DOI QR코드

DOI QR Code

EDLC용 CMC+PTFE 혼합바인더 전극의 전기적, 기계적 특성

Electric and Mechanical Properties of CMC+PTFE Binary Binder Electrode for Electric Double Layer Capacitor

  • 김익준 (한국전기연구원 전지연구그룹) ;
  • 이선영 (한국전기연구원 전지연구그룹) ;
  • 문성인 (한국전기연구원 전지연구그룹)
  • 발행 : 2004.10.01

초록

This work describes the effect of electrode binder on the characteristics of electric double layer capacitor. Among carboxymethylcellulose (CMC), Polyvinylpyrrolidone (PVP), Polyvinyl Alcohol (PVA), and Polyvinylidene Fluoride (PVDF), the unit cell using CMC showed good rate capability at current densities between 2.5 mA/$\textrm{cm}^2$~100 mA/$\textrm{cm}^2$. However, CMC as a binder is incongruent, because the electrode bound with CMC is rigid and easy to crack during a press and winding process for fabrication of capacitor. The unit cell capacitor using the electrode bound with binary binder composed of CMC and Polytetrafluoroethylene (PTFE), especially in composition CMC : PTFE =60 : 40 wt.%, has exhibited the better mechanical properties than those of the unit cell with CMC. On the other hand, the mechanical properties of CMC+PTFE electrode, coated on underlayer composed of CMC and carbon black, were much improved.

키워드

참고문헌

  1. B. E. Conway, 'The electrolyte factor in supercapacitor design and performance: conductivity, ion-pairing and solvation', Proceedings of The 4th International Seminar on Double Layer Capacitors and Similar Energy Storage Devices, Deerfield Beach, FL, p. 12, 1994
  2. B. E. Conway, 'Transition from supercapacitor to battery behavior in electrochemical energy storage', J. Electrochem. Soc., Vol. 138, p. 1539, 1991 https://doi.org/10.1149/1.2085829
  3. S. Sarangapani, B. V. Tilak, and C. P. Chen, 'Materials for electrochemical capacitprs', J. Electrochem. Soc., Vol. 143, p. 3791, 1996 https://doi.org/10.1149/1.1837291
  4. J. DeGaynor and R. Johnston, 'Double layer capacitors for automotive applications', Proceedings of The 4th International Seminar on Double Layer Capacitors and Similar Energy Storage Devices, Deerfield Beach, FL, p. 12, 1994
  5. 김익준, 이선영, 도칠훈, 문성인, '전기이중층 커패시터의 특성에 미치는 혼성 도전재의 영향', 전기전자재료학회논문지, 17권, p. 107, 2004
  6. 야노경제연구소, '전기이중층 콘덴서 시장의 철저연구', 2002
  7. 도칠훈, 최상진, 문성인, '유기전해액에서 루테늄산화물 전극의 전기화학적 특성', 한국전기전자재료학회 2002하계학술대회논문집, p. 1125, 2002
  8. 김지훈, 엄승욱, 문성인, 윤문수, 김주용, 육경창, 박정후, '$MnO_{2}$ 입자크기에 따른 아연 공기전지의 특성연구', 한국전기전자재료학회 2002하계학술대회논문집, p. 1129, 2002

피인용 문헌

  1. Effect of Acid / Heat Treatment on Electric Double Layer Performance of Needle Cokes vol.12, pp.1, 2009, https://doi.org/10.5229/JKES.2009.12.1.034