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Dielectric and Piezoelectric Properties of Pb(Zr1/2Ti1/2)O3-Pb(Cu1/3Nb2/3)O3-Pb(Mn1/3Nb2/3)O3 System

Pb(Zr1/2Ti1/2O3-Pb(Cu1/3Nb2/3)O3-Pb(Mn1/3Nb2/3)O3계의 유전 및 압전 특성

  • Lee, Hyeung-Gyu (Electronic Materials and Packaging Research Center, KETI) ;
  • Kang, Hyung-Won (Electronic Materials and Packaging Research Center, KETI) ;
  • Choi, Ji-Hyun (Electronic Materials and Packaging Research Center, KETI)
  • 이형규 (전자부품연구원 전자소재패키징연구센터) ;
  • 강형원 (전자부품연구원 전자소재패키징연구센터) ;
  • 최지현 (전자부품연구원 전자소재패키징연구센터)
  • Published : 2005.10.01

Abstract

Dielectric and Piezoelectric properties of complex perovskite 0.92Pb($Zr_{1/2}Ti_{1/2})O_{3}-(0.08-x)Pb(Cu_{1/3}Nb_{2/3})O_{3}-xPb(Mn_{1/3}Nb_{2/3})O_{3}(0{\leq}x{\leq}0.080$) (PZT-PCN-PMN) system were investigated as a function of PMN content. With the increase of PMN content of the sintered specimens, tetragonal phase was coexisted with rhombohedral phase, the dielectric constant was decreased, mechanical quality factor ($Q_{m}$) was inceased, and optimal sintering temperature was increased up to 1050$^{\circ}C$. For the composition of x = 0.064 sintered at 1050$^{\circ}C$ for 2 h, 1939 of maximum mechanical quality factor ($Q_{m}$), 57$\%$ of electromechanical coupling factor ($k_{p}$), and 1100$^{\circ}C$ of dielectric constant, 0.37$\% $ of dielectric loss (tan $\delta$) were obtained.

Keywords

References

  1. Electronic Materials Manufactures Association of Japan, 'Piezoelectric Ceramics and their Application(in Jpn.),' Tokyo, 114-5 (1974)
  2. D. E. Wittner and R. C. Buchanon, 'Low-Temperature Densification of Lead Zirconia Titanate with Vanadium Pentoxide Additive,' J. Am. Ceram. Soc., 64 [8] 485-90 (1981) https://doi.org/10.1111/j.1151-2916.1981.tb09902.x
  3. S. Y. Cheng, S. L. Fu, and C. C. Wei, 'Low-Temperature Sintering of PZT Ceramics,' Ceram. Inter., 13 223-31 (1987) https://doi.org/10.1016/0272-8842(87)90066-6
  4. S. Y. Cheng, S. L. Fu, C. C. Wei, and G. M. Ke, 'The Properties of Low-Temperature Fired Piezoelectric Ceramics,' J. Meter Sci., 21 572-76 (1986)
  5. D. Dong, K. Murakami, N. Okada, and S. Kaneko, 'Behavior of Morphotropic Phase Boundary in Low-Temperature Sintered Lead Zirconate-Titanate Ceramics with $BiFeO_3$ and $Ba(Cu_{0.5}W_{0.5})O_3$,' Jpn. J. Appl. Phys., 33 [9B] 5529-32 (1994) https://doi.org/10.1143/JJAP.33.5529
  6. T. Yamamoto, 'Optimum Preparation Methods for Piezoelectric Ceramics and their Evaluation,' Am. Ceram. Soc. Bull., 71 [6] 978-85 (1992) https://doi.org/10.1111/j.1151-2916.1988.tb07568.x
  7. H. Zheng, I. M. Reaney, and W. E. Lee, 'Effects of Octahedral Tilting on the Piezoelectric Properties of Strontium/Barium/Niobium-Doped Soft Lead Zirconate Titanate Ceramics,' J. Am. Ceram. Soc., 85 [9] 2337-44 (2002) https://doi.org/10.1111/j.1151-2916.2002.tb00457.x
  8. B. Jaffe, W. R. Cook, Jr., and H. Jaffe, Piezoelectric Ceramics, pp. 271-280 Academic Press, London & New York, 1971
  9. K. H. Yoon and H. R. Lee, 'Effect of $Ba^{2+}$ Substitution on Dielectric and Electric-Field-Induced Strain Properties of PMN-PZ-PT Ceramics,' J. Am. Ceram. Soc., 83 [11] 2693-98 (2000) https://doi.org/10.1111/j.1151-2916.2000.tb01618.x