Applied Chemistry for Engineering (공업화학)

The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
권호 표지

Fabrication and Characterization of Zirconia-Alumina Composites by Organic-Inorganic Solution Technique

유기물-무기물 용액법을 이용한 지르코니아-알루미나 복합체의 제조 및 특성

  • Kim, Youn Cheol (Division of Chemical Engineering, Kongju National University) ;
  • Bang, Moon-Soo (Division of Chemical Engineering, Kongju National University) ;
  • Lee, Sang Jin (Department of Advanced Materials Science and Engineering, Mokpo National University)
  • 김연철 (공주대학교 화학공학부) ;
  • 방문수 (공주대학교 화학공학부) ;
  • 이상진 (목포대학교 신소재공학과)
  • Received : 2005.02.02
  • Accepted : 2005.08.08
  • Published : 2005.10.10
Download PDF
⟨ Previous Next ⟩

Abstract

Zirconia-alumina polymer precursor was prepared from zirconium acetylacetonate (ZA). paluminium nitrate (AN), polyethylene glycol (PEG), and ethyl alcohol via an organic-inorganic solution technique. The thermal properties and viscosity of the polymer precursor were measured by differential scanning calorimetry (DSC), thermograbimetric analyzer (TGA), and dynamic viscometer. The vigorous exothermic reaction with volume expansion occurred at $140^{\circ}C$. The volume expansion was caused by abrupt decomposition of the organic group in metal compounds and the metal ions-PEG reaction. The evidences for these reactions were confirmed by FT-IR and $^{13}C$ solid NMR results. The peak intensity at N-O, O-H and C=C decreased with increasing temperature. This indicated that the decomposition of metal compounds and the metal ions-PEG reaction occurred during the vigorous exothermic reaction. At $800^{\circ}C$ for 2 h, the porous powders transformed to the crystalline $ZrO_2-Al_2O_3$ composites.

Zirconia-alumina 고분자 전구체가 유기물-무기물 용액 방법으로 zirconium acetylacetonate (ZA), aluminium nitrate (AN), polyethylene glycol (PEG), 그리고 에탄올을 이용하여 제조되었다. 고분자 전구체의 열적 특성 및 점도를 시차주사열용량분석기(DSC), 열중량분석기(TGA), 그리고 동적유변측정기를 이용하여 측정하였다. 부피 팽창을 동반하는 강렬한 발열반응이 $140^{\circ}C$에서 일어났다. 고분자 전구체의 부피팽창은 금속물질중에 유기물의 분해반응과 금속양이온과 PEG 사이의 반응에 의한 것이다. 이들 분해반응과 금속양이온과 PEG 사이의 반응에 대한 여부를 적외선분광기(FT-IR)와 $^{13}C$ solid-NMR 결과로부터 확인하였다. 고분자 전구체의 온도가 증가함에 따라 N-O, O-H, 그리고 C=C에서의 피이크 강도가 감소하였다. 이 결과는 강렬한 발열반응시 금속 물질의 분해반응과 PEG와 금속양이온의 반응이 일어났음을 나타내는 것이다. 다공성 파우더는 $800^{\circ}C$에서 2 h 동안 소결과정을 거쳐 결정성 $ZrO_2-Al_2O_3$ 복합체가 되었다.

Keywords

Acknowledgement

Supported by : 한국과학재단

References

  1. K. Niihara, J. Ceram. Soc. Jpn., 99, 974 (1991) https://doi.org/10.2109/jcersj.99.974
  2. M. Sternitzke, J. Eur. Ceram. Soc., 17, 1061 (1997) https://doi.org/10.1016/S0955-2219(96)00222-1
  3. J. Dusza, P. Sajgalik, and M. Steen, J. Am. Ceram Soc., 82, 3613 (1999) https://doi.org/10.1111/j.1151-2916.1999.tb02287.x
  4. S. T. Buljan, J. G. Baldoni, and M. L. Huckabee, Am. Ceram. Soc. Bull., 66, 347 (1987) https://doi.org/10.1111/j.1151-2916.1983.tb10046.x
  5. M. Herrmann, C. Schuber, A. Rendtel, and H. Hubner, J. Am. Ceram Soc., 81, 1095 (1998) https://doi.org/10.1111/j.1151-2916.1998.tb02456.x
  6. A. H. Heuer, J. Am. Ceram Soc., 70, 689 (1987) https://doi.org/10.1111/j.1151-2916.1987.tb04865.x
  7. C. Laurent, A. Rousset, P. Bonnefond, D. Oquab, and B. Lavelle, J. Eur. Ceram. Soc., 16, 937 (1996) https://doi.org/10.1016/0955-2219(96)00008-8
  8. A. C. Faro, K. R. Souza, V. Lucia, D. J. Camorim, and M. B. Cardoso, Phys. Chem. Chem. Phys., 5, 1932 (2003) https://doi.org/10.1039/b300899a
  9. D. J. Green, J. Am. Ceram Soc., 65, 610 (1982) https://doi.org/10.1111/j.1151-2916.1982.tb09939.x
  10. J. G. Liu and D. J. Wilkox, J. Mater. Res., 10, 84 (1995) https://doi.org/10.1557/JMR.1995.0084
  11. M. K. Naskar, M. Chatterjee, and N. S. Lakshmi, J. Mater. Sci., 37, 343 (2002) https://doi.org/10.1023/A:1013656413578
  12. C. Li, Y. W. Chen, and T. M. Yen, J. Sol-Gel Sci. Technol., 4, 205 (1995) https://doi.org/10.1007/BF00488375
  13. S. Bhaduri, S. B. Bhaduri, and E. Zhou, J. Mater. Res., 13, 136 (1998)
  14. M. Balasubramanian, S. K. Malhotra, and C. V. Gokulrathnam, J. Mater. Sci., 30, 3515 (1995) https://doi.org/10.1007/BF00349903
  15. R. D. Sisson and B. M. Smyser, NanoStructured Mater., 10, 829 (1998) https://doi.org/10.1016/S0965-9773(98)00119-6
  16. R. N. Viswanath and S. Ramasamy, NanoStructured Mater., 12, 1085 (1999) https://doi.org/10.1016/S0965-9773(99)00304-9
  17. M. Chattezjee, M. K. Naskar, and D. Ganguli, J. Sol-Gel Sci. Technol., 28, 217 (2003) https://doi.org/10.1023/A:1026085217698
  18. S. J. Lee, Y. C. Kim, and J. H. Hwang, J. Ceram. Proc. Res., 5, 223 (2004)
  19. M. P. Pechini, U. S. Patent, 3,330,697 (1967)
  20. S. J. Lee, M. D. Biegalski, and W. M. Kriven, J. Mater. Res., 14, 3001 (1999) https://doi.org/10.1557/JMR.1999.0403
  21. S. J. Lee, E. A. Benson, and W. M. Kriven, J. Am. Ceram Soc., 82, 2049 (1999) https://doi.org/10.1111/j.1151-2916.1999.tb02039.x
  22. S. J. Lee and Y. C. Kim, J. Kor. Ceram. Soc., 40, 837 (2003) https://doi.org/10.4191/KCERS.2003.40.9.837
  23. S. J. Lee and W. M. Kriven, J. Am. Ceram. Soc., 81, 2605 (1998) https://doi.org/10.1111/j.1151-2916.1998.tb02667.x
  24. S. W. Lu, B. J. Lee, and J. A. Mann, Mater. Left., 43, 102 (2000)
  25. X. Wu, J. Zou, S. Yang, and D. Eang, J. Colloid & Interface Sci., 239, 369 (2001) https://doi.org/10.1006/jcis.2001.7600
  26. J. D. Tsay, T. T. Fang, T. A. Gubiotti, and J. Y. Ying, J. Mater. Sci., 33, 3721 (1998) https://doi.org/10.1023/A:1004636219542
  27. J. J. Clark, T. Takeuchi, N. Ohtori, and D. C. Sinclair, J. Mater. Chem., 9, 83 (1999) https://doi.org/10.1039/a805756g
  28. P. Duran, D. Gutierrez, J. Tartaj, M. A. Banares, and C. Moure, J. Eur. Ceram. Soc., 22, 797 (2002) https://doi.org/10.1016/S0955-2219(01)00392-2
  29. J. J. Koenig, Spectroscopy of Polymers, ACS, 197 (1992)
  30. Z. Chen, K. K. Chawla, and M. Koopman, Mater. Sci. Eng., 367, 24 (2004) https://doi.org/10.1016/j.msea.2003.09.070