A Study on the Phosphorus Removal from Wastewater by Eggshell

난각을 이용한 폐수중의 인 제거에 관한 연구

  • 김민수 (광운대학교 환경공학과) ;
  • 강선홍 (광운대학교 환경공학과)
  • Received : 2004.01.10
  • Accepted : 2004.03.19
  • Published : 2004.04.15

Abstract

This study is a fundamental research to test the applicability of abandoned eggshell as seed material for crystallization reaction. Eggshell was calcinated at $850^{\circ}C$ and ground to lesser than 0.42mm. The calcination characteristics of eggshell were examined by X-ray diffraction (XRD). The effect of initial calcium concentration, alkalinity, reaction temperature condition, seed dosage were studied by batch test. For the low concentration sample(P concentration is under 50mg/L), more than 90% of P can be removed. The effect of initial calcium concentration(0~120mg/L) was performed. At the result of the test, more than 50mg/L calcium concentration has high removal efficiency. Alkalinity effect was studied for synthetic solution(100mg/L initial P, 50mg/L calcium, 0.025% seed dosage) with 0~300mg/L bicarbonate alkalinities. For synthetic solution(100mg/L initial P, 50mg/L calcium, 100mg/L bicarbonate alkalinity, 0.025% seed dosage), the phosphorus concentration was examined with $10{\sim}35^{\circ}C$. In addition, calcinated eggshell was injected to swine wastewater to test the applicability to actual wastewater.

Keywords

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