A study on the HPHT-processed NOUV diamonds by means of their gemological and spectroscopic properties

  • Published : 2005.06.30

Abstract

This study has been carried out with the eight HPHT processed NOUV diamonds - two yellow, two yellowish green, two green and two orangy yellow color stones. The gemological properties of these diamonds included a highly saturated body color, graphitized fractures around the girdles, tension cracks around crystalline inclusions, long-wave UV with medium yellowish green to a very strong yellowish green luminescence, and short-wave UV with faint yellowish green to a strong yellowish green luminescence. Distinctive features of spectroscopic properties include absorption peaks at 415 nm and 503 nm a strong absorption band at $460{\sim}480nm$ and a H2 center at 986nm. Infrared spectra showed an absorption peak at $1344cm^{-1}$ (C center), which is the characteristics related to single substitutional nitrogen.

Keywords

References

  1. T.M. Moses and I. Reinitz, 'Yellow to yellow-green diamonds treated by HPHT, from GE and others', Gems Gemology 35(4) (1999) 203
  2. T. Anthony, J. Casey, S. Vagarali, J. Shigley, T. Moses and M.S. Hall, 'GE-POL yellowish green diamonds enter the marketplace', Professional Jeweler 3(5) (2000) 36
  3. A.T. Collins, 'The color of diamond and how it may be changed', J. Gemm. 27(6) (2001) 341 https://doi.org/10.15506/JoG.2001.27.6.341
  4. F.D. Weerdt and A.T. Collins, 'The influence of pressure on high-pressure, high-temperature annealing of type Ia diamond', Diamond Relat. Mater. 12 (2003) 507
  5. B. Deljanin, 'HPHT-processed diamonds from Korea', Gems Gemology 39(3) (2003) 240
  6. Y.C. Kim and H.M. Choi, 'A study on the identification of type IIa natural diamonds treated by the HPHT method', J. Kor. Cryst. Growth 14(1) (2004) 21
  7. A.T. Collins, H. Kanda and H. Kitawaki, 'Colour changes produced in natural brown diamonds by high-pressure, high-temperature treatment', Diamond Relat. Mater. 9 (2000) 113
  8. A.T. Collins, 'The detection of colour-enhanced and synthetic gem diamonds by optical spectroscopy', Diamond Relat. Mater. 12 (2003) 1976
  9. F.D. Weerdt and J.V. Royen, 'Investigation of seven diamonds, HPHT treated by NovaDiamond', J. Gemm. 27(4) (2000) 201 https://doi.org/10.15506/JoG.2000.27.4.201
  10. F.D. Weerdt and J.V. Royen, 'Defects in coloured natural diamonds', Diamond Relat. Mater. 10 (2001) 474 https://doi.org/10.1016/S0925-9635(00)00521-5
  11. I.M. Reinitz, P.R. Brerki, J.E. Shigley, S.F. McClure and T.M. Moses, 'Identification of HPHT-treated yellow to green diamonds' Gems Gemology 36(2) (2000) 128
  12. M.A. Prelas, G. Popovici and L.K. Bigelow, 'Handbook of industrial diamonds and diamond films', ch. 7 (New York, Marcel dekker, 1998), p. 227
  13. P.R. Buerki, I.M. Reinitz, S. Muhlmeister and S. Elen, 'Observation of the $H_2$ defect in gem-quality type Ia diamond', Diamond Relat. Mater. 8 (1999) 1061