Journal of Korean Ophthalmic Optics Society (한국안광학회지)

The Korean Ophthalmic Optics Society (한국안광학회)
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Study on Poly(triazine bissulfide)s Derivatives being the Synthesized Optical Plastic Material

합성한 광학플라스틱 재료인 Poly(triazine bissulfide)s 유도체에 대한 연구

  • Lee, Y.H. (Research Institute for Basic Sciences, Dongeui University) ;
  • Lee, D.H. (Research Institute for Basic Sciences, Dongeui University) ;
  • Kim, J.J. (Sin-Kwang Chemical Co.) ;
  • Ha, T.W. (Research Institute for Basic Sciences, Kyungsung University) ;
  • Cha, J.W. (Department of Ophthalmic Optics, Shinheung College)
  • 이용희 (동의대학교 기초과학연구소 및 화학과) ;
  • 이동환 (동의대학교 기초과학연구소 및 화학과) ;
  • 김재종 (광화학(주)) ;
  • 하태욱 (경성대학교 기초과학연구소) ;
  • 차정원 (신흥대학 안경광학과)
  • Received : 2004.08.09
  • Published : 2004.12.31
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Abstract

Poly(triazine bissulfide)s were synthesized from 6-dibutylamino-1,3,5-triazine-2,4-dithiol with bis(4-chloro-3-nitrophenyl)sulfone in the presence of the phase transfer catalyst, and from m-dibromide xylene and p-dibromide xylene with 6-dibutylamino-1,3,5-triazine-2,4-dithiol in the presence of cetyltrimethyl ammonium bromide at $70^{\circ}C$ for 24h. We could acquire the good results about solubility, thermal property, and molecular weight to make cast film. These results are important as base for the synthesis of functionalization polymer material being optical plastic material. The maximum algebra viscosity was 0.57~1.40dl/g at the temperature more than $50{\sim}60^{\circ}C$.

Poly(triazine bissulfide)s는 상간이동촉매하에서 bis(4-chloro-3-nitrophenyl)sulfone와 6-dibutylamino-1,3,5-triazine-2,4-dithiol로도 합성하였으며, 또한 m-dibromide xylene와 p-dibromide xylene으로 cetyltrimethyl ammonium bromide와 함께 $70^{\circ}C$에서 24시간 동안 6-dibutylamino-1,3,5-triazine-2,4-dithiol로 반응시켜서도 합성하였다. 캐스트필름을 만들기 위해서 합성한 이들에 대한 용해도, 열적 성질, 평균분자량 등에 대해서 좋은 결과를 얻었다. 이러한 결과는 기능성 광학플라스틱 재료인 고분자물질을 합성하는데 있어서 중요한 것임을 보여주는 것이다. 최대대수정도는 $50{\sim}60^{\circ}C$이상에서 0.57~1.40dl/g의 값을 보였다.

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