Elastomers and Composites

The Rubber Society of Korea (한국고무학회)
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Study on Synthesis and Properties of Water-born Polyurethane

수분산성 폴리우레탄의 합성 및 물성에 관한 연구

  • Cho, Ur-Ryong (Department of Applied Chemical Engineering, Korea University of Technology and Education) ;
  • Choi, Seo-Yoon (Hoimyung Semiclean Co., Ltd)
  • 조을룡 (한국기술교육대학교 응용화학공학과) ;
  • 최서윤 (회명세미크린㈜)
  • Published : 2005.12.31
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Abstract

Polyurethane(PU) prepolymers were prepared from polyol and diisocyanate. Unionized PU prepolymers were synthesized from poly(propylene glycol)(PPG, MW: 1000), 2,2-bis (hydroxymethyl) propionic acid(DMPA), and isophorone diisocyanate(IPDI) by prepolymer syhthesizing process. After PU prepolymers were dispersed into water, the physical properties were investigated by changing the molar ratio of polyol and diisocyanate. The results showed a stable state with the best physical properties when the prepolymer was composed of PPG/DMPA with hard segment=40%, NCO%=3.43%, [NCO]: [OH]=1.5: 1.0 in molar ratio, and was dispersed into water with 30% solid content. PU prepolymers also were synthesized with various molar ratio of PPG and DMPA. Upon higher molar ratio of DMPA, particle size of polyurethane dispersion(PUD) gradually decreased. PU-prepolymers prepared from the various blocking agents represented characteristic initial deblocking temperatures that depended on the blocking agents, and the beginning of deblocking occured within 30 mins on all the blocking agents used.

폴리우레탄 프리폴리머들이 폴리올과 디이소시아네이트로부터 제조되었다. 이온화되지 않은 폴리우레탄 프리폴리머들은 폴리프로필렌 글리콜(PPG, MW:1000), 디메치롤 프로피온산(DMPA)과 이소포론 디이소시아네이트(IPDI)를 사용하여 합성되었다. 폴리올과 디이소시아네이트의 몰비를 변화시키면서 합성된 폴리우레탄 프리폴리머들은 물에 분산된 후 물성을 측정하였다. 실험결과는 프리폴리머가 하드세그먼트 40%, NCO 3.43%, [NCO]:[OH]=1.5:1.0의 조건에서 가장 안정한 분산액을 보여 주었고, 30%의 고형분으로 물에 분산되었다. 폴리우레탄 프리폴리머들은 또한 PPG와 DMPA의 몰비를 변화시키면서 합성되었다. DMPA의 몰비가 높을 때 폴리우레탄 수분산액의 입경은 감소하였다 3가지 종류의 말단기 차단제(blocking agent)를 사용하여 제조된 폴리우레탄 프리폴리머들은 사용된 차단제에 따라 각각 다른 초기 해리 온도를 나타내었고 3가지 종류의 차단제에 대한 해리의 시작은 모두 30분 안에 일어났다.

Keywords

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