DOI QR코드

DOI QR Code

Study of the Enhancement of Magnetic Properties of NdFeB Materials Fabricated by Modified HDDR Process

  • Fu, Meng (Department of Materials, College of Materials & Metallurgy, Northeastern University, Department of Materials, Jiangsu Polytechnic University) ;
  • Lian, Fa-zeng (Department of Materials, College of Materials & Metallurgy, Northeastern University) ;
  • Wang, jie-Ji (Department of Materials, College of Materials & Metallurgy, Northeastern University) ;
  • Pei, Wen-Ii (Department of Materials, College of Materials & Metallurgy, Northeastern University) ;
  • Chen, Yu-lan (Department of Materials, College of Materials & Metallurgy, Northeastern University) ;
  • Yang, Hong-cai (Department of Materials, College of Materials & Metallurgy, Northeastern University)
  • Published : 2004.12.01

Abstract

The HDDR (Hydrogenation-Disproportionation-Desorption-Recombination) process is a special method to produce anisotropic NdFeB powders for bonded magnet. The effect of the modified HDDR process on magnetic properties of $Nd_2Fe_{14}B$-based magnet with several composition $Nd_{11.2}Fe_{66.5-x}Co_{15.4}B_{6,8}Zr{0.1}Ga_x(x=0{\sim}1.0)$ and that of microelement Ga, disproportional temperature and annealing temperature on $_jH_c$, grain size were investigated in order to produce anisotropic powder with high magnetic properties. It was found that modified HDDR process is very effective to enhance magnetic properties and to fine grain size. The addition of Ga could change disproportionation character remarkably of the alloy and could improve magnetic properties of magnet powder. Increasing annealing temperature induces significant grain growth. And grain size produced by modified HDDR process is significantly smaller than those produced by conventional HDDR process.

Keywords

References

  1. R. Nakayama, T. Takeshita, M. Itakura, N. Kuwano, and K. Oki, Appl. Phys. 76, 412-417 (1994) https://doi.org/10.1063/1.357091
  2. S. Besenicar, B. Saje, G. Drazic, and J. Hole. J. Magn. Magn. Mater. 104-107, 1175 (1992). https://doi.org/10.1016/0304-8853(92)90539-Z
  3. T. Takeshita, and R. Nakayama, in: 11th International Workshop on Rare Earth Magnets and Their Appl., Pittsburg, PA, USA. pp. 49-53 (1990)
  4. J. M. Cadogan, and J. M. D. Coey, Appl. Phys. Lett. 48, 442 (1986) https://doi.org/10.1063/1.96525
  5. T. Takeshita, and R. Nakayama, in: 10th Int. Workshop on RE Maanets and their Applications, Kyoto, 551 (1989)
  6. H. Nakamura, K. Kato, D. Book, et al. In: Proc 15th Int Workshop on Rare-Earth Magnets and their Applications. Dresden, Germany, 507 (1998).
  7. G. K. Williamson and W. H. Hall, Acta Metal!. 1, 22 (1953) https://doi.org/10.1016/0001-6160(53)90006-6
  8. K. J. H. Bushow. IEEE Trans Magn. 30, 565 (1994) https://doi.org/10.1109/20.312337