Elastomers and Composites

  • 제40권1호
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  • Pages.45-52
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  • 2005
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  • 2092-9676(pISSN)
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  • 2288-7725(eISSN)
한국고무학회 (The Rubber Society of Korea)
권호 표지

마이크로파 조건에서 여러가지 산화제를 이용한 풀러렌[$C_{60}$의 산화반응

The Oxidation of Fullerene[$C_{60}$] using Several Oxidants under Microwave Irradiation

  • 발행 : 2005.03.31
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초록

풀러렌[$C_{60}$]은 3-chloroperoxy benzoic acid, benzoyl peroxide, trichloroisocyanuric acid, chromium(VI) oxide 등의 산화제를 사용하여 마이크로파 조건에서 반응시켜 풀러렌 산화물[$C_{60}(O)_n$] ($n=1{\sim}4$ or n=1)을 합성하였다. 동일한 마이크로파 조건에서 여러 가지 산화제와 풀러렌[$C_{60}$]의 고체상태 반응성은 3-chloroperoxy benzoic acid>benzoyl peroxide>trichloroisocyanuric acid$\simeq$chromium(VI) oxide 순으로 증가함을 나타냈다. MALDI-TOF-MS, UV-visible, 그리고 HPLC를 사용하여 분석한 결과 생성된 풀러렌 산화물은[$C_{60}(O)_n$] ($n=1{\sim}4$ or n=1)임을 알 수 있었다.

Synthesis or fullerene oxides[$C_{60}(O)_n$] ($n=1{\sim}4$ or n=1) by fullerene[$C_{60}$] and several oxidants such as 3-chloroperoxy benzoic acid, benzoyl peroxide, trichloroisocyanuric acid, and chromium(VI) oxide took place under microwave irradiation. The reactivity in solid state of fullerene[$C_{60}$] with various oxidants under same microwave rendition increased in order or 3- chloroperoxy benzoic acid > benzoyl peroxide > trichloroisocyanuric acid $\simeq$chromium(VI) oxide. The MALDI-TOF-MS, UV-visible spectra and HPLC analysis confirmed that the products of fullerene oxidation were [$C_{60}(O)_n$] ($n=1{\sim}4$ or n=1).

키워드

참고문헌

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