NOx Gas Absorption in the Green Tobacco

  • Oh, In-Hyeog (KT&G Central Research Institute) ;
  • Michael D. Boyette (Department of Biological and Agricultural Engineering, North Carolina State University)
  • Published : 2004.06.01

Abstract

On-going research has recently documented the certain tobacco specific nitrosamines (TSNAs) are formed during the curing process by an interaction of nitrogen oxides (NOx) contained in combustion gases and naturally occurring compounds in the tobacco leaves. Although the role of TSNAs in human health have been extensively investigated, little research has been conducted on the physical and chemical phenomena relating to their formation during curing. In this paper, we developed a mathematical model for describing NOx absorption into green (uncured) tobacco. We found considerable uptake of NOx by green tobacco with variations related to several factors. Specifically, tobacco from the lower stalk positions (bottom one third) absorbs more NOx gas per unit weight than tobacco from upper stalk positions. Additionally, the green tobacco packed with a density of 0.103 g/㎤ absorbs more NOx gas per unit weight than either 0.0443 g/㎤ or 0.0739 g/㎤. Further, the NOx absorption increases proportionally with temperature with the maximum absorption point around 4$0^{\circ}C$.

Keywords

References

  1. Andersen, R. A., Burton, H. R., Fleming, P. D., Hamilton Kemp, T. R. and Gay, S. L. (1987) Effects of air curing environment on alkaloid derived nitrosamines in burley tobacco. IARC Sci. Publ. 84: 451-455
  2. Boyette, M. D. and Hamm, L. A. (2001) Resultsof year 2000 TSNA sampling program influe cured tobacco. Rec. Adv. Tob. Sci. 27:17 - 22
  3. Dong, M., Schmeltz, I., Jacobs, E. and Hoffmann,D. (1978) Aza arenes in tobacco smoke. J.Anal. ToxicoI. 2: 21 - 25 https://doi.org/10.1093/jat/2.1.21
  4. Johnstone, R. A. W., Quan, P.M. and Caruthers, W. (1962) Composition of cigarette smoke: some low boiling components. Nature 755:1267 -1269
  5. Long, R. C., Wahlberg, I., Brandt, P. and Wiemik, A. (1999) The development of lowTSNA air cured tobaccos, II. Effects of curing conditions and post curing drying onTSNA formation. Coresta Proceeding ST8
  6. Nestor, T. B., Gentry, J. S., Peele, D. M., Riddick, M. G., Conner, B. T. and Edwards, M. E. (2003) Role of Oxides of Nitrogen inTobacco Specific Nitrosamine Formation inFlue Cured Tobacco. Beitr. Tabakforsch. 20(7): 467-475
  7. Neurath, G. and Ehmke, H. (1964) Untersuchungen uiber den Nitratgehalt des Tabaks [Studies on the nitrate content of tobaccos J. Beitr. Tabakforsch. 2: 333-344
  8. Peele, D. M. and Gentry, J. S. (1999) Formation of tobacco specific nitrosaimnes in flue cured tobacco. Coresta Proceeding ST6
  9. Pradhan, M. P. and Joshi, J. B. (2000) Absorption of NOx gases in plate column: Selective manufacture of sodium nitrite. Chemical Engineering Science 55: 1269-1282 https://doi.org/10.1016/S0009-2509(99)00397-8
  10. Wahlberg, I., Long, R. C., Brandt, P. and Wiernik, A. (1999) The development of low TSNA air cured tobaccos. I. Effects of tobacco genotype and fertilization on the formation of TSNA. Coresta Proceeding ST7