DOI QR코드

DOI QR Code

The Effects of Suspension Composition on Defects in Aqueous Tape Casting of Alumina Ceramics

  • Shin, Hyo-Soon (Central R&D Institute, Samsung Electro-Mechanics Co. Ltd.,)
  • Published : 2004.09.01

Abstract

In aqueous tape casting of alumina slurry systems, the relationships between the suspension compositions and the defects of the dried tapes were discussed. The suspensions compositions were controlled with the ratios of the solids, water and organics binder contents. The effects of the thickness of dried tape and kinds of binder system were also examined. In the defect free region, the apparent viscosity showed nearly same value due to the count balancing effect of solid and organic binder content on the apparent viscosity. When water content was constant, increasing solid led to decrease of organic binder content. The defect free region was narrowed with increasing of casting thickness. When linear type acrylic emulsion binders system (D1000 and D 1035) were used, defect free zone formed the belt type in the triangle of solid, water and organic binder content according to the line of constant water contents. However the defect free region was not found in the cross-link type emulsion binder system (D 1050).

Keywords

References

  1. G. N. Howatt, R. G. Breckenridge, and J. M. Brownlow, 'Fabrication of Thin Ceramic Sheets for Capacitors,' J. Am. Ceram. Soc., 30 [8] 237-42 (1947) https://doi.org/10.1111/j.1151-2916.1947.tb18889.x
  2. R. E. Mistler, 'Tape Casting: The Basic Process for Meeting the Needs of the Electronics,' Am. Ceram. Soc. Bull., 69 [6] 1022-26 (1990)
  3. A. Roosen, 'Basic Requirements for Tape Casting of Ceramic Powders' Ceram. Trans., Vol. 1B, Ceramic Powder Science II, Edited by G. L. Messing, E. R. Fuller, Jr., and H. Hausner, The Am. Ceram. Soc. Inc., 675-92 (1988)
  4. D. Hotza and P. Greil, 'Review: Aqueous Tape Casting of Ceramic Powders,' Mater. Sci. Eng., A202 206-17 (1995)
  5. P. Nahass, W. E. Rhine, R. L. Pober, and H. K. Bowen, 'A Comparision of Aqueous and Non-Aqueous Slurries for Tape-Casting, and Dimensional Stability in Dried Tapes,' Ceram. Trans., Vol. 15, Materials and Processes for Microelectronic Systems, Edited by K. M. Nair, R. Pohanka, and R. C. Buchanan, The Am. Ceram. Soc. Inc., 355-64 (1990)
  6. J. F. Kelso and T. A. Ferrazzoli, 'Effect of Powder Surface Chemistry on the Stability of Concentrated Aqueous Dispersions of Alumina,' J. Am. Ceram. Soc., 72 [4] 625-27 (1989) https://doi.org/10.1111/j.1151-2916.1989.tb06185.x
  7. B. Bitterlich, C. Lutz, and A. Roosen, 'Slurries for the Tape Casting Process,' Ceram. Int., 28 [6] 675-83 (2002) https://doi.org/10.1016/S0272-8842(02)00027-5
  8. Y. G. Lin and L. Gao, 'Dispersion of Aqueous Alumina Sus-pensions Using Copolymers with Synergistic Functional Groups,' Mater. Chem. Phys., 82 [2] 362-69 (2003) https://doi.org/10.1016/S0254-0584(03)00268-2
  9. K. Nagata,'Rheology and Aqueous Tape Casting of Acrylic Ester-Acrylic Acid Copolymer Dispersed Alumina,' Ceram. Trans. Vol. 22, Ceramic Powder Science IV, Edited by S.-I. Hirano, G. L. Messing, and H. Hausner, The Am. Ceram. Soc. Inc., 335-40 (1991)
  10. X. Tang and A. T. Donato, 'Aqueous Emulsion Acrylic Binders for Low-Foaming Ceramic Slips,' J. Am. Ceram. Soc., 79 [2] 510-12 (1996) https://doi.org/10.1111/j.1151-2916.1996.tb08155.x
  11. K. Nagata, 'Correlation of Conformation of Acrylic Polymers in Aqueous Suspensions and Properties of Alumina Green Sheets,' Ceram. Trans., Vol. 26, Forming Science and Technology for Ceramics, Edited by M. J. Cima, The Am. Ceram. Soc. Inc., 205-10 (1992)
  12. X. Tang, S. A. Ibbitson, and A. T. Donato, 'Acrylic Emulsion Binder for Tape Casting' Ceram. Trans., Vol. 62, Sci-ence Technology and Commercialization of Powder Synthesis and Shape Forming Processes, Edited by J. J. Kingsley, C. H. Schilling, and J. H. Adair, The Am. Ceram. Soc. Inc., 157-64 (1996)
  13. M. Descamps, M. Mascart, B. Thierry, and D. Leger, 'How to Control Cracking of Tape-Cast Sheets,' Am. Ceram. Soc. Bull., 74 [3] 89-92 (1995)
  14. H. Loest, E. Mitsoulis, and S. Spauszus, 'Free Surface Measurements and Numerical Simulations of Ceramic Tape Casting,' Interceram, 42 [2] 80-4 (1993)
  15. T. J. Soltesz, W. M. Carty, H. J. Miller, T. R. Armstrong, and P. A. Smith, 'A Rheological Process Control Diagram for Tape Casting,' Presented at the\{99^t^h} Annual Meeting of the Am. Ceram. Soc., Cincinnati, USA, April (1997)