Korean Journal of Materials Research (한국재료학회지)

Materials Research Society of Korea (한국재료학회)
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The Effect of NiO Addition to the PNN-PZT Piezoelectric Ceramics on Piezoelectric Properties

Pb(Ni1/3Nb2/3)O3-PZT 세라믹스 고용체에서 과잉 NiO첨가에 따른 압전특성 변화

  • Choi Y. G. (Department of Materials Science and Engineering/Research Center for Sustainable Eco-Device and Materials(ReSEM), Chungju National University) ;
  • Son Y. J. (Department of Materials Science and Engineering/Research Center for Sustainable Eco-Device and Materials(ReSEM), Chungju National University) ;
  • Kweon J. C. (Department of Materials Science and Engineering/Research Center for Sustainable Eco-Device and Materials(ReSEM), Chungju National University) ;
  • Cho K. W. (Department of Materials Science and Engineering/Research Center for Sustainable Eco-Device and Materials(ReSEM), Chungju National University) ;
  • Yoon M. S. (Department of Materials Science and Engineering/Research Center for Sustainable Eco-Device and Materials(ReSEM), Chungju National University) ;
  • Kim I. H. (Department of Materials Science and Engineering/Research Center for Sustainable Eco-Device and Materials(ReSEM), Chungju National University) ;
  • Kim Y. M. (Corea Electronics Corporation(CEC)) ;
  • Ur S. C. (Department of Materials Science and Engineering/Research Center for Sustainable Eco-Device and Materials(ReSEM), Chungju National University)
  • 최용길 (충주대학교 신소재공학과/친환경 에너지 변환 저장소재 및 부품개발 연구센터) ;
  • 손영진 (충주대학교 신소재공학과/친환경 에너지 변환 저장소재 및 부품개발 연구센터) ;
  • 권준철 (충주대학교 신소재공학과/친환경 에너지 변환 저장소재 및 부품개발 연구센터) ;
  • 조경원 (충주대학교 신소재공학과/친환경 에너지 변환 저장소재 및 부품개발 연구센터) ;
  • 윤만순 (충주대학교 신소재공학과/친환경 에너지 변환 저장소재 및 부품개발 연구센터) ;
  • 김일호 (충주대학교 신소재공학과/친환경 에너지 변환 저장소재 및 부품개발 연구센터) ;
  • 김영민 (고려전자(주) 소재개발부) ;
  • 어순철 (충주대학교 신소재공학과/친환경 에너지 변환 저장소재 및 부품개발 연구센터)
  • Published : 2005.06.01
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Abstract

Perovskite $Pb(Ni_{1/3}Nb_{2/3})O_3-Pb(Zr,Ti)O_3[PNN-PZT]$ ceramics were synthesized by conventional ceramic processing technique. In order to modify piezoelectric properties for sensor application in this system, NiO addition was considered to provide $Ni^{+2}$ as an acceptor, which was known to occupy with B site in the structure. The effect of NiO addition up to $8\;mol\%$ on the following piezoelectric properties as well as sintering properties was investigated. When NiO added more than $1\;mol\%$, average grain size was decreased and second phase was found to form. Moreover, the second phase caused decrease in relative dielectric constant $(\varepsilon_{33}T/\varepsilon0)$, electro-mechanical coupling factor $(k_p)$, and piezoelectric charge constant $(d_{33})$, while increasing mechanical quality factor $(Q_m)$. When $1\;mol\%$ NiO was added, density, dielectric properties and piezoelectric properties were abruptly increased.

Keywords

References

  1. L. Lebrun, B. Guiffard, D. Audigier, E. Boucher, D. Guyomar, L. Eyraud and E. Pleska, J. of Eur. Cer. Soc. 21, 1357 (2001) https://doi.org/10.1016/S0955-2219(01)00018-8
  2. R. A. Pferner. G. Thurn and F. Aldinger, Mater. Chem. Phys., 61, 24 (1999) https://doi.org/10.1016/S0254-0584(99)00108-X
  3. H. R. Rukmini, R. N. P. Choudhary and V. V. Rao, Mater. Chem. Phys., 55, 108 (1998) https://doi.org/10.1016/S0254-0584(98)00144-8
  4. A. P. Barranco, F. C. Pinar, P. Mattinez and E. T. Garciaet, J. Euro. Ceram. Soc., 21, 523 (2001) https://doi.org/10.1016/S0955-2219(00)00216-8
  5. D. Berlincourt, 'Parameters of Piezoelectric Ceramics, in Ultrasonic Transducer Materials 100', O. E. Mattiat, Plenum Press, Newyork-London (1971)
  6. A. Fukumoto, Ferroelectrics, 40, 217 (1982) https://doi.org/10.1080/00150198208218171
  7. H. V. Nguyen, T. T. Srinivasan, R. E. Newnham and A. S. Bhalla, 'Hysteretic Forces on a Magnet Levitation above the high Tc Superconductor / Polymer 0-3 composite,' 112-SVI-89, 91th Annual of American Ceramic Soc. Indianapolis, Indiana, USA (1989)
  8. W. L. Zhong, Y. G. Wang, S. B. Yue and P. L. Zhang, Soild State Comm., 90(6), 383 (1994) https://doi.org/10.1016/0038-1098(94)90804-4
  9. S. Y. Chu, T. Y. Chen and I. T. Tsai, Mater. Lett., 53, 752 (2004) https://doi.org/10.1016/j.matlet.2003.07.004
  10. S. Takahashi and S. Hirose, Jpn. J. Appl. Phys., 31(9B), 3055 (1992) https://doi.org/10.1143/JJAP.31.3055
  11. T. Takenaka, A. S. Bhalla and L. E. Cross, J. Am. Ceram. Soc., 72(6), 1016 (1989) https://doi.org/10.1111/j.1151-2916.1989.tb06261.x
  12. T. Ikeda, 'Fundamentals of Piezoelectricity', Tohoku., Japan, 221 (1980)
  13. Z. Gui, L. Li, H. Lin and X. Zhang, Ferroelectric, 101, 93 (1990) https://doi.org/10.1080/00150199008016505
  14. T. Kanegae. K. Sakada and T. Takenaka, Jpn. J. Appl. Phys., 30(9B), 2232 (1991) https://doi.org/10.1143/JJAP.30.2232
  15. A. S. Khim, J. Wang and X. Junmin, J. Alloys Comp., 311(2), 181 (2000) https://doi.org/10.1016/S0925-8388(00)01117-8
  16. J. Wang, D. M. Wan, J. M. Xue and W. B. Ng. Am. Ceram. Soc., 82, 477 (1999) https://doi.org/10.1111/j.1551-2916.1999.tb20091.x
  17. IRE Standards on Piezoelectric Crystals: Measurements of piezoelectric ceramics, Proc. IRE, 49, 1161 (1961) https://doi.org/10.1109/JRPROC.1961.287860
  18. S. L. Swartz and T. R. Shrout, Mater. Res. Bull., 1245 (1982) https://doi.org/10.1016/0025-5408(82)90159-3
  19. K. Kakegawa, J. Mohri, S. shirasaki and K. Takahashi, J. Am. Ceram. Soc., 65, 515 (1982) https://doi.org/10.1111/j.1151-2916.1982.tb10344.x
  20. J. C. Wurst and J. A. Nelson, J. Am. Cerm, Soc., 55, 450, (1972) https://doi.org/10.1111/j.1151-2916.1972.tb11224.x
  21. E. S. Na, Y. H. Kim and S. C. Choi, Journal of the Korean Association of Crystal Growth., 10(2), 245-251 (2000)
  22. B. Jaffe, Piezoelectric Ceramics, Academic Press., 33, (1971)
  23. K. Okazaki and K. Nagata, J. Am. Cerm. Soc., 56(2), 82 (1973) https://doi.org/10.1111/j.1151-2916.1973.tb12363.x
  24. T. Kamiya, T. Susuki and T. Turumi, Jpn. J. Appl. Phys., 31(9B), 3058-60, (1992) https://doi.org/10.1143/JJAP.31.3058
  25. U. Robels, L. Schneider-Stotmann and G. Arlt, Ferroelectrics. 133, 223 (1992) https://doi.org/10.1080/00150199208218003