Properties of Urethane-Based IPN Elastomers

우레탄을 기초로 한 IPN 탄성체의 성질

  • Min, Seong-Kee (Division of Applied Chemical Engineering, College of Engineering, Pukyong National University) ;
  • Park, Chan-Young (Division of Applied Chemical Engineering, College of Engineering, Pukyong National University)
  • 민성기 (부경대학교 공과대학 응용화학공학부) ;
  • 박찬영 (부경대학교 공과대학 응용화학공학부)
  • Published : 2004.12.01

Abstract

IPNs have interpenetrating motion and phase separation behavior of independent polymers, respectively, and also these are affected by the physical interaction of polymer components. First of all, 2- and 3-component IPNs based on PU are prepared by combination with two or three components of PU, PMMA, PS and epoxy resin. And then the entire physical properties concerning morphological and mechanical behaviors of these IPNs are measured by employing FT-IR, SEM, Rheovibron, and DSC, etc. Compared with pure component, Tg's of IPN are shifted to higher temperature in all IPN kinds, and these are considered in attribution to internal movement of glass transition temperature or partial phenomenon of interpenetration. Rheovibron measurement results in a broader distribution with peaks of tan${\delta}$ or E", and this morphologically represents a medium degree of partially mixed IPNs in confirmation of SEM photographs.

Keywords