Preferential face coating of knitted PET fabrics via UV curing for water- and oil-repellent finish

자외선 경화에 의한 PET 니트직물의 편면 발수발유 가공

  • Jeong, Yong-Kyun (School of Advanced Materials and System Engineering, Kumoh National Institute of Technology) ;
  • Jeong, Yongjin (School of Textile Engineering, Soongsil University) ;
  • Jang, Jinho (School of Advanced Materials and System Engineering, Kumoh National Institute of Technology)
  • 정용균 (금오공과대학교 신소재시스템공학부 섬유패션공학) ;
  • 정영진 (숭실대학교 공과대학 섬유공학부) ;
  • 장진호 (금오공과대학교 신소재시스템공학부 섬유패션공학)
  • Published : 2005.12.01

Abstract

Conventional pad- dry-cure(thermo-fixation) process usually produces functional performance on both sides of a fabric. UV curing technique was applied to impart water- and oil-repellent finish effective only on the face of a PET knitted fabric. The preferential one-side coating, by virtue of the limited penetration of UV light, was achieved by W curing after padding of a fluorocarbon agent without special coating or printing equipments. The difference in the functional property of face and back sides was examined by measuring water and oil repellency at each side of the treated fabric. The influence of pre/post-irradiation dose and agent concentration on the performance of the finished fabrics were investigated. While increase in both resin concentration and post-irradiation did not have significant effect on the finish, UV pre-irradiation of PET fabrics caused remarkable influence presumably due to appropriate surface modification of PET fabrics required for facile wetting of the resin. The dimensional stability and color change of the UV cured fabrics measured by FAST and reflectance spectrophotometry showed significantly decreased color difference and increased percent extension compared with the samples pre-irradiated without agent application.

Keywords

References

  1. G. Y. Moon, Fiber Wetting and Water Repellent Finish, J. Korean Fiber Soc. 7, 99-106(1970)
  2. R.R. Thomas, 'Fluoropolymers', G. Hougham, P. E. Cassidy, K. Johns, T. Davidson(Ed.), Vol 2, Kluwer Academic/Plenum Publishers, N.Y., pp.47-67, 1999
  3. E. Kissa, 'Fluorinated Surfactants and Repellents', Marcel Decker Inc, N.Y., pp. 516-551, 2001
  4. I. Hohne, 'Textile Finishing', D. Heywood(Ed.), Society of Coiourists, Bradford, pp.176-210, 2003
  5. I. J. Pack, D. Kim and S. Lee, Fluorine-containing Surface Modification Agents, Prospect. Industr. Chem., 2(2), 13-19(1999)
  6. B. Lee and J. Rho, Surface Treatment of Polymers Using Direct Fluorination, Polym. Sci. Technol., 13, 751-758(2002)
  7. J. Ha, I. J. Pack and S. Lee, Application of Water and Oil Repellent Based on Perfluoroalkyl Acrylate, Polym. Sci. Technol., 13, 744-750(2002)
  8. F. Audenaert, H. Lens, D. Rolly, and P. Van der Elst, Fluorochemical Textile Repellents-Synthesis and applications: A 3M Perspective, J. Text. Inst., Part 3, 90, 76-94(1999) https://doi.org/10.1080/00405009908659480
  9. B. O. Lee, P. K. Park, H. C. Kim, Y. S. Cheong, and H. S. Lee, Water Repellent Finish for Divided Type PET/Nylon Fabrics with Fluoroalkyl Resin, J. Korean Soc. Dyers Finishers, 9, 213-218(1997)
  10. P. K. Park, B. O. Lee, H. C. Kim, and H. Y. Kim, Flame Retardant and Water Repellent Finishing of Automobile Indoor Fabrics, J. Korean Soc. Dyers Finishers, 11, 285-290(1999)
  11. J. Jang, M. J. Kim, and Y. J. Jeong, Cationic Dyeable Treatment of PET and PTT Fabrics by Continuous UV/$O_{3}$ Irradiation, J. Korean Fiber Soc. 40, 423-430(2003)
  12. J. Jang, S. I. Eam, and Y. H. Kim, Contiuous Surface Modification of PET Fihn via UV Irradiation: Effect of Spectral Irradiance, J. Korean Fiber Soc. 39, 100-107(2002)
  13. AATCC Test method 22-1985 & 118-1983, AATCC
  14. J. F. Rabek, 'Mechanisms of Photophysical Processes and Photochemical Reactions in Polymer', John & Sons, N.Y., pp.478-570, 1987
  15. I. Matieson and R. H. Bradley, Improved Adhesion to Polymers by UV/ozone Surface Oxidation, Int. J. Adhesion Adhesives, 16, 29-31(1996) https://doi.org/10.1016/0143-7496(96)88482-X
  16. M. Stibel, M. J. Walzak, J. M. Hill, A. Lin, E. Karbashewski, and C. S. Lyons, A Compression of Gas-phase Methods of Modifying Polymer Surface, J. Adhesion Sci. Technol., 9, 365-383(1995) https://doi.org/10.1163/156856195X00554