Journal of the Korean Crystal Growth and Crystal Technology (한국결정성장학회지)

The Korea Association of Crystal Growth (한국결정성장학회)
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Fabrication of $TiN_x$ by planetary milling

Planetary milling에 의한 $TiN_x$의 제조

  • Kim, Sung-Jin (Department of Materials Science & Engineering, Kumoh National University of Technology) ;
  • Kim, Dong-Sik (Department of Materials Science & Engineering, Kumoh National University of Technology) ;
  • Rahno, Khamidova (Department of Materials Science & Engineering, Kumoh National University of Technology) ;
  • Park, Sung-Bum (Department of Materials Science & Engineering, Kumoh National University of Technology) ;
  • Gwon, Won-Il (Department of Materials Science & Engineering, Kumoh National University of Technology) ;
  • Kim, Moon-Hyup (Department of Materials Science & Engineering, Kumoh National University of Technology) ;
  • Woo, Heung-Sik (Department of Safety Engineering, Dongguk University) ;
  • Ahn, Joong-Ho (Advenced Materials Engineering, Andong National University)
  • 김성진 (금오공과대학교 재료공학과) ;
  • 김동식 (금오공과대학교 재료공학과) ;
  • 라노 (금오공과대학교 재료공학과) ;
  • 박성범 (금오공과대학교 재료공학과) ;
  • 권원일 (금오공과대학교 재료공학과) ;
  • 김문협 (금오공과대학교 재료공학과) ;
  • 우흥식 (동국대학교 안전공학과) ;
  • 안중호 (안동대학교 신소재공학과)
  • Published : 2005.06.30
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Abstract

[ $TiN_x$ ] powder have been fabrication by making of reaction between titanium powder and $Si_3N_4$ bowl during a planetary milling. Milling times were maintained for 1 hour, 5 hours, and 10 hours, respectively. The XRD result showed existence of non-stoichiometric compound of $TiN_{0.26}$ after 5 hours milling and coexistence of TiN with $TiN_{0.26}$ after 10 hours milling. Particle size distribution was investigated by particle size analyzer and microstructure was analyzed by FE-SEM. The size of titanium was decreased with increasing the milling time and the mean size of $TiN_x$ after 10 hours milling was increased by 200 nm.

Planetary milling법을 사용하여 Ti 분말과 $Si_3N_4$ bowl과의 반응을 유도하여 $TiN_x$을 제조하였으며, 이때 milling 시간은 1시간, 5시간, 10시간으로 조정하였다. 시편의 물성평가는 X선 회절분석을 통해 결정상의 변화를 분석한 결과 milling 시간이 5시간이 되면 비화학당량적 화합물인 $TiN_{0.26}$가 먼저 생성되고 10시간의 milling에서는 $TiN_{0.26}$과 TiN이 혼재되어 있는 것으로 확인되었다. 입도분석 및 FE-SEM으로 미세구조 분석을 한 결과, milling 시간이 증가함에 따라 Ti 입자사이즈가 감소하는 것으로 나타났으며, 10시간의 milling에서는 평균사이즈가 200nm의 $TiN_x$를 제조할 수 있었다.

Keywords

References

  1. A.H. Claure and J.J. de Barbadillp, Solid State Powder Processing, 3-19 (TMS, 1990)
  2. J.S. Benjamin, 'Dispersion strengthened superalloys by mechanical alloying', Metall. Trans. 1 (1970) 2943
  3. J.S. Jo and S.I. Kweon, 'High temperature behaviours of mechanically alloyed Ni-base alloys', 1992 Spring Meeting Abstracts 30 (1992) 648
  4. G.B. Schaffer and P.G. McCormick, 'A nanocrystalline mixture of intermetallic compounds by mechanical alloying', Metall. Trans. A 23 (1992) 1285 https://doi.org/10.1007/BF02665060
  5. J. Zbiral, G. Jangg and G. Korb, 'Influences of heat treatments on the constitution and the recrystallization response of the Y'-strengthened ODS-Ni-base alloy PM 3030', Metall. Sci. Forum, Trans Tech. Publications, Zurich 88-90 (1992) 18
  6. J.S. Benjamin and M.J. Bamford, 'Dispersion strengthned aluminum made by mechanical alloying', Metall Trans. 8A (1977) 1301
  7. J.S. Benjamin and R.D. Schelleng, 'Temperature alloys : theory design', Metall Trans. 12A (1981) 1827
  8. K. Aoki, A. Memezawa and T. Masumoto, 'Nitrogen induced amorphization of Ti-Zr powders during mechanical alloying', Appl. Phys. Lett. 61 (1992) 1037
  9. K. Sakurai, C.H. Lee, N. Kuroda, T. Fukunaga and U. Mizutani, 'Nitrogen effect in mechanical alloying of immiscible Cu-V : extended X-ray absorption fine structure study', J. Appl. Phys. 75 (1994) 7752
  10. Y. Ogino, S. Murayama and T. Yamasaki, 'Influence of milling atmosphere on amorphization of chromium and Cr-Cu powders by ball milling', J. Less-Common Metals 168 (1991) 221
  11. C.H. Lee, M. Mori, Fukunaga and U. Mizutani, 'Structural evidence for the amorphization of mechanically alloyed Cu-Ta powders studied by neutron diffraction and EXAFS', Mat. Sci. Forum 88 (1992) 399