;M.Drilon https://doi.org/10.1039/a805870i
  6. J. Mater. Chem. v.7 Preferectial intercalation of isomers of anthraquinone sulfonate ions into layered double hydroxides W.K.Kuk;Y.D.Huh https://doi.org/10.1039/a702349i
  7. Chem. Rev. v.95 Photofunctions of intercalation compounds M.Ogawa;K.Kuroda https://doi.org/10.1021/cr00034a005
  8. Eur. J. Inorg. Chem. Structure and magnetism of a polycrystalline transition metal soap - Co[OOC${(CH₂)}_{10}$COO](H₂O)₂ J.M.rueff;N.Masciocchi;P.Rabu;A.Sironi;A.Skoulios
  9. Chem. Eur. J. v.8 Synthesis, structure and magnetism of homologous series of polycrystalline cobalt alkane mono- and dicarboxylate soaps J.M.Rueff;N.Masciocchi;P.Rabu;A.Sironi;A.Skoulions https://doi.org/10.1002/1521-3765(20020415)8:8<1813::AID-CHEM1813>3.0.CO;2-G
  10. Chem. Mater. v.13 Mn₂(H₂O) [O₂C${(CH₂)}_nCO₂]₂(n = 3-12): replication of an inorganic monolayer in three-dimensional (dicarboxylato) manganese (Ⅱ) Y.J.Kim;E.W.Lee;D.Y.Jung https://doi.org/10.1021/cm010219s
  11. Inorg. Chem. v.35 Magnetic properties of Cu₂(OH)₃(alkanecarboxylate) compounds: drastic modification with extension of the alkyl chain W.Fujita;K.Awaga https://doi.org/10.1021/ic950965x
  12. Inorg. Chem. v.36 EXAFS study of two-dimensional organic/inorganic hybrid nanocomposites, Cu₂(OH)₃(n-$C_m{H}_{2m+1}$COO) (m = 0,1,7,8,9): structural modification in the inorganic layer induced by the interlayer organic molecule W.Fujita;K.Awaga;T.Yokoyama https://doi.org/10.1021/ic960787n
  13. J. Am. Chem. Soc. v.119 Control of inorganic layer thickness in self-assembled iron oxide/surfactant composites S.H.Tolbert;P.Slieger;G.D.Stucky;S.M.J.Aubin;C.C.Wu;D.N.Hendrickson https://doi.org/10.1021/ja970695c
  14. J. Am. Chem. Soc. v.119 Reversible structural transformation and drastic magnetic change in a copper hydroxides intercalation compound W.Fujita;K.Awaga https://doi.org/10.1021/ja970239o
  15. Handbook of chemistr and physics(70th ed.) R.C.Weast