DOI QR코드

DOI QR Code

인산염 피막처리 분말을 사용한 Fe-6.0 wt%Si 합금 압분자심의 자기적 특성

Magnetic Properties of Fe-6.0 wt%Si Alloy Dust Cores Prepared with Phosphate-coated Powders

  • 장대호 (안동대학교 공과대학 신소재공학부) ;
  • 노태환 (안동대학교 공과대학 신소재공학부) ;
  • 김광윤 (한국과학기술연구원 신금속재료연구센터) ;
  • 최광보 ((주)창성 중앙연구소)
  • Jang, D.H. (School of Advanced Materials Engineering, Andong National University) ;
  • Noh, T.H. (School of Advanced Materials Engineering, Andong National University) ;
  • Kim, K.Y. (Advanced Metals Research Center, Korea Institute of Science & Technology) ;
  • Choi, G.B. (Research Center, Changsung)
  • 발행 : 2005.10.01

초록

가스분무법으로 제조한 $35\~180\;{\mu}m$ 크기의 $Fe-6.0wt\%Si$ 합금분말에 대하여 인산염계 절연물질을 피막처리하고 $600\~900^{\circ}C$에서 1시간 동안 열처리한 후 압축성형한 압분자심(분말코아)의 자기적 성질 및 기계적 특성을 조사하였다. 대체적으로 열처리온도가 증가할수록 압축강도가 감소하였으며, 자심손실 또한 낮아졌다. $800^{\circ}C$에서 열처리한 경우 압축성형강도가 15 kgf, 100 kHz에서 실효투자율은 74, 품질계수는 26, 50 Oe의 직류자장 하에서 퍼센트투자율은 78 정도의 값을 나타내었으며, 50 kHz-0.1 T에서 자심손실은 $750\;mW/cm^3$였다. 그리고 투자율-주파수 곡선 상에서의 cut-off 주파수는 거의 200 kHz 이상에 이르는 것으로 나타났다. $Fe-6.0wt\%Si$ 합금 압분자심의 이러한 제반 특성은 인산염 피막의 양호한 전기절연효과와, 고규소농도에 따른 합금의 결정자기이방성 및 포화자기변형의 감소, 전기비저항의 증대 등 기초 물성의 변화에 기인하는 것으로 사료되었다.

Dust cores (compressed powder cores) of $Fe-6.0wt\%Si$ alloy with a size of $35\~180\;{\mu}m$ in diameter have been prepared by phosphate coatings and annealings at $600\~900^{\circ}C$ for 1 h in nitrogen atmosphere. Further the magnetic and mechanical properties of the powder cores were investigated. As a general trends, the compressive strength and core loss decreased with the increase in annealing temperature. When annealed at $800^{\circ}C$, the compressive strength was 15 kgf, the permeability and quality factor were 74 and 26, respectively. Moreover the core loss at 50 kHz and 0.1 T induction was $750\;mW/cm^3$, and the percent permeability under the static field of 50 Oe was estimated to be about 78. In addition, the cut-off frequency in the cure representing the frequency dependence of effective permeability was measured to be around 200 kHz. These properties of the $Fe-6.0wt\%Si$ alloy dust cores could be considered to be due to the good insulation effect of iron-phosphate coats, the decrease in magnetocrystalline anisotropy and saturation magnetostriction and the increase in electric resistivity.

키워드

참고문헌

  1. K. S. Narasimhan, Soft Magnetic Materials 96, Assessing the Business Opportunities, Markets and Technologies for Soft Magnetic Materials 96(1996)
  2. A. Jack, Powder Metallurgy World Congress and Exhibition, Special Interest Seminar, Magnetic and Functional Materials (1998)
  3. L. Hultsman, Proceedings of the 2002 World Congress on Powder Metallurgy & Particulate Materials, Metal Powder Industries Federation, pp. 14-26(2005)
  4. M. Muller, A. Novy, M. Brunner, and R. Hilzinger, J. Magn. Magn. Mater., 196-197, 357(1999) https://doi.org/10.1016/S0304-8853(98)00747-1
  5. V. Leger, C. Ramiarinjaona, R. Barrue, and R. Lebourgeois, J. Magn. Magn. Mater., 191, 169(1999) https://doi.org/10.1016/S0304-8853(98)00300-X
  6. D. Nuetzel, G. Rieger, J. Wecker, J. Petzold, and M. Mueller, J. Magn. Magn. Mater., 196-197, 327(1999)
  7. 濱欠裕貴, 藤井重男, 日立金屬技報, 21, 39(2005)
  8. S. Tajima, T. Hattori, M. Kondoh, M. Sugiyama, K. Higashiyama, H. Kishimoto, and T. Kikko, Mater. Trans., 45(6), 1891(2004) https://doi.org/10.2320/matertrans.45.1891
  9. H. Mitani, H. Houjou, and K. Fujisawa, Kobe Steel Engineering Reports, 54(1), 39(2004)
  10. B. Shen, H. Kimura, A. Inoue, M. Omori, and A. Okubo, Mater. Trans., 43(8), 1961 (2002) https://doi.org/10.2320/matertrans.43.1961
  11. S. Ishihara, W. Zhang, H. M. Kimura, M. Omori, and A. Inoue, Mater. Trans., 44(1), 1(2003)
  12. S. Tajima, T. Hattori, M. Kondoh, H. Kishimoto, M. Sugiyama, and T. Kikko, J. Jpn. Soc. Powder & Powder Metallurgy, 52(3), 164(2005) https://doi.org/10.2497/jjspm.52.164
  13. H. Mitani, A. Hanaki, H. Yaguchi, and Y. Seki, Kobe Steel Engineering Reports, 48(3), 25(1998)
  14. H. Horie, K. Ochiai, I. Arima, and M. Morita, J. Jpn. Inst. Met., 50(2), 127(1986)
  15. T. H. Noh, H. Y. Choi, and S. J. Ahn, J. Kor. Mag. Soc., 14(1), 7(2004)